• Title/Summary/Keyword: Poly (vinyl alcohol)

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중합형미세토너 합성을 위한 PVA 입자 제조에 관한 연구

  • 김정렬;전재우;곽진우;류원석;김삼수;허만우
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2003.04a
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    • pp.192-196
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    • 2003
  • 폴리비닐알코올[poly(vinyl alcohol)(PVA)]은 1924년에 Herrmann과 Haehnel이 폴리아세트산비닐[(poly(vinyl acetate)(PVAc)]의 비누화 도중 처음 합성되었으며, 2차 세계대전 이후 일본에서 비닐론 섬유용 수지로 상업화되기 시작했다. PVAc의 비누화로부터 제조되는 PVA는 흰색의 분말상 고분자로 필름 및 섬유의 형성이 용이하고 표면 활성도가 높으며, 기계적 성질 및 접착 강도가 높고, 용해도와 화학적 반응성이 우수하다. (중략)

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Transport Properties of Crosslinked Poly Vinyl Alcohol Membrane in Pervaporation

  • Lee, Chul-Haeng;Hong, Won-Hi
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.10a
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    • pp.92-93
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    • 1996
  • PVA membrane was widely used in the dehydration pervaporation process. PVA membrane showed remakable selectivity towed water and an excellent film-forming polymer, with a good resistance to orgamic solvents but it has poor stability in aqueous mixtures. Generally the PVA is manufactured by the hydrolysis reaction from poly vinyl acetate(PVAc) and so the degree of PVA hydrolysis is a major parameter for properties of PVA membrane such as the crystallinity and polarity.

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Control of Crack and Enhanced Durability Performance of Face Slab Concrete (차수벽 콘크리트의 균열제어 및 성능향상에 관한 연구)

  • 임정열;정우성;김완영;원종필
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.537-540
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    • 2003
  • The effects of substituting cement with fly ash(10%, 15%, 20%) and different fiber addition(polypropylene, cellulose, poly vinyl alcohol), on the control of microcrack and enhanced durability performance of face slab concrete in CFRD was studied experimentally It was conducted experiments of plastic shrinkage of mortar and concrete, and drying shrinkage of concrete. Also, durability test were carried out the chloride permeability, abrasion resistance and freeze-thaw repetition. Through the experimental results, it was concluded that ploy vinyl alcohol fiber containing concrete was the most effective mixture in control of cracking and durability.

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Studies on the Preparation of the Poly(vinyl alcohol) ion Exchange Membranes for Direct Methanol Fuel cell (폴리비닐알콜을 이용한 직접메탄을 연료전지용 이온교환막 제조에 관한 연구)

  • 임지원;천세원;전지현;남상용
    • Membrane Journal
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    • v.13 no.3
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    • pp.191-199
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    • 2003
  • Cation exchange polymer electrolyte membrane for the application of direct methanol fuel cell (DMFC) was studied. Poly(vinyl alcohol)(PVA) well known as a methanol barrier in pervaporation separation was used fur the base materials and poly(acrylic acid)(PAA) was used for the crosslinking agent with various concentration. Methanol permeability, ion conductivity, ion exchange capacity, water contents and fixed ion concentration of the membranes were investigated to evaluate the performance of the fuel cell electrolyte membrane. Methanol permeability and ion conductivity of the membranes were decreased with increasing PAA content and were increased over 15% of PAA content. These phenomena would be explained with the introduction of hydrophilic crosslinking agent. The membranes with 15% content of PAA showed methanol permeability of $6.49{\times}10^{-8}/cm^2/s,\; 2.85{\times}10^{-7}CM^2/s$ at $25^{\circ}C,\; 50^{\circ}C$ of operating temperatures, respectively. ion conductivities of the membrane were $2.66{\times}10^{-3}\;S/cm,$ $9.16{\times}10^{-3}\;S/cm$ at $25^{\circ}C,\; 50^{\circ}C$ of operating temperatures, respectively. ion exchange capacity, water content and fixed ion concentration of the membrane were revealed 1.32 meq/g membrane,0.25 g $H_2$O/g membrane and 5.25 meq/g $H_2O$, respectively.