• Title/Summary/Keyword: Poly vinyl chloride (PVC)

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Synthesis and Charcterization of UV-curable Polyurethane Acrylates Coating Composition for PVC Tiles (PVC 바닥상재용 광경화형 폴리우레탄 아크릴 수지의 합성 및 특성고찰)

  • Zhao, Hong;Ha, Jin-Wook
    • Proceedings of the KAIS Fall Conference
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    • 2009.12a
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    • pp.80-83
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    • 2009
  • Application of UV curing technique for poly vinyl chloride (PVC) floor tiles coating has improved the quality of PVC floor. Various formulations including acrylated oligomers based on a polyurethane were blended with reactive monomers, photoinitiators and other additives. The used oligomers are commercial aliphatic urethane acrylates. Thin films were prepared on PVC tiles by bar coating with different formulations using UV radiation. The coating resins were characterized by FTIR. The properties of UV-cured films such as gloss grade and adhesion were examined. The properties of UV-cured films dependent on the influence of composition and processing conditions was studied. The investigation was conducted to achieve an optimal domain of composition and desired coating effect.

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Preparation of Silver Nanoparticles with Various Morphology Using Amphiphilic Graft Copolymer Membranes (양쪽성 가지형 공중합막을 이용한 다양한 모양의 은 나노입자 제조)

  • Seo, Jin-Ah;Choi, Jin-Kyu;Ahn, Sung-Hoon;Yeon, Seung-Hyeon;Kim, Jong-Hak
    • Membrane Journal
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    • v.20 no.2
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    • pp.169-172
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    • 2010
  • Silver ions of poly(vinyl chloride)-g-poly(styrene sulfonic acid) (PVC-g-PSSA) graft copolymer were reduced to form silver nanoparticles under thermal condition ($80^{\circ}C$). We were successful in synthesizing silver nanoparticles with various morphologies by changing reaction time. At short reaction times (~1 h), silver nanoparticles with 5 nm in size were formed without disrupting a microphase-separated structure of graft copolymer. At medium reaction times (~5 h), silver nanoparticles were aggregated to form large clusters ranging 30~50 nm in size. At much longer reaction times (~18 h), hurricane-like silver clusters were observed due to strong particle aggregation.

A Study of Characteristics of Weft Used in Wig Manufacturing (가발에 사용되는 원사의 특성 연구)

  • Lim, Sun-Nye
    • Textile Coloration and Finishing
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    • v.24 no.3
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    • pp.204-212
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    • 2012
  • This study was used a thermogravimetric analyzer to determine thermal characteristics, a hair analysis system to examine morphological changes of wefts-human hair, poly vinyl chloride(PVC) and polyethylene terephthalate (PET)-used in manufacturing wigs. According to a flammability test on human hair and synthetic wefts for wigs, the best results were observed in human hair. According to a thermal test, PET was the best in terms of thermal stability. Also good tensile strength was observed as well. In a scanning electron microscope observation, no human hair scale layer was found because of chemical treatment. In the PVC sample, homogeneous unevenness was observed. Due to a lack of human hair supply and increase in its price, recently, PET weft has emerged as a great substitution for human hair. Because it can be curled using an electric curling device and is more efficient than the conventional non-flammable material PVC in terms of thermal resistance, it will become the next-generation weft for wigs.

Morphology and Mechanical Properties of Waste PVC Blends (II)- The Relationship between Rheology and Morphology of Waste PVC/PE Blends (폐폴리(염화 비닐)계 고분자 블렌드의 구조 및 물성 연구(II)-폐폴리(염화 비닐)/폴리에틸렌 고분자 블렌드의 형태학 및 유변학적 거동)

  • 유영재;박재찬;원종찬;최길영;이재흥
    • Polymer(Korea)
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    • v.28 no.6
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    • pp.460-467
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    • 2004
  • The polymer blends of waste poly(vinyl chloride) (RPVC) and waste polyethylene (RPE) were prepared by melt mixing. Their morphologies and rheological properties were investigated and torque changes were also measured. Comparing the torques calculated by the log additivity rule with measured torque changes, the polymer blends showed the large negative deviation behavior (NDB) due to their incompatibility. The shear viscosities of the blends decreased with increasing shear rates, showing shear thinning behavior. The shear viscosity of the blends with compatibilizer was larger than that of the blends without compatibilizer. SEM micrographs of the strands after measurement showed that the domain size of the blends was slightly enlarged with increasing the shear rate. Also, RPVC domain size was larger in the core-sections of the strands from capillary viscometer than in the surface region.

Removal of PVC from Granular Plastic Mixture by Using Air Table (Air Table을 이용한 입상플라스틱 혼합물로부터 PVC의 건식분리)

  • ;Hiroki Yotsumoto
    • Resources Recycling
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    • v.10 no.6
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    • pp.35-42
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    • 2001
  • A study was conducted in order to remove Poly vinyl chloride (PVC) from granular plastic mixture by using Air Table. The motion of plastic particle on Air Table was investigated, and separation test on the plastic mixture with the mixing ratio of PVC 10% and PE 90% was conducted. At the optimum condition obtained from this study, that is frequency of 9.2Hz, air velocity of 1.05 m/sec, End-slope of $7.5 ^{\circ}$, Side-slope of $1^{\circ}$, Feeding speed of 450 g/min, etc., we could separate the PE-PVC mixture to PE (99.96% grade and 98.9% yield) and PVC (88.7% grade and 99.6% yield).

