• Title/Summary/Keyword: Polarization coefficient

Search Result 178, Processing Time 0.022 seconds

Modeling and parametric studies of PEM fuel cell performance (운전 조건에 따른 PEM 연료전지 모델링 및 성능 분석)

  • Noh, Young-Woo;Kim, Sae-Hoon;Jeong, Kwi-Seong;Son, Ik-Jae;Han, Kook-Il;Ahn, Byung-Ki
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.19 no.3
    • /
    • pp.209-216
    • /
    • 2008
  • In the present study, a mathematical model has been formulated for the performance of polymer electrolyte fuel cells. Modify the concentration polarization equation using concentration coefficient that represents the characteristics of bipolar plate reactant distribution. The model predictions have been compared with experimental results and good agreement has been demonstrated for the cell polarization curves. The effects of operating parameters on the performance of fuel cells have been studied. Increases of operation pressure reduce the effect of temperature on the performance.

Uncertainty in Potentiodynamic Polarization Resistance Measurement (동전위 분극저항 측정에서의 불확도)

  • Kim, Jong Jip
    • Corrosion Science and Technology
    • /
    • v.8 no.5
    • /
    • pp.193-196
    • /
    • 2009
  • For the estimation of uncertainty in potentiodynamic polarization resistance measurement, the type A uncertainty was measured using type 316 stainless steel in an acidified NaCl solution. Sensitivity coefficients were determined for measurand such as scan rate of potential, temperature of solution, concentration of NaCl, concentration of HCl, surface roughness of specimen and flow rate of purging gas. Sensitivity coefficients were large for the measurand such as the scan rate of potential, temperature of solution and roughness of specimen. However, the sensitivity coefficients were not the major factors influencing the combined standard uncertainty of polarization resistance due to the low values of uncertainty in measurements of the measurands. A major influencing factor was the concentration of NaCl. The value of type A uncertainty was 1.1 times the value of type B uncertainty, and the combined standard uncertainty was 10.5 % of the average value of polarization resistance.

Corrosion Characteristics with Polarization Curve of Polymers

  • Park, Chil-Nam;Jung, Oh-Jin
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
    • /
    • v.10 no.S_4
    • /
    • pp.181-187
    • /
    • 2001
  • This study was carried out to measure the variations of potential and current density with polymers. The results were particularly examined to identify the influences on potential and rate of various factors including temperature and pH. The Tafel slope for anodic dissolution was determined by the polarization effect depending on these conditions. The optimum conditions were established for each case. The second anodic current density peak and maximum current density were designated as the relative polarization sensitivity$(I_r/I_f)$. The mass transfer coefficient value$(\alpha)$ was determined with the Tafel slope for anodic dissolution based on the polarization effect with optimum conditions.

  • PDF

Accurate Evaluation of Polarization Characteristics in the Integrated Optic Chip for Interferometric Fiber Optic Gyroscope Based on Path-matched Interferometry

  • Choi, Woo-Seok;Jo, Min-Sik
    • Journal of the Optical Society of Korea
    • /
    • v.13 no.4
    • /
    • pp.439-444
    • /
    • 2009
  • Accurate evaluation of polarization characteristics in the integrated optic chip (IOC) for interferometric fiber optic gyroscope was performed. Spatial distribution of optical wavetrains caused by the polarization parameters such as local polarization cross-coupling and polarization rejection coefficient of the IOC were measured utilizing the path-matched optical coherence domain polarimetry (PM-OCDP). With the analytic model deduced from Jones matrix representation, we could accurately identify the polarization characteristics of the IOC. Both degree of measurement error due to the imperfect equipment conditions in PM-OCDP and birefringence of IOC chip were also characterized.

Study of Voltage Loss on Polymer Electrolyte Membrane Fuel Cell Using Empirical Equation (Empirical Equation을 이용한 고분자전해질 연료전지의 전압 손실에 대한 연구)

  • Kim, Kiseok;Goo, Youngmo;Kim, Junbom
    • Applied Chemistry for Engineering
    • /
    • v.29 no.6
    • /
    • pp.789-798
    • /
    • 2018
  • The role of empirical equation to predict the performance of polymer electrolyte membrane fuel cell is important. The activation, ohmic and mass transfer losses were separated in a polarization curve, and the curve fitting according to each region was performed using Kim's model and Hao's model. Changes of each loss were compared according to operation variables of the temperature, pressure, oxygen concentration and membrane thickness. The existing model showed a good fitting convergence, but less fitting accuracy in the separated loss region. A new model using the convergence coefficient was suggested to improve the accuracy of performance prediction of fuel cells of which results were demonstrated.

