• Title/Summary/Keyword: Polarization of water

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On the Corrosion Protection Characteristics of Port Steel Structures Corroded Naturally for a Long Period of Time (장기간 자연 부식된 항만부두 강구조물의 방식특성 연구)

  • Kim, K.J.;Choi, Y.S.
    • Journal of Korean Port Research
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    • v.12 no.1
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    • pp.145-154
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    • 1998
  • Protection characteristics of the corroded steel pile which was served as a pier structure over 8 years in seawater have been examined in terms of corrosion potential, electrochemical impedance spectroscopy(EIS) and anodic/cathodic polarization curves. The steel structure was sectioned into two parts, waterline(splash zone, just above the seawater surface) and in-water(underwater), and protection characteristics for the two parts were investigated with the application of cathodic protection(CP) by sacrificial anodes using Zn and Al alloys. The main results obtained were as follows; (1) The corrosion potential of waterline zone was higher than that of in-water, which implied that the corrosion of waterline was more severe than that of in-water, (2) As a result of EIS examination, the transition period from the apparent CP to the substantial CP took about twenty to thirty days according to the corrosion condition.

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Extract of Camellia sinensis as Green Inhibitor for the Corrosion of Mild Steel in Aqueous Solution

  • Fouda, Abd El-Aziz S.;Mekkia, Dina;Badr, Abeer H.
    • Journal of the Korean Chemical Society
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    • v.57 no.2
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    • pp.264-271
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    • 2013
  • Corrosion inhibition of mild steel used in water station in 35 ppm aluminum sulfate and 10 ppm chloride solution by Camellia sinensis leaves extract was studied using weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy techniques at $30^{\circ}C$. Results show that the inhibition efficiency increases with increasing concentration of the extract and decreases with increasing temperature. Inhibitive effect was afforded by adsorption of the extract's components which was found to accord with Langmuir adsorption isotherm. Inhibition mechanism is deduced from the temperature dependence of the inhibition efficiency and was further corroborated by the values of activation parameters obtained from the experimental data.

Analysis on Shielding Effectiveness of Electromagnetic Wave in Fire Pipes (물이 채워진 소화 배관의 전파 차폐도 해석)

  • Kim, Yoon-Jeung
    • Fire Science and Engineering
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    • v.30 no.4
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    • pp.94-102
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    • 2016
  • When establishing shielding facilities for EMP protection, WBC effect is used to protect fire pipes and honeycomb cells are inserted into the fire pipes to improve the shielding effectiveness. At this point, the smaller unit cell of honeycombs becomes, the more likely it interrupts the flow of water, which ends up clogging the fire pipes with sediment. To prevent this phenomenon, I would suggest a design method due to the pilarization loss of water molecules that contributes to increasing the size of honeycomb cells and remaining thin-walled sufficient for required shielding effectiveness.

Electrical Properties of Both a Monolayer at the Air/Water Interface and a Langmuir-Blodgett Film Sandwiched Between Aluminum Electrodes (수면상의 고분자막과 알루미늄 전자간의 Langmuir-Blodgett막에 대한 전기적 특성)

  • Mitsumasa Iwamoto;Kang, Dou-Yol
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.38 no.1
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    • pp.35-42
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    • 1989
  • Electrical properties of both a monolayer at the air/water interface and Langmuir-Blodgett films sandwiched between aluminum electrodes are studied using a current-measuring technique. A change in induced charges on an electrode suspended in the air was measured in combination with the surface area isotherm in the electrical measurement of the monolayer. A change in induced charges on an electrode is measured while heating the sample in the electrical measurement of the LB films. From both measurements, we elucidated that a spontaneous polarization plays very important role in the electrical properties of both a monolayer at the air/water interface and LB films sandwiched between aluminum electrodes.

The Degumming and Sericin Recovery of the Silk fabric Using the Electrolytic Water(II) (전해수를 이용한 견섬유 정련 및 세리신 회수(II)-분리막에 의한 세리신 농축을 중심으로-)

  • 배기서;이태상;노덕길;홍영기
    • Textile Coloration and Finishing
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    • v.16 no.4
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    • pp.10-18
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    • 2004
  • In this work, Aqueous sericin solution was prepared by degumming process with electrolytic reduction water. Then, the microfiltration and ultrafiltration systems were applied to the concentration of aqueous sericin solution. The objective of this study was to select the optimum operating condition among the different pressure. The permeate flux and rejection ratio were observed with time, pressure, flow rate and concentration. and, the wastewater and permeated water quality values such as pH, BOD, COD, and NH levels were measured. In order to see the influence of electrolytic reduction water, the flux of pure water and electrolytic reduction water by PVDF22(MF) and PS100(UF) membrane was measured. In microfiltration system, the relative flux reduction decreased rapidly to 0.02 in the 30min, as the concentration polarization and gel layer formation were increased. and then the sericin concentration rejection ratio was 40%. In ultrafiltration system, the permeate flux decreased with time and concentration, and increased with the operating pressure and flow rate. Optimal condition in PS100 membrane system for sericin concentration was operating pressure 1.464kgf/$cm^24, operating flow rate $7\ell/min at\; 40^{\circ}C$. At that time, sericin concentration rejection ratio was 83% respectably. The sericin solution was concentrated from 0.1wt% solution to 0.2 wt % solution during about 2 hrs by the UF filteration membrane system.

