• Title/Summary/Keyword: Polarization of water

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Effect of Annealing Heat Treatment to Corrosion Resistance of a Copper (구리의 내식성에 미치는 어닐링 열처리의 영향)

  • Kim Jin-Kyung;Moon Kyung-Man;Lee Jin-Kyu
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.6
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    • pp.654-661
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    • 2005
  • Copper is a well known alloying element that is used to improve the resistance to general corrosion of stainless steel And also Cu cation have the anti-fouling effect to inhibit adhesion of the marine algae and shellfish to the surface of heat exchanger cooling pipe or outside wall of the ship, Therefore there are some anti-fouling methods such as anti-fouling Paint mixed with copper oxide or MGPS(Marine Growth Preventing System) by using Cu cation dissolved to the sea wather solution. Cu cation can be dissolved spontaneously by galvanic current due to Potential difference between Cu and cooling pipe of heat exchanger with Ti material, which may be one of the anti-fouling designs. In this study the effect of annealing heat treatment to galvanic current and Polarization behavior was investigated with a electrochemical points of view such as measurement of corrosion Potential, anodic polarization curve. cyclic voltammetric curve, galvanic current etc The grain size of the surface in annealed at $700^{\circ}C$ was the smallest than that of other annealing temperatures. and also the corrosion Potential showed more positive potential than other annealing temperatures. The galvanic current between Ti and Cu with annealed at $700^{\circ}C$ was the largest value in the case of static condition. However its value in the case of flow condition was the smallest than the other temperatures. Therefore in order to increase anti-fouling effect by Cu cation, the optimum annealing temperature in static condition of sea water is $700^{\circ}C$, however non- heat treated specimen in the case of flow condition may be desirable.

Studies on the Syndiotactic Poly(vinyl alcohol) Polarizing Film -Preparation of Low Molecular Weight Syndiotactic Poly(vinyl alcohol)/Iodine Complex Film and Its Characterization- (교대배열 폴리비닐알코올 편광필름에 관한 연구 -저분자량 교대배열 폴리비닐알코올/요오드 복합체 필름의 제조와 특성 해석-)

  • 류원석;염정현;최진현;지병철;노태환
    • Polymer(Korea)
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    • v.24 no.5
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    • pp.713-720
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    • 2000
  • A polymer/iodine complex film was prepared using syndiotactic poly(vinyl alcohol) (s-PVA) with number-average degree of polymerization of 900 and syndiotactic diad content of 63.1%. In comparison with atactic-PVA/iodine films, degree of polarization of the s-PVA/iodine film was improved up to over 99% although a lower transmittance was obtained. By soaking in iodine/potassium iodide aqueous solution of a lower iodine concentration and subsequent drawing by 4 times, s-PVA/iodine film of a higher transmittance and degree of polarization was produced. The degree of iodine desorption of the s-PVA/iodine film in water were very low. The crystallinity and the d-spacing and crystal size of (100) plane increased at the early stage of soaking time, however, remained constant or decreased slightly with increasing soaking time. In consequence, s-PVA/iodine complex formation took place mainly inside crystal region at the initial stage of soaking time, whereas it occurred outside crystal region or physical adsorption of iodine dominated after sufficient soaking.

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Effects of the Variables in the Fabrication of Anode on the Performance of DMFC (직접 메탄올 연료전지용 산화극 제조 변수가 성능에 미치는 영향)

  • Kim, Joon-Hee;Ha, Heung-Yong;Oh, In-Hwan;Hong, Seong-Ahn;Lee, Ho-In
    • Journal of the Korean Electrochemical Society
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    • v.6 no.1
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    • pp.18-22
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    • 2003
  • Single cell performance has been investigated and characterized with variables in the fabrication of DMFC anode. The performance was checked as a function of ionomer content which affects ion conductivity in the catalyst layer, and catalyst slurry solvent which determines structure of agglomerates consisting of an ionomer and a catalyst. Anode with total ionomer to catalyst ratio of 0.6 showed the best performance and the lowest polarization resistance. Also, electrochemically effective surface area increased with ionomer content. As solubility of the ionomer decreases with decreasing solvent polarity, the size of agglomerates consisting of a catalyst and an ionomer became larger in the less polar solvent. The anode using DPK $(\varepsilon=12.60)$ as a solvent, which is less polar than generally-used water or alcohol species, showed the maximum performance and the lowest polarization resistance.