A Study on Polarization Diversity for the Next Generation Mobile Radio Communications

  • Jung, Hee-Chang;Park, Seung-Keun;Ha, Deock-Ho
    • Journal of Electrical Engineering and information Science
    • /
    • v.3 no.1
    • /
    • pp.117-125
    • /
    • 1998
  • In this paper, in order to investigate the fading reduction effect of narrowband and broadband signals in an indoor multipath propagation environment, both the received narrowband signal while a vehicle unit in motion and the frequency sweeped broadband signal received by vertical polarized antenna, horizontal polarized antenna and circularly polarized antenna are analyzed. Specifically, in order to evaluate polarization diversity effect, we examined the difference of fading reduction effect between the polarization diversity reception and the space diversity reception. Using the correlation coefficient and correlation graph for the polarization diversity branches, the diversity effect is evaluated. And also, using the cumulative distribution for the received signal strength simulated by diversity reception, the diversity effect is also estimated. From the evaluation results it was found that the polarization diversity which use a circularly polarized antenna at the transmitting end and the vertical and horizontal polarized antenna branches at the receiving end is markedly excellent.

  • PDF

Redox Reaction on Polarization Curve Variations of Polymer with Enzymes

  • Park, Chil-Nam
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
    • /
    • v.4 no.3
    • /
    • pp.165-171
    • /
    • 2000
  • Experiments were carried out to measure variations in the oxidation potential and current density using the polarization curves of polycarbonate. The results were then examined to identify the influences affecting the oxidation potential related to various conditions, such as temperature, pH, and oxydase(citrate and lipase). The lines representing the active anodic and cathodic dissolution shifted only slightly in the potential direction relative to temperature, pH, and the effect of the enzyme. The Tafel slope for the anodic and cathodic dissolution was determined such that the reversibility polarization was indicated as being effected by various conditions. The slope of the polarization curves describing the active-to-passive transition region shifted noticeably in their direction. Also, by varying the conditions, the optimum conditions for the most ready transform were identified, including temperature, pH, oxidation rate, and resistance of oxidation potential. The critical oxidation sensitivity(I(sub)r/I(sub)f) of the anodic current density peak and maximum passive current density was also determined, which is used in measuring the critical corrosion sensitivity of a polycarbonate.

  • PDF

Trends on Income Inequality and Bi-polarization for Forest Household (임가의 소득불평등과 양극화 추이)

  • Kim, Eui-Gyeong;Jung, Byung-Heon;Kim, Dong-Hyun
    • Journal of Korean Society of Forest Science
    • /
    • v.106 no.4
    • /
    • pp.497-508
    • /
    • 2017
  • This study conducted to examine about the income inequality and bi-polarization for forestry household. For this purpose, Gini coefficient and Atkinson index were used to analyze the income inequality for forestry household. Also, DER index were employed to show their income bi-polarization. Before using these methodologies, forestry household income was divided into three parts that was forestry income, non forestry business income and transfer income. And then, income inequality and bi-polarization were analyzed respectively. The result shows that forestry household income inequality was higher than whole household inequality. Apart from transfer income, forestry household income, forestry income and non forestry business income inequality was aggravated. At the same time, these tendency was able to observe the bi-polarization for forestry household income and other income sources.

Effect of Electrolytic Condition on Composition of Zn-Co Alloy Plating (Zn-Co 합금도금의 조성에 미치는 전해조건의 영향)

  • Kang, Soo Young
    • Journal of the Korea Convergence Society
    • /
    • v.8 no.11
    • /
    • pp.287-292
    • /
    • 2017
  • The electrodeposition of Zn on the automotive parts has been adapted However, because Zn electrodeposit needs to increase thickness for corrosion protection, it has problem of destruction of electrodeposit Zn-based electrodeposit have teen studied for corrosion protection and decreasing electrodeposit thickness. Especially; Zn-Co electrodeposit have much attention In this study, the Composition of Zn-Co electrodeposit in various manufacturing condition such as temperature, current density and electrolyte content was investigated to understand effect of electrolysis condition on Co content of specimen. The results were explained by cathode overvoltage and diffusion coefficient. As the current density increases, the electrolyte temperature decreases, and as the electrolyte concentration decreases, the overvoltage of the cathode increases. As the overvoltage of the cathode increases, the concentration polarization becomes more important than the activation polarization. Concentration polarization is determined by the diffusion of the mass transfer in the diffusion layer. In a constant concentration polarization, a large amount of elements with a large diffusion coefficient is diffused. That is, as the overvoltage of the cathode increases, the Zn content having a large diffusion coefficient increases.