• Title/Summary/Keyword: PolyPhenol

검색결과 71건 처리시간 0.023초

Effect of Surface-Modified Poly (4-vinyl phenol) Gate Dielectric on Printed Thin Film Transistor

  • Sung, Chao-Feng;Tsai, Hsuan-Ming;Lee, Yuh-Zheng;Cheng, Kevin
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
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    • pp.1771-1773
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    • 2007
  • Surface modification of the gate dielectric has a strong influence on the performance of printed transistors. The surface modification occurs between the gate dielectric and semiconductor. The printed transistor with evaporated vanadium pentoxide ($V_2O_5$) modification exhibits a mobility of $0.2cm^2\;V^{-1}\;s{-1}$ and a subthreshold slope of 1.47 V/decade.

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영가금속 및 촉매를 이용한 방향족 유기오염물의 환원

  • 김영훈;도혜현;신원식;하태욱;최상준
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2003년도 추계학술발표회
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    • pp.176-179
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    • 2003
  • The objective of this study was to investigate reductive dechlorination of aromatic hydrocarbons using zero valent metals (ZVMs) and catalysts as reactive materials for permeable reactive barriers (PRBs). A group of small aromatic hydrocarbons such as monochlorophenols, phenol, benzene were readily reduced with palladium catalyst and zero valent iron. Poly-aromatic hydrocarbons (PAHs) were also tested with the catalysts and zero valent metal combinations. The aromatic rings were reduced and partly reduced PAHs were found as the daughter compounds. Current preliminary study implicate that ZVMs and modified catalysts can be successfully applied for PRBs which currently applicable for halogenated organic compounds and some inorganic contaminants including chromium(Ⅵ) and nitrate.

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An Efficient Synthesis of Poly-Substituted Phenols and Pyridines from Morita-Baylis-Hillman Acetates and Diethyl Oxalacetate

  • Yu, Jin;Kim, Ko Hoon;Lee, Hyun Ju;Kim, Jae Nyoung
    • Bulletin of the Korean Chemical Society
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    • 제34권10호
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    • pp.3027-3032
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    • 2013
  • Various phenol derivatives were synthesized in a one-pot reaction from MBH acetates and sodium diethyl oxalacetate via a [4C+2C] cyclization protocol. In addition, some pyridine derivatives could also be synthesized using the same starting materials, by isolating the $S_N2^{\prime}$ reaction intermediate and performing the cyclization with $NH_4OAc$.

Hyperbranched Poly(aryl ester)s as Developer Materials for Thermal Printing System

  • Jang, Yeon-Im;Choi, Won-Ho;An, Byeong-Kwan
    • Bulletin of the Korean Chemical Society
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    • 제34권4호
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    • pp.1225-1231
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    • 2013
  • A novel class of hyperbranched polyesters, HPpEP and HPmEP, were prepared via a facile one-pot polymerization of a phloroglucinol (as a $B_3$ monomer) with a phthaloyl dichloride (as an $A_2$ monomer) for replacing a problematic BPA developer in thermal printing system. The resulting polymers, HPpEP and HPmEP, had highly branched structures and met well the requirements for high performance developer materials such as colorlessness, easy and inexpensive synthesis, high thermal stability, etc. In addition, these polymers exhibited an efficient reaction with leuco dyes (ODB-2) for a coloring process by releasing protons from linear and terminal phenol groups of polymers when heated.

Effect of Characteristic of the Organic Memory Devices by the Number of CdSe/ZnS Nanoparicles Per Unit Area Changes

  • 김진우;이태호;노용한
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.388-388
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    • 2013
  • 현대 사회에서 고집적 및 고성능의 전자소자의 필요성은 지속적으로 요구되고 있으며, 투명하거나 플렉서블한 특성의 필요성에 따라 이에 대한 기술개발이 이루어지고 있다. 특히, 이러한 특성을 만족하면서 대면적화 및 저온 공정의 특성을 지니는 유기물 반도체가 주목받고 있고, 이를 이용하여 OLED (Organic Light Emitting Diode), OTFT (Organic Thin Film Transistor)와 같은 다양한 유기물 반도체 소자가 개발되고 있다. 대표적인 예로는이 있다. 유기물 반도체 소자의 특성을 이용한 메모리 소자 또한 연구 및 개발이 지속되고 있으며, 유연성과 낮은 공정가격 등의 특성을 가지는 나노 입자들이 기존 Floating Gate의 대체물로 각광받고 있다. 본 논문에서는 MIS (Metal/Insulator/Semiconductor) 구조를 제작하고, Insulator 내부에Core/Shell 구조를 가지는 CdSe/ZnS 나노 입자를 부착하여 메모리 소자의 특성 확인 및 단위 면적당 개수에 따른 특성 변화를 확인하고자 하였다. 합성된 PVP (Poly 4-Vinyl Phenol)를 Insulator 층으로 사용하였으며 단위 면적당 나노 입자의 개수를 조절하여 제작된 MIS 소자를 Capacitance versus Voltage (C-V) 측정을 통하여 변화특성을 확인하였다.

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Semiconducting ZnO Nanofibers as Gas Sensors and Gas Response Improvement by $SnO_2$ Coating

  • Moon, Jae-Hyun;Park, Jin-Ah;Lee, Su-Jae;Zyung, Tae-Hyoung
    • ETRI Journal
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    • 제31권6호
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    • pp.636-641
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    • 2009
  • ZnO nanofibers were electro-spun from a solution containing poly 4-vinyl phenol and Zn acetate dihydrate. The calcination process of the ZnO/PVP composite nanofibers brought forth a random network of polycrystalline wurtzite ZnO nanofibers of 30 nm to 70 nm in diameter. The electrical properties of the ZnO nanofibers were governed by the grain boundaries. To investigate possible applications of the ZnO nanofibers, their CO and $NO_2$ gas sensing responses are demonstrated. In particular, the $SnO_2$-deposited ZnO nanofibers exhibit a remarkable gas sensing response to $NO_2$ gas as low as 400 ppb. Oxide nanofibers emerge as a new proposition for oxide-based gas sensors.

