• 제목/요약/키워드: Poly(4-vinylpyridine)-supported

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Synthesis, Characterization and Application of Poly(4-vinylpyridine)-Supported Brønsted Acid as Reusable Catalyst for Acetylation Reaction

  • Borah, Kalyan Jyoti;Dutta, Papia;Borah, Ruli
    • Bulletin of the Korean Chemical Society
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    • 제32권1호
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    • pp.225-228
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    • 2011
  • Poly(4-vinylpyridine)-supported $Br{\phi}nsted$ acids (P4VP-HX) were prepared by wet impregnation technique. These supported acids were found as efficient heterogeneous green catalysts for acetylation of alcohol, amine and phenol with different catalytic activities. The wide application of P4VP-HX as reusable solid acid catalyst in organic reactions is possible because of its simple preparation and handling, stability, simple work up procedure.

Applications of Cross-linked Poly(4-vinylpyridine/styrene) Copolymer supported Ytterbium(III) Triflate in Mannich-type Reaction:Three Component One-pot Synthesis of β-Aminoketones

  • Lee, Sang-Hyeup;Lee, Byoung-Se
    • Bulletin of the Korean Chemical Society
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    • 제30권3호
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    • pp.551-555
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    • 2009
  • The ytterbium catalyst immobilized on the cross-linked poly(4-vinylpyridine/styrene) copolymer (P/S-Yb) was applied in the Mannich-type, three component one-pot synthesis of $\beta$-aminoketones. This catalytic system showed excellent catalytic activity and selectivity which resulted in the exclusive formation of $\beta$-aminoketone. The applicability of this immobilized catalyst system was shown by the reusability test and again highlighted by the synthesis of a $\beta$-aminoketone library using a broad range of substrates.