• Title/Summary/Keyword: Pollutant removal efficiency

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Preparation of $TiO_2$-Coated Polypropylene Beads by PCVD Process for Phenol Removal

  • Pham, Hung-Cuong;Kim, Dong-Joo;Kim, Kyo-Seon
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.10a
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    • pp.185-185
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    • 2009
  • Polypropylene beads (PP) coated with $TiO_2$ thin films were prepared by a rotating cylindrical plasma chemical vapor deposition (PCVD) reactor and were used to remove phenol in aqueous solution. The $TiO_2$ thin films of 416 nm thickness were coated on the PP particles uniformly. As the number of $TiO_2$-coated PP beads increases, the phenol is degraded faster, because of larger total surface area of photocatalysts for photodegradation. This study shows that a rotating cylindrical PCVD reactor can be a good method to prepare the particles coated with high-quality $TiO_2$ thin films, which can be applied to the pollutant removal by a photodegradation reaction of $TiO_2$ with high efficiency.

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Performance assessment of an urban stormwater infiltration trench considering facility maintenance (침투도랑 유지관리를 통한 도시 강우유출수 처리 성능 평가)

  • Reyes, N.J. D.G.;Geronimo, F.K.F.;Choi, H.S.;Kim, L.H.
    • Journal of Wetlands Research
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    • v.20 no.4
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    • pp.424-431
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    • 2018
  • Stormwater runoff containing considerable amounts of pollutants such as particulates, organics, nutrients, and heavy metals contaminate natural bodies of water. At present, best management practices (BMP) intended to reduce the volume and treat pollutants from stormwater runoff were devised to serve as cost-effective measures of stormwater management. However, improper design and lack of proper maintenance can lead to degradation of the facility, making it unable to perform its intended function. This study evaluated an infiltration trench (IT) that went through a series of maintenance operations. 41 monitored rainfall events from 2009 to 2016 were used to evaluate the pollutant removal capabilities of the IT. Assessment of the water quality and hydrological data revealed that the inflow volume was the most relative factor affecting the unit pollutant loads (UPL) entering the facility. Seasonal variations also affected the pollutant removal capabilities of the IT. During the summer season, the increased rainfall depths and runoff volumes diminished the pollutant removal efficiency (RE) of the facility due to increased volumes that washed off larger pollutant loads and caused the IT to overflow. Moreover, the system also exhibited reduced pollutant RE for the winter season due to frozen media layers and chemical-related mechanisms impacted by the low winter temperature. Maintenance operations also posed considerable effects of the performance of the IT. During the first two years of operation, the IT exhibited a decrease in pollutant RE due to aging and lack of proper maintenance. However, some events also showed reduced pollutant RE succeeding the maintenance as a result of disturbed sediments that were not removed from the geotextile. Ultimately, the presented effects of maintenance operations in relation to the pollutant RE of the system may lead to the optimization of maintenance schedules and procedures for BMP of same structure.

Characteristics of a Wet Air Cleaning System for Removal of Air Pollutants (습식 공기청정장치의 공기오염물질 제거 특성)

  • Bae, Gwi-Nam;Kim, Yong Pyo;Baik, Nam Jun
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.1
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    • pp.21-31
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    • 2000
  • Performance characteristics of a wet air cleaning system were investigated experimentally, and discussed in relation with physicochemical properties of the target pollutants. The system is composed of an air cleaner, a separator, and a medium filter. Removal efficiency of the system was measured for ambient particles and gaseous air pollutants: $SO_2$, NO, $NO_2$, HCHO, and $NH_3$. For particle removal test, particles were introduced into the system through a fan, and the particle size distribution was measured at three locations by using two laser particle counters. Particle removal efficiency for each system component was obtained from the particle size distribution. It was found that the separator primarily removed coarse particles greater than $5{\mu}m$ in diameter, and that the medium filter mainly removed fine particles less than $5{\mu}m$ in diameter. For gas removal test, air with gaseous air pollutant was injected into the outlet of the fan, and the concentration was measured both at the upstream of the air cleaner and at the downstream of the separator. It was found that the gaseous species with high Henry's law coefficients, such as $SO_2$, HCHO, and $NH_3$, showed high removal efficiency, but the gaseous species with low Henry's law coefficients, such as NO and $NO_2$, showed low removal efficiencies. It was also found that negative ions were generated from the air cleaner.

