• Bulletin of the Korean Chemical Society
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• v.27 no.12
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• pp.2011-2018
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• 2006

We have investigated the solvent effects on $\Delta log\;K_s $(the difference of stability constant of binding) and the different free energies of binding of $Nd^{3+}$ and $Eu^{3+}$ ions to 18-crown-6, i.e., the selectivity of $Nd^{3+}$ and $Eu^{3+}$ ions to 18-crown-6 using a Monte Carlo simulation of statistical perturbation theory (SPT) in diverse solvents. The stability constant ($\Delta log\;K_s $) of binding of $Nd^{3+}$ and $Eu^{3+}$ ions to 18-crown-6, in $CH_3OH$ was calculated in this study as -1.06 agrees well with the different experimental results of -0.44~-0.6, respectively. We have reported here the quantitative solvent-polarity relationships (QSPR) studied on the solvent effects the relative free energies of binding of $Nd^{3+}$ and $Eu^{3+}$ ions to 18-crown-6. From the calculated coefficients of QSPR, we have noted that solvent polarity (ET) and Kamlet -Tafts solvatochromic parameters (b ) dominate the differences in relative solvation Gibbs free energies of $Nd^{3+}$ and $Eu^{3+}$ ions but basicity (Bj) dominates the negative values in differences in the stability constant ($\Delta log\;K_s $) as well as the relative free energies of binding of $Nd^{3+}$ and $Eu^{3+}$ ions to 18-crown-6 and acidity (Aj) dominates the positive values in differences in the stability constant ($\Delta log\;K_s $) as well as the relative free energies of binding of $Nd^{3+}$ and $Eu^{3+}$ ions to 18-crown-6.

• Journal of Electrical Engineering and Technology
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• v.2 no.3
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• pp.366-372
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• 2007

Joining thin aluminum alloy is difficult using most welding techniques. Many of the problems are associated with bum-through by the high heat input. Common welding techniques are TIG (Tungsten Inert Gas), MIG (Metal Inert Gas), and PULSE-MIG welding. The method provides more control of the heat balance in the welding arc by taking advantage of the different arc characteristics obtained with each of the two polarities. In this paper, we proposed a new welding method by control DSP 320C32, and the characteristic and experiment result-voltage, current, welding bead, and penetrations by this method are presented.

• Journal of Communications and Networks
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• v.2 no.1
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• pp.69-75
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• 2000

A new frame synchronization confirmation technique using a pilot pattern of both uplink and downlink channels is proposed for W-CDMA (Wideband Code Division Multiple Access) system. It is shown that by using this technique, we can cancel the side lobe for autocorrelation functions of the frame synchronization words of pilot pattern have the maximum to-of-phase autocorrelation value "4" with two peak values equal in magnitude and opposite in polarity at zero and middle shifts. Due to this side lobe cancellation effect, therefore, the autocorrelation function of the frame synchronization words becomes ideal for the frame synchronization confirmation since double maximum correlation values equal in magnitude and opposite polarity at zero ad middle shifts can be achieved. This property can be used to double check frame synchronization timing and thus. improve the frame synchronization confirmation performance.

• Journal of Photoscience
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• v.6 no.4
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• pp.159-163
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• 1999

The fluorescence quenching of 2-phenyl-5-(4-biphenylyl)-1,3,4-oxadiazole (PBD) and 1,4-di-[2-(5-phenyloxazolyl)]-benzene (POPOP) by aniline has been carried out in different solvent mixtures of dioxane and acetonitrile at room temperature. The quenching is found to be appreciable and a positive deviation from linearity was observed in the Stern-Volmer plot in all the solvent mixtures. Various rate constants for the quenching processes have been determined using a modified Stern-Volmer equation. From the positive deviations of linear Stern-Volmer plots and the dependence of rate constants on the polarity of the solvents, it has been concluded that both static and dynamic quenching processes are responsible for the observed positive deviation in the Stern-Volmer plot.

• Bulletin of the Korean Chemical Society
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• v.26 no.1
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• pp.47-50
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• 2005

Solvatochromic fluorescence behavior of 8-aminoquinoline based benzothiazole derivative in varying solvent systems has been investigated. Benzothiazole appended 8-aminoquinoline 3 showed distinctive fluorescence color changes depending upon the solvent polarities and the fluorescence color changes occurred over relatively wide span in visible region from 486 nm to 598 nm which can be detected with naked eye. Compound 3 also exhibited significant spectral shifts in ${\lambda}_{em}$ as a function of water composition in binary aqueous solvent systems. The changes are due to the specific interaction of 3 by hydrogen bonding with water as well as general solvent effect. The observed solvatochromic fluorescence characteristics of 3 could be used as a new probe for the micro-environmental polarity changes as well as a sensitive sensor for the determination of water composition in binary aqueous solutions.

