• 제목/요약/키워드: Polyamide fibers

검색결과 53건 처리시간 0.024초

Syntan 처리에 의한 폴리아마이드 섬유의 캐티온 염료 염착특성 (Dyeing properties of cationic dye on polyamide fibers using syntan treatment)

  • 박영민;김병순;손영아
    • 한국염색가공학회지
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    • 제19권1호
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    • pp.12-16
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    • 2007
  • Exhaustion increase using cationic dyes on polyamide fibers are not easy work due to the limited amounts of the functional end groups(-COOH) in the substrates. Therefore, to enhance dye exhaustion, polyamide fibers are required to be modified onto desired surface properties of the fibers using anionic bridging agent. In this study, synthetic tanning agent for pre-treatment finishing and cationic dye(berberine chloride) for dyeing of polyamide fibers were used. For surface modification, polyamide fibers were pre-treated with synthetic tanning agent at various concentrations and temperatures. The increased concentration and temperatures of synthetic tanning agents had resulted in exhaustion increase. The modified polyamide substrates skewed increased cationic dyeing exhaustions and the corresponding dyeing results from treated samples represented higher exhaustion properties than those of non-treated counterpart. The increased dyeing effects of cationic dye can be attributed to the supplied ionic interaction and electrostatic attraction sites on the surface of polyamide substrates.

CONTAINMENT PERFORMANCE EVALUATION OF PRESTRESSED CONCRETE CONTAINMENT VESSELS WITH FIBER REINFORCEMENT

  • CHOUN, YOUNG-SUN;PARK, HYUNG-KUI
    • Nuclear Engineering and Technology
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    • 제47권7호
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    • pp.884-894
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    • 2015
  • Background: Fibers in concrete resist the growth of cracks and enhance the postcracking behavior of structures. The addition of fibers into a conventional reinforced concrete can improve the structural and functional performance of safety-related concrete structures in nuclear power plants. Methods: The influence of fibers on the ultimate internal pressure capacity of a prestressed concrete containment vessel (PCCV) was investigated through a comparison of the ultimate pressure capacities between conventional and fiber-reinforced PCCVs. Steel and polyamide fibers were used. The tension behaviors of conventional concrete and fiber-reinforced concrete specimens were investigated through uniaxial tension tests and their tension-stiffening models were obtained. Results: For a PCCV reinforced with 1% volume hooked-end steel fiber, the ultimate pressure capacity increased by approximately 12% in comparison with that for a conventional PCCV. For a PCCV reinforced with 1.5% volume polyamide fiber, an increase of approximately 3% was estimated for the ultimate pressure capacity. Conclusion: The ultimate pressure capacity can be greatly improved by introducing steel and polyamide fibers in a conventional reinforced concrete. Steel fibers are more effective at enhancing the containment performance of a PCCV than polyamide fibers. The fiber reinforcementwas shown to bemore effective at a high pressure loading and a lowprestress level.

EVALUATION OF SEISMIC SHEAR CAPACITY OF PRESTRESSED CONCRETE CONTAINMENT VESSELS WITH FIBER REINFORCEMENT

  • CHOUN, YOUNG-SUN;PARK, JUNHEE
    • Nuclear Engineering and Technology
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    • 제47권6호
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    • pp.756-765
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    • 2015
  • Background: Fibers have been used in cement mixture to improve its toughness, ductility, and tensile strength, and to enhance the cracking and deformation characteristics of concrete structural members. The addition of fibers into conventional reinforced concrete can enhance the structural and functional performances of safety-related concrete structures in nuclear power plants. Methods: The effects of steel and polyamide fibers on the shear resisting capacity of a prestressed concrete containment vessel (PCCV) were investigated in this study. For a comparative evaluation between the shear performances of structural walls constructed with conventional concrete, steel fiber reinforced concrete, and polyamide fiber reinforced concrete, cyclic tests for wall specimens were conducted and hysteretic models were derived. Results: The shear resisting capacity of a PCCV constructed with fiber reinforced concrete can be improved considerably. When steel fiber reinforced concrete contains hooked steel fibers in a volume fraction of 1.0%, the maximum lateral displacement of a PCCV can be improved by > 50%, in comparison with that of a conventional PCCV. When polyamide fiber reinforced concrete contains polyamide fibers in a volume fraction of 1.5%, the maximum lateral displacement of a PCCV can be enhanced by ~40%. In particular, the energy dissipation capacity in a fiber reinforced PCCV can be enhanced by > 200%. Conclusion: The addition of fibers into conventional concrete increases the ductility and energy dissipation of wall structures significantly. Fibers can be effectively used to improve the structural performance of a PCCV subjected to strong ground motions. Steel fibers are more effective in enhancing the shear performance of a PCCV than polyamide fibers.

