• Title/Summary/Keyword: Polychlorinated Biphenyls

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Distribution of Organochlorine Pesticides in Korean Human Tissues (한국인 장기조직중 유기염소제류 농약의 분포)

  • 유영찬;이상기;이수연;양자열;인상환
    • YAKHAK HOEJI
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    • v.45 no.4
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    • pp.366-377
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    • 2001
  • Persistent organochlorine pesticides has been used intensively in agriculture for a long time. The occurrence of organochlorine pesticides in the environment and subsequently in parts of the food chains, results in the intake of these compounds by human and animal. The measurement of the levels of organochlorine pesticides in tissues or blood of human populations is a good marker in evaluating the extent of exposure and hazards. So, most countries have conducted initial monitoring programs to determine organochlorine pesticides and polychlorinated biphenyls in human tissues. But, in Korea, a few research has been reported. In this study, the legally prohibited organochlorines, such as, $\alpha$-BHC, $\beta$-BHC, ${\gamma}$-BHC, $\delta$-BHC, p,p'-DDT, p,p'-DDD, p,p'-DDE, endrin, dieldrin and aldrin were determined in human blood, brain, adipose tissue, kidney cortex and liver tissues collected at autopsy of 10 men and 10 women, 16~65 years of age. Almost all the organochlorine pesticides mentioned previously were determined in human tissue samples indicated that they have been widely distributed in Korean human body. No significant difference was found in the levels of organochlorine pesticides between sexes, districts and ages.

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Degradation of Organochlorinated Pollutants by Microorganism -Isolation of PCBs-Degrading Strain and Conditions of Degradation- (미생물에 의한 난분해성 유기염소계 오염물질의 분해 -PCBs 분해 균주의 분리 및 그 분해 조건-)

  • Kim, Chan-Jo;Oh, Man-Jin;Lee, Jong-Soo;Sohn, Hyun-Ju;Sung, Chang-Keun
    • Applied Biological Chemistry
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    • v.29 no.3
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    • pp.273-278
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    • 1986
  • PCBs was degraded by bacterium, which was classified as a strain of Alcaligenes aquamarinus. Its PCB-42 degradation was maximized when grown on mineral salts medium containing 0.1% of PCB-42 as a sole carbon source at $25^{\circ}C$ and initial pH $7.0{\sim}8.0$, and also shaking culture was effective for it. The addition of glucose and peptone were effective for the degradation of PCB-42, but metal ions were not effective.

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Decontamination of PCBs by Hybrid Adsorption/Regeneration on Granular Activated Carbon (입자상 활성탄의 흡착과 재생에 의한 PCBs 오염제거)

  • Hong, Yong Pyo;Choe, Jong Ha
    • Journal of the Korean Chemical Society
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    • v.46 no.2
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    • pp.117-124
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    • 2002
  • Counterflow oxidation was developed and evaluated for treatment of organics that adsorbed in/on granular activated carbon(GAC). This reaction is a method that destructs and removes organics adsorbed, at the same time, regenerates waste carbon, uti lizing a self-sustained flame which propagates itself ina direction counter to the oxygen flow. The results showed that the mass loss of carbon and flam temperature were strongly dependent on the flow rate of oxyen, adsorptive capability of regenerated carbon completely was recovered, as well as destrution and removal efficiency of thermally stable PCBs was achieved with the value of better than 99.99%.

Concentration Distribution of PBDEs and PCBs in Soil (토양 중 PBDEs와 PCBs의 농도분포)

  • Lee, Sung-Hee;Cho, Ki-Chul;Yeo, Hyun-Gu
    • Journal of Environmental Health Sciences
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    • v.35 no.6
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    • pp.510-516
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    • 2009
  • Polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) were measured in soil samples of Ansung in Kyonggi-province to investigate concentration distribution of PBDEs and PCBs. The 10 soil samples were collected using a stainless steel hand-held corer that was cleaned before and after each sample using hexane. Total concentration of PBDE and PCBs were 2,205.3 and 348.1 pg/g dry weight (DW) in soil sample, respectively. BDE-209 showed as the most abundant congener in soil samples which was related to imported amount and usage amount of deca-BDE technical mixture in Korea. Also, BDE-99, BDE-47, BDE-100 deposition in soil sample was higher than other congeners and was related to the imported and usage amount reported for penta-BDE technical mixture in Korea. Correlation coefficient between PBDE contribution and technical mixture formulation (Bromokal 70-5DE) were significant (r=0.91, p<0.01) which suggests the influence of sources in this technical mixtures.