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PDMS (Polydimethylsilioxane)-Coated Silica Nanoparticles for Selective Removal of Oil and Organic Compound from Water

  • Cho, Youn Kyoung;Kim, Dae Han;Yoon, Hye Soo;Jeong, Bora;Kim, Young Dok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.257-257
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    • 2013
  • In order to selectively remove oil and organic compound from water, silica nanoparticles with hydrophobic coating was used. Since silica nanoparticles are generally hydrophilic, removal efficiency of oil and organic compound, such as toluene, in water can be decreased due to competitive adsorption with water. In order to increase the removal efficiency of oil and toluene, hydrophobic polydimethylsiloxane (PDMS) was coated on silica nanoparticles in the form of thin film. Hydrophobic property of the PDMS-coated silica nanoparticles and hydrophilic silica nanoparticles were easily confirmed by putting it in the water, hydrophilic particle sinks but hydrophobic particle floats. PDMS coated silica nanoparticles were dispersed on a slide glass with epoxy glue on and the water contact angle on the surface was determined to be over $150^{\circ}$, which is called superhydrophobic. FT-IR spectroscopy was used to check the functional group on silica nanoparticle surface before and after PDMS coating. Then, PDMS coated silica nanoparticles were used to selectively remove oil and toluene from water, respectively. It was demonstrated that PDMS coated nanoaprticles selectively aggregates with oil and toluene in the water and floats in the form of gel and this gel remained floating over 7 days. Furthermore, column filled with hydrophobic PDMS coated silica nanoparticles and hydrophilic porous silica was prepared and tested for simultaneous removal of water-soluble and organic pollutant from water. PDMS coated silica nanoparticles have strong resistibility for water and has affinity for oil and organic compound removal. Therefore PDMS-coated silica nanoparticles can be applied in separating oil or organic solvents from water.

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Evaluation and Comparative Physical/Biological Removal Performance for Extremely Low-Concentration NDMA(N-nitrosodimethylamine) (극저농도 NDMA(N-nitrosodimethylamine) 물리적/생물학적 처리 효율 비교 평가)

  • Park, Seyong;Kim, Hui Joo;Kim, Moonil
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.2
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    • pp.55-61
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    • 2011
  • NDMA(N-Nitrosodimethylamine) has been considered as a carcinogenic pollutant even at extremely low-concentration (10ng/L). However, previous researches on NDMA have focused on mainly high concentration due to a difficulty of analysis. In this study, removal efficiencies were evaluated for individual or combined methods with PAC(Powder Activated Carbon), GS(Granular Sludge), MF(Microfiltration), UF(Ultrafiltration) and Silica gel(MCM-41, Diatomite, Spherical silica gel) at both aerobic and anaerobic conditions. Combined method of GS, PAC and UF membrane at anaerobic condition showed the highest removal efficiency of 65% while Silica gel showed the lowest removal efficiency of 6%. The outcomes of this study could be used further study of extremely low-concentration NDMA removal.

LIDMOD3 Development for Design and Evaluation of Low Impact Development (저영향개발기법 설계 및 평가를 위한 LIDMOD3 개발)

  • Jeon, Ji-Hong;Seo, Seong-Cheol
    • Journal of Korean Society on Water Environment
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    • v.34 no.4
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    • pp.382-390
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    • 2018
  • In this study, the LIDMOD3 was developed to design and evaluate low impact development (LIDMOD). In the same fashion, the LIDMOD3 employs a curve number (NRCS-CN) method to estimate the surface runoff, infiltration and event mean concentration as applicable to pollutant loads which are based on a daily time step. In these terms, the LIDMOD3 can consider a hydrologic soil group for each land use type LID-BMP, and the applied removal efficiency of the surface runoff and pollutant loads by virtue of the stored capacity, which was calculated by analyzing the recorded water balance. As a result of Model development, the LIDMOD3 is based on an Excel spread sheet and consists of 8 sheets of information data, including: General information, Annual precipitation, Land use, Drainage area, LID-BMPs, Cals-cap, Parameters, and the Results. In addition, the LIDMOD3 can estimate the annual hydrology and annual pollutant loads including surface runoff and infiltration, the LID efficiency of the estimated surface runoff for a design rainfall event, and an analysis of the peak flow and time to peak using a unit hydrolograph for pre-development, post-development without LID, and as calculated with LID. As a result of the model application as applied to an apartment, the LIDMOD3 can estimate LID-BMPs considering a well spatical distributed hydroloic soil group as realized on land use and with the LID-BMPs. Essentially, the LIDMOD3 is a screen level and simple model which is easy to use because it is an Excel based model, as are most parameters in the database. This system can be expected to be widely used at the LID site to collect data within various programmable model parameters for the processing of a detail LID model simulation.