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Synthesis and Characterization of UV-curable Polyurethane Acrylates Coating Resins for PVC Tiles (PVC 바닥상재용 광경화형 폴리우레탄 아크릴 수지의 합성 및 특성고찰)

  • Zhao, Hong;Ha, Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.5
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    • pp.1773-1777
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    • 2010
  • The Application of UV curing technique for poly (vinyl chloride) (PVC) floor tiles coating has improved the quality of PVC floor. Several formulations were made including acrylated oligomers based on a polyurethane were blended with reactive monomers, photoinitiators and other additives. The used oligomers are commercial aliphatic urethane acrylates. Thin films were prepared on PVC tiles by bar coating with different formulations using UV radiation. The coating resins were characterized by FTIR. The properties of UV-cured films such as gloss and adhesion were examined. The properties of UV-cured films dependent on the influence of composition and processing conditions was studied.

Properties of Paint Protection Film Containing Poly(urea-urethane)-based Self-Recovery Coating Layer (Poly(urea-urethane) 자기복원 코팅층을 가진 도장 보호필름 물성 연구)

  • Minseok Song
    • Journal of Adhesion and Interface
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    • v.24 no.2
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    • pp.69-75
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    • 2023
  • Recently, the application of paint protection films (PPFs) for automobiles having a self-recovery coating layer has been grown up. In this study, we report the evaluation results on the basic physical properties of a poly(vinyl chloride)- based PPF containing poly(urea-urethane) hybrid self-recovery coating layer. Depending on the main chemical composition and the thickness of poly(urea-urethane)-based coating layer for PPF, the self-recovery performance by an optical microscope and the stain resistance through color difference value are measured. To improve the surface properties and show its easy-cleaning effect against the polluted things, silicone-modified polyacrylate is introduced to the self-recovery coating composition. The contact angle of water on the coated surface is confirmed to show its hydrophobic surface. Finally, accelerated weathering test of paint protection film with poly(urea-urethane) hybrid coating layer is performed to check the possibility of discoloration and deformation due to long-term exposure on harsh condition.

Gas-Sensing Membrane Electrodes for the Determination of Dissolved Gases (III). Continuous-Automated Determination of Nitrite Ion Using a New Tubular PVC Membrane Type of Selective Electrode Nitrate (溶解氣體 分析用 氣體感應膜 이온選擇性 電極 (第 3 報). 새로운 管形 PVC膜 질산이온 選擇性 電極을 이용한 아질산이온의連續·自動化 定量)

  • Lee Heung Lark;Yun Jong-Hoon
    • Journal of the Korean Chemical Society
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    • v.35 no.1
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    • pp.51-58
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    • 1991
  • A new tubular poly(vinyl chloride) membrane type of nitrate selective electrode was prepared and its characteristics were evaluated. The response slope, detection limit, and response time (t$_{99}$) under the optimum membrane composition (5${\%}$ aliquat-NO$_3$ solution + 32${\%}$ poly(vinyl chloride) + 63${\%}$ dibutyl sebecate) of the electrode were 58.5 ${\pm}$ 0.1 mV/decade, 2.0 ${\times}$ 10$^{-5}$ M, and 25 seconds, respectively. The nitrite ion was determined by the continuous-automated method using the new electrode. 10$^{-2}$ M phosphate buffer solution (pH 7.6) was used as a recipient solution. And also hydrogen peroxide (0.3${\%}$) was added to the recipient as an oxidant. The linear response range and response range and response slope for the standard nitrite solution under the optimum condition of this electrode system were 8.0 ${\times}$ 10$^{-5}$ M ∼ 5.0 ${\times}$ 10$^{-2}$ M and 56.8 ${\pm}$ 0.2 mV/decade, respectively.

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Optimal Immobilization of Penicillinase for Ion-selective Electrode

  • Hur, Moon-Hye;Kang, Hee-Jin;Min, Hye-Young;Lee, Ji-Yeun;Lee, Ki-Hyun;Ahn, Moon-Kyu
    • Archives of Pharmacal Research
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    • v.20 no.1
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    • pp.68-71
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    • 1997
  • Penicillin sensor was prepared by immobilizing penicillinase (Pcase) on $H^{+}$-selective carboxylated poly (vinyl chloride) (PVC-COOH) membrane or cellulose filter membrane. The immobilization techniques are as follows. Pcase was immobilized with GTH on $H^{+}$-selective PVC-COOH membrane or some amount of BSA was dropped on that membrane. Another method to make immobilization is to mix type I Pcase with GTH and drop on a cellulose filter membrane. According to immobilization techniques, there were some differences in response properties of enzyme electrodes, however, all electrodes responded to Pcase-resistant penicillin derivatives. Pcase immobilized on cellulose filter membrane with $H^{+}$-selective PVC membrane eletrode was more stable and more sensitive to penicillinase-resistant penicillin derivatives than any other immobilization techniques.

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Mechanical Behaviors of Electrospun Non-woven of PVC/PU blend (전기방사된 PVC/PU의 기계적 거동)

  • Lee, Bong-Seok;Lee, Keun-Hyung;Kim, Hak-Yong;Pyo, Soo-ho;Park, Sun-Woong
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.269-270
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    • 2003
  • Thermoplastic polyurethane is a engineering plastic with elasticity, abrasion resistance and good resistance to oil, grease and many solvents. Characteristics of poly(vinyl chloride) (PVC) are good general chemical resistance, excellent weatherablility, good insulate. properties, and self-extinguishing or flame resistance, etc. So it is used in widespread industrial fields[2]. (omitted)

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