Early-life exposure to endocrine disrupting chemicals associates with childhood obesity

  • Yang, Chunxue;Lee, Hin Kiu;Kong, Alice Pik Shan;Lim, Lee Ling;Cai, Zongwei;Chung, Arthur C.K.
    • Annals of Pediatric Endocrinology and Metabolism
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    • v.23 no.4
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    • pp.182-195
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    • 2018
  • Increasing prevalence of childhood obesity poses threats to the global health burden. Because this rising prevalence cannot be fully explained by traditional risk factors such as unhealthy diet and physical inactivity, early-life exposure to endocrine disrupting chemicals (EDCs) is recognized as emerging novel risk factors for childhood obesity. EDCs can disrupt the hormone-mediated metabolic pathways, affect children's growth and mediate the development of childhood obesity. Many organic pollutants are recently classified to be EDCs. In this review, we summarized the epidemiological and laboratory evidence related to EDCs and childhood obesity, and discussed the possible mechanisms underpinning childhood obesity and early-life exposure to non-persistent organic pollutants (phthalates, bisphenol A, triclosan) and persistent organic pollutants (dichlorodip henyltrichloroethane, polychlorinated biphenyls, polybrominated diphenyl ethers, per- and polyfluoroalkyl substances). Understanding the relationship between EDCs and childhood obesity helps to raise public awareness and formulate public health policy to protect the youth from exposure to the harmful effects of EDCs.

Levels of organochlorine pesticides and PCB congeners in Korean human tissues

  • Yoo, Young-Chan;Lee, Sang-Ki;Yang, Ja-Youl;Kim, Ki-Wook;Lee, Soo-Yeun;Oh, Seung-Min;Chung, Kyu-Hyuck
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.283.2-283.2
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    • 2002
  • Organochlorine pesticides and polychlorinated biphenyls (PCBs) have been used intensively in agriculture and industry for a long time. They belong to a group of contaminants whose occurrence in the environment is a serious concern to environmental chemists and toxicologists due to their resistance to degradation in the environment as well as their potential toxicity. Also. the lipophilic characteristics of these substances are responsible for their ability to bioaccumulate in tissues and organs rich in lipids of men and animals through food chain. Therefore, the measure of the levels of organochlorine pesticides and PCBs in human tissues are good markers in detemining the extent to exposure and evaluating the hazards. This study was preformed to compare concentrations of organochlorine pesticides(${\alpha}-BHC, {\beta}-BHC, {\gamma}-BHC, {\delta}-BHC$, p.p'-DDT,p.p'-DDD,p.p.'-DDE. endrin. dieldrin. aldrin) and seven marker PCBs(PCB nos. 28. 52. 101. 118. 138. 153. 180) in liver. kidney cortex, lung blood and adipose tissue collected at autopsies of 10men and 10 women using gas chromatography equipped with electron capture detector to express the data on a lipid adjusted basis. From the results, the significant differences in the levels of organochlorines of PCBs between sexes, districts where they had lived and ages were also investigated.

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Source Estimation and Concentration Levels of PCBs in Ambient Air of an Industrial Area (공단지역 대기 중 PCBs의 오염농도 및 발생원 추정)

  • Kim, Kyoung-Soo;Song, Byung-Joo;Park, Seok-Un;Kim, Jong-Guk
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.4
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    • pp.385-389
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    • 2005
  • To understand the pollution level by polychlorinated biphenyls (PCBs) in ambient air of industrial area, PCBs concentrations were measured at Sihwa and Banwol industrial region, Korea. The concentrations of total PCB and WHO-TEQ ranged from 2,080 to $5820\;pg/m^3$ (median value is 2,760) and from 0.19 to $1.01\;pgTEQ/m^3$ (median value is 0.42), respectively. In terms of homologues composition the fraction of highly chlorinated biphenyls(from hexa-CB to deca-CB) were higher than the air samples of other regions such as jeonju and yokohama area. The cluster analysis was conducted to study the relation between the air samples and sources such as incinerator flue gases and Aroclor samples. The isomer fractions in the homologue were used as input variables. Based on the results, the industrial ambient air samples were divided from source samples with long Euclidian distance. This suggest that the ambient air samples of Sihwa and Banwol were not on the influence of Aroclor and incinerators. Therefore, further investigation on systematical air monitoring will be required to estimate the sources of PCBs in the above industrial areas.

