• Analytical Science and Technology
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• v.8 no.1
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• pp.79-84
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• 1995

Ion-selective poly(vinyl chloride) membrane electrodes for the determination of the anticholinergic drug alverine in pure substances is described. Ion-pair complex of alverine with anionic counter ion acid red 97 is investigated as electroactive compound for the electrode membrane. On the optimal composition of membrane, its slope was 55.35mV/decade, relative standard deviation was 0.61 and lower limit of linear range was $1.0{\times}10^{-5}M$. The observed potentiometric selectivity coefficient was -2.625 toward methylephedrine and -2.216 toward histidine. We can got the stable potential at pH 7.0~4.0. Response time was 20~30 seconds for solutions${\leq}10^{-4}M$, about 10 seconds for solutions ${\geq}10^{-4}M$ of these compounds.

• Journal of Embryo Transfer
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• v.25 no.4
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• pp.207-213
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• 2010

Thousands of new chemicals have been introduced to environment during last decades. Many of them and common consumer products have been shown to be the endocrine disrupting chemicals. One such chemical group is the phthalates, used in soft poly vinyl chloride (PVC) material and in a huge number of consumer products. The prevalence of these modem chemicals have a remarkable increase. Approximately 3.5 million tons of the main phthalate, di-(2-ethylhexyl) phthalate (DEHP), are produced annually worldwide and indeed, DEHP is considered a ubiquitous environmental contaminant. It has been demonstrated that high doses of phthalate can adversely affect adult and developing animals. In this review, we critically discuss the conclusions of recently original research papers and provide an overview of studies on reproductive disrupting effects of phthalates. In addition, we review the reproductive toxicity data of phthalates in some in vitro research and in both male and female reproductive systems in experimental and domestic animals. Finally, we point out some critical issues that should be addressed in order to clarify the implication of phthalates for human reproduction.

• The Journal of the Acoustical Society of Korea
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• v.24 no.8
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• pp.441-446
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• 2005

This paper presents the changes of acoustic scattering pattern from a single cylinder and two identical cylinders in both theoretical calculations and experimental measurements. Bi-static scattering pattern by single cylinder and two parallel cylinders (length 2m, radius 30mm) was measured in $5m\times5m\times5m$ water tank using high frequency projector (120 kHz) and hydrophone. The results show similar agreement between experiment and theory. In case of single cylinder scattering. omni-directional pattern was observed in backward but there are fluctuations or target strength in forward. Interference between each cylinder's scattering fields produce fluctuations of target strength in all directions of two cylinders.

• Journal of the Korean Applied Science and Technology
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• v.30 no.2
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• pp.258-263
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• 2013

New conducting polymers containing heterocyclic ring with carbazole, EDOT and benzobisthiazole were synthesized and characterized by organic spectroscopic methods. Potentiometric ion-selective membrane electrodes (ISMEs) have been extensively used for ion analysis in clinical, environmental, and industeial fields owing to its wide response range (4 to 7 orders of magnitude), no effect of sample turbidity, fast response time, and ease of miniaturization. Considerable attention has been given to alternative use of room temperature vulcanizing (RTV)-type silicone rubber(SR) owing to its strong adhesion and high thermal durability. Unfortunately, the high membrane resistance of SR-based (ISMs)(2 to 3 higher orders of magnitude compared to those of poly(vinyl chloride)(PVC)-based ones) has significantly restricted its application. Herein we demonstrate a new method to reduce membrane resistance via addition of new conducting polymer into the SR-based ISMs.

• Journal of Food Hygiene and Safety
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• v.20 no.4
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• pp.277-283
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• 2005

A plasticizer is a substance which is added to a material to improve its processability, flexibility and stratchability. Phthalates and adipates are the most frequently used plasticizers of poly(vinyl chloride) (PVC). However, they can migtate into food from PVC food packaging, and some of them are especially suspected as endocrine disruptors. In this study, Simultaneous analysis of 13 phthalates and 9 adipates were carried out by dual-column gas chromatography system equipped wi two FID detectors for rapid confirmation and quantification. The Proposed method was validated with > 0.993 of linearity in the ranges of 10-500 mg/l, < $3.5\%$ RSD of reproducability in 10 inter-days sample preparations, and > $98.1\%$ of recoveries for all the plasticizers. DEHA was detected in all the 3 PVC wraps at levels of 176.9-198.5mg/g. Among the 51 samples of PVC gaskets, the targeted plasticizers were detected in 41 samples. Of these plasticizer detected samples,40 contained DIDP at the levels of 157.3-374.7 mg/g and one contained DMP at the levels of 165.6 mg/g. Also, some plasticizers were detected in other packaging materials such as PET, PP, PE, Pulp. But it might be attributed to contamination in manufacturing.

• Composites Research
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• v.31 no.4
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• pp.133-138
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• 2018

Polymer foams were used to fill the void in the structure in addition to flame retardant and heat insulation. Polymer foams such as polyurethane, polyisocyanurate, poly(vinyl chloride), polyethylene terephthalate were used to weight lighting materials. In this study, epoxy foam was used to improve mechanical properties of polymer foam. Acid anhydride type hardener reacts with polyol. Using this phenomenon, if blowing agent was added into epoxy resin using acid anhydride type hardener, formation and compressive properties of epoxy foam was studied. Formation of polymer foam was compared with type of blowing agent and concentration of blowing agent via compressive test. As these results, optimized condition of epoxy foam was found and epoxy foam had better compressive property than other polymer foam.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.26 no.2
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• pp.147-158
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• 2016

Objectives: The objective of this study was to evaluate the assessment of exposure to welding fume and heavy metals among construction welders. Methods: Activity-specific personal air samplings(n=206) were carried out at construction sites of three apartment, two office buildings, and two plant buildings using PVC(poly vinyl chloride) filters with personal air samplers. The concentration of fumes and heavy metals were evaluated for five different types of construction welding jobs: general building pipefitter, chemical plant pipefitter, boiler maker, ironworker, metal finishing welder. Results: The concentration of welding fumes was highest among general building pipefitters($4.753mg/m^3$) followed by ironworkers($3.765mg/m^3$), boilermakers($1.384mg/m^3$), metal finishing welders($0.783mg/m^3$), chemical pipefitters($0.710mg/m^3$). Among the different types of welding methods, the concentration of welding fumes was highest with the $CO_2$ welding method($2.08mg/m^3$) followed by SMAW(shield metal arc welding, $1.54mg/m^3$) and TIG(tungsten inert gas, $0.70mg/m^3$). Among the different types of workplace, the concentration of welding fumes was highest in underground workplaces($1.97mg/m^3$) followed by outdoor($0.93mg/m^3$) and indoor(wall opening as $0.87mg/m^3$). Specifically comparing the workplaces of general building welders, the concentration of welding fumes was highest in underground workplaces($7.75mg/m^3$) followed by indoor(wall opening as $2.15mg/m^3$). Conclusions: It was found that construction welders experience a risk of expose to welding hazards at a level exceeding the exposure limits. In particular, for high-risk welding jobs such as general building pipefitters and ironworkers, underground welding work and $CO_2$ welding operations require special occupational health management regarding the use of air supply and exhaust equipment and special safety and health education and fume mask are necessary. In addition, there is a need to establish construction work monitoring systems, health planning and management practices.