Heterobifunctional 반응성염료의 폴리아마이드 섬유에의 염착특성 (The Application of Heterobifunctional Reactive Dyes on Polyamide Fibers and Their Dyeing Properties)

  • 손영아;홍진표;김태경
    • 한국염색가공학회지
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    • 제15권5호
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    • pp.301-309
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    • 2003
  • Of the various types of dye that can be used to apply polyamide fibers, acid dyes and pre-metallised acid dyes are great in use so far. However, since these acid dyeings suffer from dye loss during laundering, recourse to an aftertreatment is usually necessary to achieve adequate fastness to washing. In the case of reactive dyes, the characteristically high washfastness of dyeings comes with the concomitant advantages of brightness and low environmental impact. Despite the obvious advantages, the commercialization of reactive dyes for polyamide fibers has not gained widespread success. In this context, the rewards for approach are likely to be considerable. Heterobifunctional reactive dyes were applied to polyamide fibers using various conditions. Optimum conditions and fixation were determined. The forms in which the vinylsulphone and hydrolyzed moieties were examined using HPLC-Mass. In addition, it was found that the extent of the washfastness secured, in terms of both change in color and staining of adjacent multifiber was being acceptable.

용매 환경에서의 폴리아미드 고분자 재료의 자체확산과 유변학적인 특성 (Self Diffusions and Rheological Properties of Polyamide Polymer Materials in Various Solvents)

  • 김남정
    • 한국응용과학기술학회지
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    • 제36권4호
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    • pp.1050-1059
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    • 2019
  • 비결정성 영역에서의 유동단위의 고찰을 위하여 유동 파라메타와 결정크기로부터 폴리아미드 섬유고분자 물질의 자체확산, 홀 부피, 유동 열역학 파라메타 등을 계산하였다. 폴리아미드 섬유의 응력완화 실험은 용매기를 부착한 인장 시험기를 사용하여 여러 온도의 공기, 증류수, 산, 염기 용액에서 실행하였다. REM 모델의 이론적인 응력완화 식에 응력완화 실험 결과를 적용하여 여러 가지 유동 파라메타를 계산하였다. 이들 시료의 유동 파라메타는 완화 스펙트럼, 자체확산, 점도 및 유동 활성화 에너지와 직접적인 연관을 갖는 것으로 규명되었다.

라카제를 이용한 폴리아미드 섬유의 효소 가공 (Laccase Treatment on Polyamide Fabrics)

  • 서혜영;김혜림
    • 한국의류학회지
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    • 제35권10호
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    • pp.1264-1270
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    • 2011
  • This study is to optimize the conditions for the treatment of polyamide fabrics using laccase. The pH, temperature, treatment time, and concentration were varied; their effects were evaluated by measuring the number of primary amide groups by the uptake of an acid dye measured by K/S of dyed polyamide fibers. The hydrophilicity of the fabrics was evaluated in terms of moisture regain and wettability. The effects of the mediator, ABTS, on the laccase activity were also evaluated. The optimal treatment conditions were identified as a pH of 4.5, temperature of $30^{\circ}C$, treatment time of 6 hours, and concentration of 10% of the weight of the fabric (o.w.f.). ABTS facilitated the activity of laccase on the polyamide fabrics. Voids and cracks on the surfaces of the laccase-treated polyamide fabrics were responsible for improved wettability. The results proved that laccase treatment improved the hydrophilicity of polyamide fibers without decreasing their strength.

변형 속도에 따른 후크형 강섬유 및 폴리아미드섬유보강 시멘트 복합체의 압축 및 인장강도 특성 (Strain Rate Effect on the Compressive and Tensile Strength of Hooked Steel Fiber and Polyamide Fiber Reinforced Cement Composite)