Evaluation of the Applicability of Rice Growth Monitoring on Seosan and Pyongyang Region using RADARSAT-2 SAR -By Comparing RapidEye- (RADARSAT-2 SAR를 이용한 서산 및 평양 지역의 벼 생육 모니터링 적용성 평가 -RapidEye와의 비교를 통해-)

  • Na, Sang Il;Hong, Suk Young;Kim, Yi Hyun;Lee, Kyoung Do
    • Journal of The Korean Society of Agricultural Engineers
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    • v.56 no.5
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    • pp.55-65
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    • 2014
  • Radar remote sensing is appropriate for rice monitoring because the areas where this crop is cultivated are often cloudy and rainy. Especially, Synthetic Aperture Radar (SAR) can acquire remote sensing information with a high temporal resolution in tropical and subtropical regions due to its all-weather capability. This paper analyzes the relationships between backscattering coefficients of rice measured by RADARSAT-2 SAR and growth parameters during a rice growth period. And we applied the relationships to crop monitoring of paddy rice in North Korea. As a result, plant height and Leaf Area Index (LAI) increased until Day Of Year (DOY) 234 and then decreased, while fresh weight and dry weight increased until DOY 253. Correlation coefficients revealed that Horizontal transmit and Horizontal receive polarization (HH)-polarization backscattering coefficients were correlated highly with plant height (r=0.95), fresh weight (r=0.92), vegetation water content (r=0.91), LAI (r=0.90), and dry weight (r=0.89). Based on the observed relationships between backscattering coefficients and variables of cultivation, prediction equations were developed using the HH-polarization backscattering coefficients. Concerning the evaluation for the applicability of the LAI distribution from RADARSAT-2, the LAI statistic was evaluated in comparison with LAI distribution from RapidEye image. And LAI distributions in Pyongyang were presented to show spatial variability for unaccessible areas.

A Study on the Galvanic Corrosion for Zirconium with Titanium and 316L Stainless Steel

  • Baik, Shin-Young
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.19 no.3
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    • pp.285-289
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    • 2013
  • The coastal area of Republic of Korea is very clean compared to other countries. In this reason, west coastal area of our country is a good place for breeding up a fish such as shrimp. In winter season, the heating system is required for preventing shrimp death caused by freezing in the farm. The heater in the heating system for fishery's farm is operated very severe combating corrosion due to high accumulation by feeding material and high temperature in heated sea water. Almost all manufactured heaters of STS 316L and Ti material are scrapped every year due to heavy corrosion such a general and crevice corrosion. For comparing the general and galvanic corrosion in new heater material, the test material of Zirconium (Zr), Titanium (Ti) and STS 316L are tested by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), current density-time methods and microscopic examination in a 3.5% NaCl solution. The corrosion potential (Ecor) measured by potentiodynamic polarization for Zr, Ti and STS 316L reveals -198, -250 and -450mV, corrosion current density 0.5, 2.5 and $6.5{\mu}A/cm^2$ respectively. The film resistance measured by EIS are Zr 63,000, Ti 39,700 and 316L $3,150{\Omega}$, and the current of Zr-Ti couple is $0.03{\mu}A$, whereas Zr-316L SS is $0.1{\mu}A$. According to the result of this experiment in 3.5% NaCl solution, Zr is excellent corrosion resistance material than Ti and STS 316L.

The Recognition and Segmentation of the Road Surface State using Wavelet Image Processing (웨이블릿 영상처리에 의한 도로표면상태 인식 및 분류)

  • Han, Tae-Hwan;Ryu, Seung-Ki;Song, Wonseok;Lee, Seung-Rae
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.4
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    • pp.26-34
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    • 2008
  • This study focus on segmentation process that classifies road surfaces into 5 different categories, dry, wet water, icy, and snowy surfaces by analyzing asphalt-paved road images taken in daylight. By using the polarization coefficients, the proportions of horizontally polarized components to vertically polarized components, regions with over 1.3 polarization coefficients are classified as wet surfaces. Except for wet surfaces, the decision process a lies time-frequency analysis to other parts by using the third order wavelet packet transform. In addition, by using the average frequency characteristics of dry and icy surfaces from image templates, decide which is closer to a test image, and finally identify dry and icy surfaces. It is confirmed that the reposed estimation and segmentation of recognition on various images. This can be interpreted as an indication that image-only mad surface condition supervision is probable.

