• Title/Summary/Keyword: Polarization of water

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The Effects of Salt Water Treating on Dielectric Properties of FRP Composite Insulation Materials (FRP 복합절연재료의 유전특성에 미치는 염수처리의 영향)

  • ;;;;;Ichikawa, K.
    • Electrical & Electronic Materials
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    • v.10 no.1
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    • pp.45-53
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    • 1997
  • The purpose of this paper is to evaluate FRP rod for aging, which exposed to salt water and pure at elevated temperature. Dielectric constant and tan .delta. on time and frequency domain were tested to observe how rapidly the FRP rod aged. Dielectric constants of FRP rods with treating time were slightly increased. That of FRP rods with frequency, However, showed strongly the effects of large relaxation time estimated from interfacial polarization a or ionic. It is obvious that absorbed water affects to dielectric and electric properties of FRP with increasing the treating time.

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Effect of Passing Aged Years and Coating Thickness on Corrosion Properties of Reinforcing Steel in Mortar (W/C:0.5) (모르타르(W/C:0.5)내의 철근의 부식 특성에 미치는 재령 년수와 피복두께의 영향)

  • Moon, Kyung-Man;Lee, Sung-Yul;Jeong, Jin-A;Lee, Myeong-Hoon;Baek, Tae-Sil
    • Corrosion Science and Technology
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    • v.14 no.2
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    • pp.99-105
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    • 2015
  • The structures of reinforced concrete have been extensively increased with rapid development of industrial society. Futhermore, these reinforced concretes are easy to expose to severe corrosive environments such as seawater, contaminated water, acid rain and seashore etc.. Thus, corrosion problem of steel bar embedded in concrete is very important in terms of safety and economical point of view. In this study, specimens having six different coating thickness (W/C:0.5) were prepared and immersed in flowing seawater for five years to evaluate the effect of coating thickness and immersion time on corrosion property. The polarization characteristics of these embedded steel bars were investigated using electrochemical methods such as corrosion potential, anodic polarization curve, and impedance. At the 20-day immersion, the corrosion potentials exhibited increasingly nobler values with coating thickness. However, after 5-yr. immersion their values were shifted in the negative direction, and the relationship between corrosion potential and coating thickness was not shown. Although 5-yr. immersion lowered corrosion potential, 5-yr. immersion did not increase corrosion rate. In addition, after 5-yr. immersion, the thinner cover thickness, corrosion current density was decreased with thinning coating thickness. It is due to the fact that ease incorporation of water, dissolved oxygen and chloride ion into a steel surface caused corrosion and hence, leaded to the formation of corrosion product. The corrosion product plays the role as a corrosion barrier and increases polarization resistance. The corrosion probability evaluated depending on corrosion potential may not be a good method for predicting corrosion probability. Hence, the parameters including cover thickness and passed aged years as well as corrosion potential is suggested to be considered for better assessment of corrosion probability of reinforced steel exposed to partially or fully in marine environment for long years.

Evaluation of Insulation Diagnostic Test Reliability for Stator Winding of High Voltage Induction Motor (고압유도전동기 절연특성시험의 신뢰도 평가)

  • Lee, Kwang-Ho;Kim, Hyun-Il;Kwak, Hee-Jin;Oh, Bong-Keun
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1838-1841
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    • 2004
  • This test was performed to assess the correlation between insulation diagnostic tests and breakdown voltage strength of the stator winding of 6.6kV class induction motor in insulation deterioration condition which have been in service for 5 years after being installed in 1998. The insulation diagnostic tests include resistance, polarization index(P.I), dissipation factor(${\triangle}tan{\delta}$), maximum partial discharges(Qmax) and AC breakdown test. we evaluated the correlation between insulation diagnostic test and AC breakdown test for stator winding of high voltage induction motor.

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Evaluation of Insulation Diagnostic Test Reliability for Stator Winding of High Voltage Induction Motor (고압유도전동기 절연특성시험의 신뢰도 평가)

  • Lee, Kwang-Ho;Kim, Hyun-Il;Kwak, Hee-Jin;Oh, Bong-Keun
    • Proceedings of the KIEE Conference
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    • 2004.11d
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    • pp.46-49
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    • 2004
  • This test was performed to assess the correlation between insulation diagnostic tests and breakdown voltage strength of the stator winding of 6.6kV class induction motor in insulation deterioration condition which have been in service for 5 years after being installed in 1998. The insulation diagnostic tests include resistance, polarization index(P.I), dissipation factor(${\Delta}tan{\delta}$). maximum partial discharges(Qmax) and AC breakdown test. we evaluated the correlation between insulation diagnostic test and AC breakdown test for stator winding of high voltage induction motor.

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Evaluation of Insulation Condition for High Voltage Induction Motor (고압유도전동기의 절연상태 평가)

  • Lee, Kwang-Ho;Lim, Jae-Il;Kim, Ki-Won;Jung, Jin-Dal;Lee, Eun-Woong
    • Proceedings of the KIEE Conference
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    • 2003.07b
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    • pp.783-785
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    • 2003
  • This test was performed to assess the insulation deterioration condition of the stator winding of 3.3kV class induction motors which have been in service for 15 years after being installed in 1988. The insulation diagnostic tests include resistance, polarization index(P.I). dissipation factor(${\Delta}tan{\delta}$) and maximum partial discharges(Qmax). The results of diagnostic tests were compared to the visual inspection in overhaul.