Evaluation of the Removal Characteristics of Pollutants in Storm Runoff Depending on the Media Properties (여재 특성에 따른 강우 유출수 내 오염물질 제거특성 평가)

  • Kim, Tae-Gyun;Cho, Kang-Woo;Song, Kyung-Guen;Yoon, Min-Hyuk;Ahn, Kyu-Hong;Hong, Sung-Kwan
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.7
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    • pp.483-490
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    • 2009
  • The aims of this study were to evaluate the removal efficiency for various pollutants in urban storm runoff by a filtration device, and to determine design parameters depending on filter media properties. Appropriate selection of filter media will affect the size and life time of the filtration device. Sets of column tests were performed in order to evaluate the removal efficiency by perlite and a synthetic resin. An investigation of surface properties including CEC (cation exchange capacity) and zeta-potential suggested that the perlite had a superior adsorption capability for cationic pollutants. TCODcr and turbidity were analyzed to investigate the removal characteristic of particulate pollutant. In both columns, the particles in the collected storm runoff was almost completely capture with a small EBCT (empty bed contact time) of 2.5 minutes. Complete clogging at the EBCT of 2.5 minutes occurred after 630 minutes in the perlite column and 810 minutes in the resin column. The removal efficiency of TCODcr and turbidity at the EBCT of 2.5 minutes decreased to below 70% due to an wall effect. The removal efficiency for dissolved pollutant (SCODcr) was negligible due to the insufficient contact time for adsorption. The removal of heavy metals (Cu, Zn, Pb) was mostly ascribed to the filtration of particles containing metals, since the relationship between CEC and the removal efficiency was not apparent. The result of this study would be valuable for the application of filtration device to control of urban storm runoff.

Generation and Current Treatment Status of Sewage at the Rural Village in Chungnam Province (충남지역 마을하수의 발생 및 처리현황)

  • Kang, Bang-Hun;Kim, Jin-Ho;Choi, Chul-Mann
    • Korean Journal of Environmental Agriculture
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    • v.27 no.1
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    • pp.44-49
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    • 2008
  • The purpose of this study is to investigate the current status, including the maintenance problems and removal efficiency, of small sewage treatment facilities in Chung-nam province(Asan, Buyeo, and Gongju city). Our results showed that inflow water quality of Asan city was 19.1 mg/L of BOD, 29.0 mg/L of COD, 13.4 mg/L of T-N and 1.5 mg/L of T-P, respectively, which was much higher than any other site. Among the factors known to be an important index of water quality, the SS and BOD removal efficiency was about 70% and 50% respectively. However, the nitrogen removal efficiency was less than 10%. The total removal efficiency of pollutant was 71.1% of SS, 52.6% of BOD, 46.2% of COD, 9.2% of T-P and 4.6% of T-N respectively. Therefore nitrogen removal processes are required to prevent serious eutrophication of small river. Removal efficiency for BOD and SS of high-efficient sewage treatment facilities (STFs) and contact oxidation process was much higher than another process. Performance of these sewage treatment facilities(STFs) is not optimal due to ineffective planning for the inflow water quality. To improve these facilities, it is proposed that a technical expert analysis of water quality at these facilities is periodically required.

A Study on the Aged Landfill Leachate Treatment with Electrolysis (전기분해공법을 이용한 고령화된 매립장 침출수 처리에 관한 연구)

  • Chung Soon-Hyung;Lee Young-Sei;Choi Hyun-Kuk;Choi Joon-Ho
    • Journal of environmental and Sanitary engineering
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    • v.20 no.1 s.55
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    • pp.32-39
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    • 2005
  • Recently, sanitary landfill was one of the most widely used for disposal of waste in Korea. With increasing of use and public awareness of this method for disposal. there is an increased concern with respect to the pollution potential by the landfill leachate. Especially, an aged landfill leachate contained relatively large amount of the nonbiodegradable substances which could not be removed by biological treatment processes. So, this study was conducted to the removal of nonbiodegradable substances, such as Humic acid and Fulvic acid with the electrolysis. In this study, electrode materials, electrolyte concentration, electrode distance, current density, and pH value were found to have significant effect on both pollutant removal efficiency and current efficiency in electrochemical oxidation process.

Management of Organic Matters by Constructed Treatment Wetlands during Rainfall Events (강우시 인공습지를 이용한 유기물관리)

  • Lee, Sang-Pal;Park, Je-Chul
    • Journal of Environmental Science International
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    • v.26 no.3
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    • pp.401-410
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    • 2017
  • This study analyzed the changes in the concentrations of organic matters in constructed treatment wetlands, coming from discharge water from a sewage treatment plant and non-point pollutant sources during rainfall events. At the beginning of a rainfall event, a massive amount of particulate organic matter flowed in, and was removed from the sedimentation basin (S1, S2); dissolved organic matter was removed after passing through stepwise treatment processes in the wetland. During dry period in the wetland, the removal efficiency rate for COD and TOC was -21 and -7%, respectively; during the rainfall event, the removal efficiency rate for COD and TOC were 47 and 43%, respectively. The highly-concentrated organic matters that flowd in at the beginning of the rainfall event was stabilized by various structures in the wetland before water discharge. Cyanobacteria blooms annually at the confluence of the So-ok stream and Daecheong Lake. Therefore, it is expected that the wetland will contribute significantly to reducing cyanobacteria and improving water quality in the area.