Electric Field Analysis and Removal Characteristics of Escherichia Coli for Water Discharge Tube with Globular SiO$_2$ (구형 SiO$_2$를 갖는 수방전관의 전계 해석 및 대장균 제거 특성)

  • 이동훈
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.2
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    • pp.103-108
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    • 2004
  • This paper shows the simulation of electric field distribution and removal characteristics of Escherichia coli for water discharge tube with globular $SiO_2$. At the experiments of the removing Escherichia coli used the discharge tube with globular dielectric($SiO_2$), because the electric field is increased when applied voltage is increased, the removed ratio of Escherichia coli was related with increasing of applied voltage. When a passing number of test water in water discharge tube is increased, the removed ratio of Escherichia coli is increased because passing number of territory with electric field is increased. When diameter of globular dielectric($SiO_2$) is increased, the removed time of Escherichia coli was decreased because electric field for dielectric polarization of globular dielectric($SiO_2$) was increased. Also, the removed ratio of Escherichia coli of the water discharge tube with globular dielectric($SiO_2$) was measured higher than the removal ratio of the discharge tube without globular dielectric($SiO_2$)

MOLECULAR-DYNAMIC SIMULATION ON THE STATICAL AND DYNAMICAL PROPERTIES OF FLUIDS IN A NANO-CHANNEL

  • Hoang, Hai;Kang, Sang-Mo;Suh, Yong-Kweon
    • Journal of computational fluids engineering
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    • v.14 no.1
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    • pp.24-34
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    • 2009
  • The equilibrium molecular-dynamic simulations have been performed to estimate the properties of the three kinds of fluids confined between two plates that are separated by 1.086 nm; included in the statical properties are the density distribution and the static structure, and the autocorrelation velocity function in the dynamic property. Three kinds of fluids considered in this study are the Lennard-Jones fluid, water and aqueous sodium-chloride solution. The water molecules are modeled by using the SPC/E model and the ions by the charged Lennard-Jones particle model. To treat the water molecules, we combined the quaternion coordinates with Euler angles. We also proposed a plausible algorithm to assign the initial position and direction of molecules. The influence of polarization of water molecules as well as the presence of ions in the solution on the properties will be addressed in this study. In addition, we performed the non-equilibrium molecular-dynamic simulation to compute the flow velocity for the case with the gravitational force acting on molecules.

Corrosion Inhibition of Steel for Water Pipe Line by Adding a Non-Toxic Spearmint Extracts

  • Farooq, Hina;Kim, Jae-Yeon;Lee, Do-Il;Byeon, Jai-Won
    • Journal of Applied Reliability
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    • v.17 no.2
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    • pp.122-128
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    • 2017
  • Purpose: To investigate the corrosion inhibition effect of the natural spearmint oil extracted from Mentha Spicata plants on 304 stainless steel in different concentrations of hydrochloric acid. Method: The anti-corrosive effect has been investigated in 0.5m, 1m and 2m HCl using weight loss test and electrochemical polarization method as a function of inhibitor concentration and immersion time in strong chloride environment. The surface morphology was analysed by scanning electron microscopy (SEM). Results: The corrosion rate of steel decreased and inhibition efficiency increased with the increase in inhibitor concentration. Microscopic evaluation revealed significant corrosion in the specimens immersed in uninhibited conditions. Potentiodynamic polarization test results showed an increase in corrosion potential (Ecorr) and decrease in corrosion current (icorr) value with increasing concentration of inhibitor. Conclusions: Immersion of steel in higher concentration of inhibitor resulted in greater surface coverage value and hence lesser number of surface corrosion sites/pores were formed; thus lowering the corrosion rate.

An adaptive approach for the chloride diffusivity of cement-based materials

  • Tran, Bao-Viet;Pham, Duc-Chinh;Loc, Mai-Dinh;Le, Minh-Cuong
    • Computers and Concrete
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    • v.23 no.2
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    • pp.145-153
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    • 2019
  • Adaptive schemes are constructed in this paper for modeling the effective chloride diffusion coefficient of cement-based materials (paste and concrete). Based on the polarization approximations for the effective conductivity of isotropic multicomponent materials, we develop some fitting procedures to include more information about the materials, to improve the accuracy of the scheme. The variable reference parameter of the approximation involves a few free scalars, which are determined through the available numerical or experimental values of the macroscopic chloride diffusion coefficient of cement paste or concrete at some volume proportions of the component materials. The various factors that affect the chloride diffusivity of cement-based material (porous material structure, uncertainty of value of the chloride diffusion coefficient in water-saturated pore spaces, etc.) may be accounted to make the predictions more accurate. Illustrations of applications are provided in a number of examples to show the usefulness of the approach.