Risk Assessment of Polychrorinated Biphenyls (PCBs) through Food Intake for the Korean Population (식품 중 폴리염화비페닐 위해평가)

  • Paek, Ockjin;Suh, Junghyuk;Park, Heera;Oh, Keumsoon;Hong, Selyung;Lee, Hyunkyung;Kim, Meehye
    • Korean Journal of Food Science and Technology
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    • v.45 no.3
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    • pp.364-369
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    • 2013
  • Polychlorinated biphenyls (PCBs) have been studied during the past few decades because of their potential impacts on the environment and human health. PCBs are toxic environmental pollutants and persistent organic pollutants (POPs). This study was carried out to assess the dietary exposure and risk to PCBs for the general Korean population through food intake. Various samples (n=389) covering 28 kinds of food were collected from 5 cities in Korea. The PCB content was not detected-$182.4{\mu}g/kg$ (mean of $5.4{\mu}g/kg$) in the food. The mean dietary exposure of PCBs for the general population was 9.54 ng/kg bw/day with an intake of 0.19% of tolerable daily intake (TDI) ($5{\mu}g/kg$ bw/day). Therefore, the level of overall dietary exposure to PCBs for the Korean population through food intake is below the recommended TDI levels.

Comparison of the elution patterns for polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDDs/Fs) and dioxin-like polychlorinated biphenyls (PCBs) by manual open columns and automatic parallel LC columns (수동 및 자동화 액체 크로마토그래피 칼럼에 의한 PCDDs/Fs 및 다이옥신과 유사한 PCBs의 용출 패턴 비교)

  • Ahn, Yun Gyong;Shin, Jeoung Hwa;Yoo, Sun Young;Khim, Jeehyeong;Hong, Jongki
    • Analytical Science and Technology
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    • v.18 no.1
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    • pp.13-22
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    • 2005
  • The elution patterns of seventeen 2,3,7,8-substituted PCDDs/Fs and 12 dioxin-like PCBs were studied by both manual open columns and automatic parallel LC columns in cleanup procedure. PCDDs/Fs and non-ortho-PCBs from other mono-ortho-PCBs were separated on automatic LC column, whereas they were not separated on an open manual column. The elution study on two cleanup methods was carried out using the PAR solution of unlabeled congeners and checked the recovery of each congener. Total recoveries of cleanup fractionation were ranged between 61.9 ~ 96.0% for PCDDs/Fs and 70.4 ~ 79.0% for PCBs by manual open columns and 71.8 ~ 104.5% for PCDDs/Fs and 61.3-120.3% for PCBs by automatic parallel LC columns, respectively. Unfortunately, #169-HxCB and 1,2,3,7,8-PeCDD were not separated on DB-5MS capillary column. The ions of 1,2,3,7,8-PeCDD were selected at M/M+2 instead of M+2/M+4 suggested by EPA method 1613. It is possible to discriminate 1,2,3,7,8-PeCDD and PCB #169 in HRGC/HRMS analysis.

The Concentration Distribution and Source Identification of Polychlorinated Biphenyls in River Sediment (하천 퇴적물 중 PCBs 농도분포 및 발생원 해석)

  • Jin, Ronghu;Oh, Jung-Keun;Kim, Jong-Guk;Kim, Kyoung-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.11
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    • pp.995-1000
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    • 2010
  • To investigate the relationship between polychlorinated byphenyls (PCBs) sources and concentration level in sediment, total 63 sediment samples with three-time sampling at one site were measured at 21 sites in Nakdong River. As a result of analysis, total concentrations and toxic equivalent (TEQ) concentration of Dioxin-like PCBs were ranged from 3.0 to 6,600 pg/g-dry with a mean value of 440 pg/g-dry and