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Development of a predictive model of the limiting current density of an electrodialysis process using response surface methodology

  • Ali, Mourad Ben Sik;Hamrouni, Bechir
    • Membrane and Water Treatment
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    • v.7 no.2
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    • pp.127-141
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    • 2016
  • Electrodialysis (ED) is known to be a useful membrane process for desalination, concentration, separation, and purification in many fields. In this process, it is desirable to work at high current density in order to achieve fast desalination with the lowest possible effective membrane area. In practice, however, operating currents are restricted by the occurrence of concentration polarization phenomena. Many studies showed the occurrence of a limiting current density (LCD). The limiting current density in the electrodialysis process is an important parameter which determines the electrical resistance and the current utilization. Therefore, its reliable determination is required for designing an efficient electrodialysis plant. The purpose of this study is the development of a predictive model of the limiting current density in an electrodialysis process using response surface methodology (RSM). A two-factor central composite design (CCD) of RSM was used to analyze the effect of operation conditions (the initial salt concentration (C) and the linear flow velocity of solution to be treated (u)) on the limiting current density and to establish a regression model. All experiments were carried out on synthetic brackish water solutions using a laboratory scale electrodialysis cell. The limiting current density for each experiment was determined using the Cowan-Brown method. A suitable regression model for predicting LCD within the ranges of variables used was developed based on experimental results. The proposed mathematical quadratic model was simple. Its quality was evaluated by regression analysis and by the Analysis Of Variance, popularly known as the ANOVA.

Effect of Gas Diffusion Layer Property on PEMFC Performance (기체확산층 물성이 고분자전해질 연료전지 성능에 미치는 영향)

  • Kim, Junseob;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.31 no.5
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    • pp.568-574
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    • 2020
  • Gas diffusion layer (GDL) is one of the main components of PEMFC as a pathway of reactants from a flow field to an electrode, water transport in reverse direction, heat management and structural support of MEA. In this study, the effect of GDL on fuel cell performance was investigated for commercial products such as 39BC and JNT30-A3. Polarization curve measurements were performed at different flow rates and relative humidity conditions using 25 ㎠ unit cell. The parameters on operating conditions were calculated using an empirical equation. The electrical resistance increased as the GDL PTFE content increased. The crack of microporous layer had influence on the concentration loss as water pathway. In addition, the ohmic resistance increased as the relative humidity decreased, but decreased as the current density increased due to water formation. Curve fitting analysis using the empirical equation model was applied to identify the tendency of performance parameters on operating conditions for the gas diffusion layer.

Metal Foam Flow Field Effect on PEMFC Performance (금속 폼 유로가 고분자전해질 연료전지 성능에 미치는 영향)

  • Kim, Junseob;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.32 no.4
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    • pp.442-448
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    • 2021
  • Flow field is an important parameter for polymer electrolyte membrane fuel cell (PEMFC) performance to have an effect on the reactant supply, heat and water diffusion, and contact resistance. In this study, PEMFC performance was investigated using Cu foam flow field at the cathode of 25 cm2 unit cell. Polarization curve and electrochemical impedance spectroscopy were performed at different pressure and relative humidity conditions. The Cu foam showed lower cell performance than that of serpentine type due to its high ohmic resistance, but lower activation and concentration loss due to the even reactant distribution of porous structure. Cu foam has the advantage of effective water transport because of its hydrophobicity. However, it showed low membrane hydration at low humidity condition. The metal foam flow field could improve fuel cell performance with a uniform pressure distribution and effective water management, so future research on the properties of metal foam should be conducted to reduce electrical resistance of bipolar plate.

Utilization of Induced Polarization and Electrical Resistivity for Identifying Rock Condition (유도분극 전하 충전성과 전기비저항을 활용한 암반 상태 파악 가능성 연구)

  • Park, Jinho;Ryu, Jinwoo;Jung, Jeehee;Lee, In-Mo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.36 no.3
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    • pp.493-502
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    • 2016
  • This study examines how rock condition affects the variation of the chargeability and electrical resistivity of the rock. In the theoretical study, the relationship correlating chargeability with the variables affecting it is derived. A parametric study utilizing the derived relationship reveals that the size of narrow pores ($r_1$) is the most influential factor on chargeability, and the salinity of pore water ($C_0$) is the second. In the laboratory experiments, small scale rock fracturing zone is modelled using sand stone. Chargeability and resistivity are measured by changing the size of the joint aperture, the location of fractured zone and the existence of clay gouge and/or clay layer which shows lower chargeability than the sand stone layer in the multi-layered ground. Test results show that chargeability is controlled not by the rock fracturing condition but by the size of narrow pore ($r_1$) where each line of current flow passes through. Also, the chargeability decreases with increase of the pore water salinity ($C_0$). In conclusion, the ground condition can be identified more efficiently by measuring the induced polarization along with the electrical resistivity; identifying the existence of sea water, the layered ground and/or the fractured rock becomes more reliable.

Corrosion behavior of coated steel pipes for water works with water content of soil (토양의 함수율에 빠른 상수도용 도복장 강관의 부식거동에 관한 연구)

  • Park, Kyung-Wha;Bae, Jeong-Hyo;Ha, Tae-Hyun;Lee, Hyun-Goo;Ha, Yoon-Cheol;Kim, Dae-Kyeong
    • Proceedings of the KIEE Conference
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    • 2004.11a
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    • pp.227-229
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    • 2004
  • The corrosion rate of buried steel pipes for water works was investigated under soil environment. Steel pipe shows various characteristics caused by complicated environment condition of underground and especially the corrosion rate of it depends on the resistivity of soil controlled by content of water. In this paper, the corrosion behavior of steel pipe was observed by polarization test under soil and the silica sand in the water content range of 0-50%. Generally it is well known that the resistivity of soil decreased rapidly over 15% water content. In fact the corrosion rate, corrosion potential, and corrosion consumption (MPY) of steel pipe were shown very different aspects within 20% water content.

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