Use of uniform distribution for generating synthetic brightness temperature in passive microwave soil moisture retrieval

  • Lee Khil-Ha
    • Proceedings of the Korea Water Resources Association Conference
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    • 2005.05b
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    • pp.19-28
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    • 2005
  • Passive microwave remote sensing technique have shown great potential for mon monitoring regional/global surface soil moisture. Given a single measurement at dual polarization/single frequency/single view angle, a strategic approach to artificially generating multiple microwave brightness temperatures is presented. And then the statistically generated microwave brightness temperature data are applied to the inverse algorithm, which mainly relies on a physically based microwave emission model and an advanced single-criterion multi-parameter optimization technique, to simultaneously retrieve soil moisture and vegetation characteristics. . The procedure is tested with dual polarized Tropical Rainfall Measurement Mission Microwave Imager (TRMM/TMI) over two different cover sites in Oklahoma and Beltsville field experimental data. The retrieval results are analyzed and show excellent performance.

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Modeling of flux enhancement in presence of concentration polarization by pressure pulsation during laminar cross flow ultrafiltration

  • Kumar, Kamal;De, Sirshendu
    • Membrane and Water Treatment
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    • v.1 no.4
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    • pp.253-271
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    • 2010
  • A theoretical study for the flux enhancement by pulsation of transmembrane pressure is presented for osmotic pressure controlled ultrafiltration under laminar flow regime. The transient velocity profile is solved analytically using Green's function method. Time dependent convective diffusive equation is solved to quantify the membrane surface concentration and the permeate flux, numerically. The effects of the amplitude and frequency of pulsation on flux, surface concentration and observed retention are studied.

THE PHOTOHYDRATION OF 1-(NITROPHENYL)-5,5-DIMETHYL-1,3-HEXADIYNES: THE NITRO SUBSTITUENT EFFECT ON THE EXCITED STATES OF DIACETYLENES

  • Baek, Eun-Kyung
    • Journal of Photoscience
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    • v.2 no.2
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    • pp.73-76
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    • 1995
  • The photohydration of 1-(m-nitrophenyl)-5, 5-dimethyl-1, 3-hexadiyne (m-NDHD) affords allenyl ketone compound (1) via triplet excited state which is converted into $\beta$-dicarbonyl compound (2) through thermal hydration. The allenyl ketone is formed by the synchronous addition of water with protonation at C$_1$ indicating that m-NDHD has the reverse polarization and greater electron withdrawing effect in the triplet excited state in comparison with p-NDHD.

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A New Empirical Potential Function and Its Application to Hydrogen Bonding

  • Kang, Young-Kee;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
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    • v.2 no.1
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    • pp.8-11
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    • 1981
  • A new potential function based on spectroscopic results for diatomic molecules is presented and applied to the hydrogen bonding systems. The potential energy of interaction is supposed to have electrostatic, polarization, dispersion, repulsion and effective charge-transfer contributions. Estimates of the effective charge-transfer quantity have been made based on the average charge of the proton donor and the acceptor atoms. For dimers such as water, methanol, acetic acid and formic acid, the vibrational stretching frequencies and dimerization energies are calculated and dicussed in connection with Badger-Bauer rule.

AN ELECTROCHEMICAL STUDY ON SURFACE FINISH OF DENTAL AMALGAM (아말감의 표면연마에 관한 전기화학적 연구)

  • Suk, Chang-In;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.16 no.2
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    • pp.18-32
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    • 1991
  • The purpose of this study was to observe characteristic properties of amalgam through the polarization curves and SEM images from 4 type amalgams (Amalcap, Shofu spherical. Dispersalloy and Tytin) with 3 different surface finish procedures (polishing, burnishing and carving) by using the potentiostats (EG & GPARC) and SEM (Jeol JSM-35). After each amalgam alloy and Hg was triturated as the direction of the manufacturer by means of mechanical amalgamator (Samki), the triturated mass was inserted into the cylndrical metal mold which was 12 mm in diameter and 10 mm in height and was pressed with $100kg/cm^2$. 4 specimens of each type amalgam were burnished with egg burnisher and another 4 specimens of each type amalgam were carved with Hollenback carver. Above 8 specimens and remaining untreated 4 specimens were stored at room temperature for about 7 days. Untreated 4 specimens of each type amalgam were polished with abrasive papers (Deer) from #400 to #1200 and finally on the polishing cloth with $0.5{\mu}m$ and $0.06{\mu}m$ $Al_2O_3 $ powder suspended water. Anodic polarization measurements was employed to compare the corrosion behaviours of the amalgams in 0.9% saline solution at $37^{\circ}C$. The open circuit potential was determined after 30 minutes immersion of specimen in electrolyte. The scan rate was 1 mV/sec and the surface area of amalgam exposed to the solution was $0.64cm^2$ for each specimen. All the potentials reported are with respect to a saturated calomel electrode (SCE). SEM images of each specimen were taken after + 800 mV (SCE) polarization. The results were as follows: 1. The corrosion potential of high copper amalgam was more anodic than that of low copper amalgam. 2. The polished amalgam were more resistant to corrosion than any other burnished and carved amalgam. 3. In the case of polishing, current density of high copper amalgam was lower than that of low copper amalgam.

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