  • 김홍섭;김규용;이상규;손민재;남정수
    • 한국구조물진단유지관리공학회 논문집
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    • 제21권3호
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    • pp.76-85
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    • 2017
  • 본 연구에서는 유압식 급속재하 시험 장치를 제작하여 변형 속도에 따른 후크형 강섬유 및 폴리아미드 섬유보강 시멘트 복합체의 압축강도 및 인장강도 특성을 평가하였다. 그 결과, 변형 속도가 증가함에 따라 압축강도, 최대 응력 점에서의 변형 및 탄성계수는 증가하였으며, 섬유 종류 및 혼입률은 변형 속도에 의한 압축강도의 영향은 크지 않았다. 본 연구에서 평가된 압축강도의 DIF는 CEB-FIP model code 2010에 비해 상회하였으며, ACI-349의 예측값과 유사한 경향이 나타났다. 인장특성의 경우에도 변형 속도가 증가함에 따라 인장강도와 변형능력이 크게 향상되었다. 후크형 강섬유보강 시멘트 복합체는 변형 속도가 증가함에 따라 섬유와 매트릭스의 부착력이 증가하는 것에 의해 인장강도와 변형능력이 크게 향상되었으며, 섬유가 매트릭스로부터 인발되는 파괴 특성이 나타났다. 한편, 폴리아미드 섬유보강 시멘트 복합체의 경우 섬유와 매트릭스의 부착력이 크기 때문에 섬유가 매트릭스로부터 인발되지 않고 끊어지는 파괴 특성이 나타났으며, 폴리아미드 섬유보강시멘트 복합체의 인장특성에 대한 변형 속도 효과는 섬유의 인장강도에 큰 영향을 받는 것으로 판단되었다. 이러한 결과로부터 폴리아미드 섬유보강 시멘트 복합체의 인장강도에 대한 변형 속도의 효과는 후크형 강섬유의 부착력에 대한 민감도 보다 큰 것으로 사료된다.

변형속도에 따른 폴라아미드 섬유 및 후크형 강섬유 보강 시멘트 복합체의 인장특성 (Tensile Properties of Polyamide Fiber and Hooked Steel Fiber Reinforced Cementitious Composites by Strain Rate)

  • 이상규;김규용;황의철;손민재;백재욱;남정수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2018년도 추계 학술논문 발표대회
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    • pp.73-74
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    • 2018
  • In this study, it evaluate the tensile properties of polyamide fiber reinforced cementitious composite and hooked steel fiber reinforced cementitious Composites by strain rate. Polyamide fiber reinforced cement composites (PAFRCC) and Hooked Steel Fiber Reinforced Cement Composite(HSFRCC) were fabricated. Each specimen was reinforced with 1.0 and 2.0vol% fiber. The length of the reinforced fiber was 30 mm for both fibers, and the tensile test specimen was made in dumbbell shape. As a result, the tensile strength of fiber in polyamide fiber and the mechanical bonding between fiber and matrix in hooked steel fiber are considered to be the main factors affecting tensile behavior of fiber reinforced cement composite.

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하이브리드 유기섬유 보강 콘크리트의 제조 및 휨성능 평가 (A Processing and Flexural Performance Evaluation of Hybrid Organic Fiber Reinforced Concrete)

  • Jeon, Chanki;Jeon, Joongkyu;Shim, Jaeyeong
    • 한국재난정보학회 논문집
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    • 제13권2호
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    • pp.213-220
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    • 2017
  • 일반적으로 유기섬유는 섬유 자체의 인장강도 및 탄성계수는 작지만, 내화성 및 내부식성이 우수하고, 콘크리트의 균열 제어 및 내충격 성능 향상에 효과적인 섬유이다. 따라서, 유기섬유는 콘크리트용 보강 섬유로서의 적용성이 매우 높은 재료이다. 본 연구에서는 폴리아미드(PA)섬유와 고강력의 폴리에스터(PET)섬유를 혼입한 하이브리드 유기섬유를 개발하였으며, 하이브리드 유기섬유를 혼입한 섬유보강 콘크리트의 휨성능 시험을 통해 하이브리드 유기섬유 보강 콘크리트의 에너지 흡수능력을 평가하고자 한다.

다발형 폴리아미드섬유 보강 콘크리트의 휨거동에 관한 실험적 연구 (A Experimental Study on the Flexural Behavior of Bundle Type Polyamide Fiber Reinforced Concrete)

  • Jeon, Chan Ki;Jeon, Joong Kyu
    • 한국재난정보학회 논문집
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    • 제10권1호
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    • pp.61-70
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    • 2014
  • 일반적으로 건설재료 용도로 많이 사용되고 있는 유기섬유 보강 콘크리트는 섬유 자체의 인장강도 및 탄성계수는 낮지만, 휨거동, 균열에 대한 저항성 및 충격저항성 등의 특성은 우수하며, 내화학성이 뛰어나고 부식의 우려가 없는 것으로 널리 알려져 있다. 최근 해외에서는 유기섬유 보강재를 터널 숏크리트와 프리캐스트 세그먼트 라이닝, 교량 슬래브 및 PC제품 분야에서 일부 활용되고 있으며, 그 종류 또한 다양하다. 본 연구에서는 다발형 폴리아미드섬유를 혼입한 콘크리트의 휨거동 특성을 ASTM C 1609 및 KS F 2566에 준하여 하중-처짐 관계를 도출하여 유기섬유 보강 콘크리트의 적용 가능성을 검토하였다.