• International Journal of Precision Engineering and Manufacturing
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• v.9 no.2
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• pp.34-38
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• 2008

Commercially available magnetic barrel machines equipped with permanent magnets have certain limitations: work can only be finished effectively in limited areas of the container because permanent magnets are arranged two-dimensionally on the magnet disk. We overcame this problem by developing a new magnetic barrel machine equipped with a three-dimensional magnet arrangement. The effectiveness of the new machine has already been reported; this study improved the machine's polishing ability by changing the polarity of magnets on a magnet block. Polishing experiments confirmed the most effective arrangement of magnets on the magnet block. An alternating arrangement of north and south poles produced far superior polishing characteristics than a uniform arrangement of the same pole facing outward. Alternating polarity probably causes increased quantities of barrel media to work together. Finally, we introduced stronger permanent magnets to the magnet block, and found that the increased magnetic field also improved polishing ability.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.26 no.5
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• pp.85-90
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• 2012

In this paper, it was investigated experimentally that diameter and polarity variation of corona wire electrode affected to ozone generation of the ozone generator using a wire-to-plate type electrode. The change in the diameter(D) of the corona wire electrode has a great effect upon ozone generation, higher influence appears in the positive corona discharge than the negative corona discharge. In the case of D=0.50[mm], maximum ozone generation and power efficiency could be obtained. However, in the case of smaller D than this, the ozone generation and efficiency decreases slowly and in the case of larger D, the ozone generation decreases rapidly. It means performance decline as an ozone generator. Therefore, ozone generation and power efficiency would increase through simple optimization of the corona electrode specification.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1992.05a
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• pp.140-143
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• 1992

This paper deals with the dielectric behaviors of $SF_{6}$ gas and prebreakdown growth caused by lightning impulse voltages in inhomogeneous field perturbed with a fixed needle-shaped protrusion on the electrode. The measuring interpretation of the external current induced by moving charges is described. The temporal growth of prebreakdown is obserbed by using a shunt and photomultiplier. The prebreakdown processes are initiated by the first streamer corona at a needle protrustion, the flashover of the main gap in the positive polarity is very sensitive to the local field and propagates into the gap with the leader mechanism. It is found that the dependence of the prebreakdown phenomena on the polarity of applied voltages is caused by the effect of space charges. In addition, the proposed measuring techniques are very useful to perform the measurements of avalanche currents, corona discharges in inhomogeneous fields ad partial discharges in voids.

• Proceedings of the KIEE Conference
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• 1994.11a
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• pp.284-286
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• 1994

This paper describes the dielectric characteristics of $SF_6$ gas in non-uniform electric filed under lightning under lightning impulse and oscillating impulse voltages. The breakdown voltage-time characteristics and the breakdown voltage-pressure characteristics are measured over a pressure range extending from 0.1 to 0.5 [MPa] fur the coaxial electrode with a needle protrusion. The curvature radius of needle protrusion is 0.3[mm]. Also, the growth of the predischarge is simultaneously observed. As a result the polarity effect is pronounced, and the breakdowns voltage under the oscillating impulse voltage are higher than those under the lightning impulse voltage. It is found that the breakdown mechanism md predischarge phenomena ate closely related with the polarity and waveforms of the testing voltage.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.31 no.1 s.49
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• pp.43-49
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• 2005

Recently, according as people who have sensitive skin increase, we've been giving more importance to the safety of cosmetics. Especially, preservative is known to be one of the main stimuli which cause side-effects of cosmetics. However, there have been few reports describing cell cytotoxicity, skin penetration, oil-aqueous phase partition, anti-microbial activity of preservatives and their correlation with skin irritation. The study is aimed to develop low irritable preservative system with phenoxyethanol, one of the most commonly used preservatives in cosmetics, considering various factors mentioned above. According to our results of cell cytotoxicity against human normal fibroblasts by means of MTT assay, phenoxyethanol showed the lowest cytotoxicity when compared to other preservatives tested (cytotoxicity: pro-pylparaben > butylparaben > ethylparaben > methylparaben > triclosan > phenoxyethanol), but human patch test for assessing shin primary irritation revealed that phenoxyethanol has higher skin irritation than methylparaben and triclosan. We performed in vitro skin penetration test using horizontal Franz diffusion cells with skin membrane prepared from hairless mouse (5 ${\~}$ 8 weeks, male) to evaluate the rate of skin penetration of preservatives. From the results, we found that the higher irritable property of phenoxyethanol in human skin correlates with its predominant permeability (skin penetration: phenoxyethanol > methylparaben > ethylparaben > propylparaben > butylfaraben > triclosan). Therefore, we made an effort to reduce skin permeability of phenoxyethanol and found that not only the rate of skin penetration of phenoxyethanol but also its skin irritation is dramatically reduced in formulas containing oils with low polarity. In the experiments to investigate the effect of oil polarity on the oil-aqueous phase partition of phenoxyethanol, more than $70\%$ of phenoxyethanol was partitioned in aqueous phase in formulas containing oils with low polarity, while about $70 {\~} 90\%$ of phenoxyethanol was partitioned in oil phase in formulas containing oils with high polarity. Also, in aqueous phase phenoxyethanol showed greater anti-microbial activity. Conclusively, it appears that we can develop less toxic preservative system with reduced use dosage of phenox-yethanol and its skin penetration by changing oil composition in formulas.