• Title/Summary/Keyword: Poly vinyl alcohol fiber

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Pervaporation Separation of Water-Isopropyl Alcohol Mixtures Using PVA/PAN Hollow Fiber Composite Membranes (PVA/PAN 중공사 복합막을 이용한 IPA수용액의 투과증발분리)

  • Kim, Ji Seon;Cho, Eun Hye;Kang, Su Yeon;Cheong, Seong Ihl;Park, Hun Whee;Seo, Chang Hee;Rhim, Ji Won
    • Membrane Journal
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    • v.23 no.2
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    • pp.170-175
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    • 2013
  • Poly (vinyl alcohol) (PVA) solution containing the glutaraldehyde (GA) as a crosslinking agent was coated onto the polyacrylonitrile (PAN) hollow fiber membrane as the supporter. Pervaporation experiments were carried out to characterize the prepared PVA/PAN composite membrane for water-isopropyl alcohol mixture. The flux and separation factor were measured at 30, 50, $90^{\circ}C$ for the feed mixture of aqueous 85 wt% IPA solution with varying the reaction temperature and composition of coating solutions. Typically the flux showed 1,870 $g/m^2{\cdot}hr$ at $90^{\circ}C$ feed mixture and the coating concentration of 3.5 wt% and the highest separation factor of 804 was obtained at $30^{\circ}C$ feed mixture and the coating concentration of 7 wt% as well.

Preparation of Monodisperse Poly(vinyl alcohol) Nanospheres[II] Preparation and Characterization Monodisperse Poly(vinyl alcohol) Nanospheres by heterogeneous surface saponificationmation (단분산성 폴리비닐알코올 나노입자 제조[II] 불균일계 표면 비누화에 의한 단분산성 폴리비닐알코올 나노입자의 제조 및 특성해석)

  • Lee, Ga-Hyun;Lee, Se-Geun;Lee, Sung-Jun;Doh, Seok-Joo;Kim, Cham;Kim, Ho-Young;Choi, Jin-Hyun
    • Proceedings of the Korean Fiber Society Conference
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    • 2007.11a
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    • pp.449-450
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    • 2007
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Effect of Stereoregularity on the Properties of Syndiotacticity-Rich Ultrahigh Molecular Weight Poly(vinyl alcohol)/Dimethylsu1foxide/Water Gel

  • Park, Jin-Hyun;Lyoo, Won-Seok;Ko, Sohk-Won
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.13-16
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    • 1998
  • Poly(vinyl alcohol) (PVA) gels are easily formed via physical pathway. Most PVA solutions including PVA/water solution are well known to form thermally reversible gels at low temperature but these gels showed poor mechanical properties. In order to overcome this weak point, transparent crosslinked PVA hydrogels were prepared by electron beam irradiation or by chemical process with crosslinking agents or additives. (omitted)

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Preparation and Characterization of Nanoscaled Poly(vinyl alcohol) fibers via Electrospinning

  • Ding, Bin;Kim, Hak-Yong;Lee, Se-Chul;Lee, Douk-Rae;Choi, Kyung-Ju
    • Fibers and Polymers
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    • v.3 no.2
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    • pp.73-79
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    • 2002
  • Nanoscaled PVA fibers were prepared by electrospinning. This paper described the electrospinning process, the processing conditions fiber morphology, and some potential applications of the PVA nato-fibers. PVA fibers with various diameters (50-250 nm) were obtained by changing solution concentration, voltage and tip to collector distance (TCD). The major factor was the concentration of PVA solution which affected the fiber diameter evidently. Increasing the concentration, the fiber diameter was increased, and the amount of beads was reduced even to 0%. The fibers were found be efficiently crosslinked by glyoxal during the curing process. Phosphoric acid was used as a catalyst activator to reduce strength losses during crosslinking. Scanning electron micrograph (SEM) and differential scanning calorimetric (DSC) techniques were employed to characterize the morphology and crosslinking of PVA fibers. It was fecund that the primary factor which affected the crosslinking density was the content of chemical crosslinking agent.

Control of Crack and Enhanced Durability Performance of Face Slab Concrete (차수벽 콘크리트의 균열제어 및 성능향상에 관한 연구)

  • 임정열;정우성;김완영;원종필
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.537-540
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    • 2003
  • The effects of substituting cement with fly ash(10%, 15%, 20%) and different fiber addition(polypropylene, cellulose, poly vinyl alcohol), on the control of microcrack and enhanced durability performance of face slab concrete in CFRD was studied experimentally It was conducted experiments of plastic shrinkage of mortar and concrete, and drying shrinkage of concrete. Also, durability test were carried out the chloride permeability, abrasion resistance and freeze-thaw repetition. Through the experimental results, it was concluded that ploy vinyl alcohol fiber containing concrete was the most effective mixture in control of cracking and durability.

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Electrospinning Fabrication of Poly(vinyl alcohol)/TiO2 Nanofibers (전기방사를 이용한 Poly(vinyl alcohol)/TiO2 나노섬유 제조)

  • Kim, Young Hun;Do, Kook Bae;Choi, Jae Young;Rabbani, Mohammad Mahbub;Han, Sang Ik;Yeum, Jeong Hyun
    • Textile Coloration and Finishing
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    • v.25 no.2
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    • pp.118-125
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    • 2013
  • Poly(vinyl alcohol) (PVA)/titanium dioxide ($TiO_2$) composite nanofibers were produced at different $TiO_2$ concentrations (0.5, 1 and 1.5 wt.%) using the electrospinning method. The parameters of electrospinning including polymer contents, voltage and tip-to-collector distance (TCD) were optimized for fabrication process. The study showed that 7.5 wt.% PVA, 15 kV applied voltage and 15 cm TCD are the best condition to obtain uniform PVA/$TiO_2$ nanofibers. $TiO_2$ nanoparticles give significant effect in fiber morphology. $TiO_2$ content increases the diameter of the fibers and roughen the fiber surfaces. The PVA/$TiO_2$ nanofibers were characterized by scanning electron microscope (SEM), transmission electron microscope (TEM) and X-ray diffraction (XRD).

Preparation of Poly(vinyl pivalate/vinyl acetate) Microspheres Using Suspension Copolymerization of Vinyl Pivalate and Vinyl Acetate and its characterization (피발산비닐과 아세트산비닐의 현탁공중합을 이용한 폴리(피발산비닐/아세트산비닐) 입자의 제조 및 특성)

  • Park, Chan-Sik;Kim, Joon-Ho;Lyoo, Won-Seok
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.46-48
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    • 2003
  • Poly(vinyl alcohol) (PVA) obtained from PVPi has the highest syndiotacticity among (PVA)s obtained via radical polymerization, and the s-diad content of PVA prepared by low temperature polymerization of vinyl pivalate (VPi)[1-5] comes to eve. 60%, Therefore, we an obtain (PVA)s with various tacticities through the copolymerization of vinyl acetate (VAc) and VPi and can examine the relation between physical properties of (PVA)s and their tacticities. (omitted)

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