에어컨 전선 마감 Tape 변색 및 냄새에 관한 고장분석 사례 (Failure Analysis of the Masking Tape for Airconditioner)

  • 서성미;최동준;박상득
    • 한국신뢰성학회지:신뢰성응용연구
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    • 제5권4호
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    • pp.405-412
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    • 2005
  • In this paper, we verified the failure mechanism of the discolored masking tape wrapped around the wire and studied an improved case study as well. Masking tapes are poly(Vinylchloride-co-Methyl methacrylate) (PVC) and the wire connecting with indoor/outdoor components of the air conditioner is chloroprene(CR). The masking tape under. the ultraviolet ray was accelerated to discolor fivefold. The results determined reveal the discoloration of masking tapes as an elution of the additives, dephenyl Amine series antioxidants, in the connecting wire. When changed dephenyl Amine series to phenol series, we found that the degree of discoloration was dramatically decreased. Due to stink of Thiourea and Thiuram monosulfide, as accelerators in CR wire, we controlled the vulcanization temperature and time without using these accelerators and could get the wire not to smell bad with the equal mechanical properties.

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Trihydric Phenol계 Photoresist의 합성과 그 감광 특성 (Synthesis and Photocharacteristics of Trihydric Phenol Photoresist)

  • 홍의석;고재용;박홍수
    • 한국응용과학기술학회지
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    • 제13권1호
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    • pp.47-54
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    • 1996
  • Cinnamoyl ester(PGEFC) of poly(phloroglucinol-formaldehyde) glycidyl ether which has photosensitive functional group was prepared to apply to photoresist. Photosensitivity of PGEFC was estimated by the solubility difference in organic solvent before and after exposure to light. The yield of residual film was calculated by immersing the sample-coated quartz plates in the solvent which was used in coating. The yield of the residual film which was closely related to the sensitivity of the film, was affected by the degree of polymerization of the backbone resin, sensitizers and their concentration. The sensitivity was depended upon the degree of polymerization. Most of effective sensitizer for PGEFC among the sensitizers was 2, 6-dichloro-4-nitroaniline.

Flexural Modulus of Larch Boards Laminated by Adhesives with Reinforcing Material

  • Injeong LEE;Weontae OH
    • Journal of the Korean Wood Science and Technology
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    • 제51권1호
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    • pp.14-22
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    • 2023
  • Economical use of larix (larch) boards (grade 3) in industries is lower than that of imported hardwood; thus, studies have been conducted toward performance improvement of larix boards. Herein, flexural modulus of larix board samples laminated with wood adhesives polyurethane resins, poly (vinyl acetate) resins, phenol-resorcinol-formaldehyde resins, melamine-formaldehyde resins, and urea-formaldehyde resins was compared with that of the samples bonded with adhesives reinforced with mesh-type basalt fibers. Moreover, the flexural moduli of the laminated samples bonded by mesh-type basalt fibers were compared with those of reinforced samples. The results showed that boards laminated with polyurethane and urea-formaldehyde resin adhesives had higher flexural modulus than those without the lamination. In particular, the increase in the flexural modulus was relatively significant for the 2- and 3-ply board structures laminated with polyurethane adhesives compared to those with reinforcement. The 3-ply board structure without reinforcement had the highest flexural modulus when the urea-formaldehyde resin adhesive was used.

Phenylene Diimide 단위를 포함한 방향족 Poly(o-hydroxyamide)s의 합성 및 열적 특성 (Synthesis and Thermal Properties of Aromatic Poly(o-hydroxyamide)s Containing Phenylene Diimide Unit)

  • 이응재;윤두수;최재곤
    • 한국산학기술학회논문지
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    • 제14권11호
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    • pp.6029-6038
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    • 2013
  • 본 연구에서는 높은 용융점과 유리 전이 온도를 갖는 PBO의 구조 변화를 통해 가공성을 향상시키고자 한다. 일련의 방향족 poly(o-hydroxyamide)s(PHAs)가 3,3'-dihydroxybenzidine과 2,2-bis(3-amino-4-hydroxyphenyl) hexafluoropropane을 포함하는 두 타입의 bis(o-amino-phenol)s과 diimide 단위를 갖는 이염기산들과의 직접 중축합에 의해서 합성되었다. PHAs의 특성은 FT-IR, $^1H$-NMR, DSC, TGA 등을 이용하여 조사하였다. PHAs 고유 점도는 $35^{\circ}C$ 의 DMAc 용액에서 측정하였으며 0.34~0.75 dL/g의 값을 보였다. o-phenylene 단위가 도입된 PHA 1과 6F-PHA 1은 NMP 등 비양자성 용매에 잘 용해되었지만, p-phenylene 단위가 도입된 PHA 3은 LiCl의 첨가에도 완전히 용해되지 않았다. 6F-PHAs은 6F-PHA 3을 제외하고 실온에서 비양자성 용매에 잘 용해되었고, PHAs 보다 더 좋은 용해도를 보였다. PBOs은 황산에 부분적으로 용해될 뿐 다른 용매에는 전혀 용해되지 않았다. DSC에 의해 측정된 PBOs의 유리전이온도(Tg)는 비교적 높은 306~$311^{\circ}C$의 범위를 보였다. PHA 3과 6F-PHA 3의 최대분해온도와 Char 수득률은 $658^{\circ}C$$653^{\circ}C$, 62.6%와 62.1%로 가장 높은 값들을 보였다.