• Journal of Conservation Science
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• v.36 no.2
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• pp.103-111
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• 2020

To compare the cleaning effect of solvents such as water and ethanol used to clean lacquer relics, the components extracted with various solvents were analyzed. A freshly dried lacquer sample and a lacquer sample exposed to ultraviolet radiation for 24 days were treated with water, ethanol, acetone, and hexane, and the dissolved material was detected by pyrolysis-gas chromatography-mass spectrometry. The amount extracted was significantly higher in acetone and ethanol than in hexane, a nonpolar solvent. Water, a highly polar solvent, was relatively efficient for extracting low-molecular-weight materials. After experiencing 24 days of ultraviolet radiation, the lacquer exhibited a significant increase of extracted materials compared with the nonexposed one. This may be due to the degradation of the urushiol chain in the form of polymers, resulting in the formation of low-molecular-weight polar substances, including dicarboxylic acids. In addition to the deterioration status of lacquer relics, such solvent extraction properties will be a crucial consideration in selecting the appropriate cleaning solvent.

• Ocean and Polar Research
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• v.36 no.4
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• pp.437-445
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• 2014

A time-series sediment trap was operated at a water depth of 4950 m from July 2003 to May 2004 at KOMO station ($10^{\circ}30^{\prime}N$, $131^{\circ}20^{\prime}W$) in the northeastern equatorial Pacific, with the aim of understanding the temporal variation of planktonic foraminifera assemblages in response to the seasonal shift of Inter-Tropical Convergence Zone (ITCZ). A total of 22130 planktonic foraminifera specimens belonging to 30 species and 11 genera were identified, which shows a distinct seasonal variation with high values (125~288 specimens $m^{-2}day^{-1}$) in the winter to spring (December-May) and low values (16~23 specimens $m^{-2}day^{-1}$) in the fall (September-November). In addition, seasonal ecological differences of foraminifera assemblages are distinctly recognizable: omnivorous foraminifera occurred predominantly during the summer season, whereas herbivorous ones were dominant during the winter season. Such seasonal variations correspond to the seasonal shift of the ITCZ. Enhanced occurrence of herbivorous species during the winter-spring season seems a result of surface water mixing generated by the southward shift of the ITCZ. The increase in omnivorous species during the summer season may be due to the northward movement of the ITCZ caused by weakened wind speed, resulting in the intensification of water column stratification and nutrient-poor environment. A significant reduction of planktonic foraminifera specimens during the fall is attributed to heavy precipitation and reduction in light intensity.

• The Korean Journal of Ecology
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• v.17 no.4
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• pp.501-511
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• 1994

Dynamics of nutrients, non-polar, water solubles, acid solubles and acid insolubles (lignin) in decomposing litter were investigated for 2 years in the oak, Quercus acutissima, and the pitch pine, Pinus rigida, stands in the vicinity of Kongju, Chungnam Province. Nitrogen and phosphorus conetrations in decomposing litter increased with time elapsed, however, potassium decreased rapidly within three months and then remined constant with time elapsed. Calcium concentration in needle litter during experimental period was lower than that of initial concentration in needle litter during experimental period was lower than that of initial concentration, and showed no significant variation with time elapsed. Calcium concentration in oak litter during the experimental period, however, were higher than that of initial concentration. Magnesium concentration in oak litter decreased repidly during six months, and then remaines constant thereafter. Annual amount of nitrogen, phosphorus, potassium, calcium and magnesium which returned to soil via litter decomposition in the oak and the pitch pine stands was $3.3g/m^2$ and $0.9g/m^2$ for N, $0.03g/m^2$ and $0.01g/m^2$ for P, $1.3g/m^2$ and $0.7g/m^2$ for K, $0.7g/m^2$ and $1.2g/m^2$ for Ca, $0.9g/m^2$ and $0.4g/m^2$ for Mg, respectively. Non-polar, and water- and acid-soluble fractions in decomposing litter decreased and lignin increased with time.

• Applied Chemistry for Engineering
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• v.5 no.2
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• pp.274-284
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• 1994

Phase Inversion Temperature (PIT) measurements showed that the addition of polar components such as oleyl alcohol and oleic acid to the system comprising n-dodecylpentaoxyethylene monoether ($C_{12}E_5$), nonpolar oil (n-hexadecane) and water produced large reductions in the PIT. The PIT was lowered as the additive-to-surfactant ratio in the surfactant films in the microemulsion phase was increased. Another dramatic effect of additive was the manner in which it affects the volume of the microemulsion phase at the PIT of the oil and water solubilization characteristics. Microemulsion phase volume was increased rapidly with decreasing PIT, i.e., with increasing amounts of additive in the system. Also with a decrease in PIT, the solubilization parameters of both oil and water in the microemulsion phase were strikingly increased. Even though soil removal data were not available for the conditions where our results obtained, PIT measurement seems a useful starting point for estimating conditions when middle-phase microemulsion formation and its associated high solubilization of oil can be expected.

• Bulletin of the Korean Chemical Society
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• v.28 no.1
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• pp.108-114
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• 2007

The lyotropic behaviors to form the structure of distearoylphosphatidylcholine (DSPC)-based liquid crystal (LC) hydrated by only propylene glycol (PG) without water were examined by differential scanning calorimetry (DSC), X-ray diffractions (XRD), polarized microscope (PM) and transmission electron microscope (TEM). By increasing the amount of PG instead of water, it showed the phase transition to be gradually changed from anisotropic structures to other structures more close to isotropic ones and their appearance to be changed from solid-like states to liquid-like ones with more fluidity. Below 50% w/w PG, the mixtures of DSPC and PG resulted in no direct observation of LC structure through PM because they were very close to solid-states. From 55% w/w to 90% w/w of PG, the dense lamella crystalline structures were observed through PM, and their thickness and area decreased as the content of PG increased. Measured by DSC with heating process, the main phase transition from α -lamella phase to isotropic phase appeared from 52.89 °C to 47.41 °C to show linearly decreasing behaviors because PG affects the hydrophobic region of DSPC-based lamella phase. The repeating distance of the lamella phase and the interlayer distance between bilayers were calculated with XRDs and the average number of bilayers related to the thickness in LC structure was approximately estimated by combining with TEM results. The WAXS and DSC measurements showed that all of PG molecules contributed to swelling both the lipid layer in the edge region of lamella phase close to phosphate groups and the interlayer between bilayers below 90% w/w of PG. The phase and thermal behaviors were found to depend on the amount of PG used by means of dissolving DSPC as a phospholipid and rearranging its structure. Instead of water, the inducement of PG as a polar solvent in solid-lamella phase is discussed in terms of the swelling effect of PG for DSPC-based lamella membrane.

• Ocean and Polar Research
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• v.28 no.2
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• pp.153-161
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• 2006

To investigate inflow path of the East Sea Intermediate Water (ESIW) into the Ulleung Basin, hydrographic data surveyed in July 2005 were analyzed. The ESIW was characterized by the Salinity Minimum Layer (SML) within a depth range of 100 to 360 meters. Averaged potential temperature and salinity of the SML were $1.835^{\circ}C$ and 34.049 psu, respectively. Mean potential density $({\sigma}_{\theta})$ of the SML was 27.221 with a standard deviation of 0.0393. On isopycnal surfaces of 27.14 and 27.18 $({\sigma}_{\theta})$ which correspond to upper layers of the ESIW, the coastal low salinity water was separated from the offshore low salinity water by the relatively warm and saline water which might be affected by the Tsushima Warm Current Water. Relatively cold and fresh water, however, intruded into the Ulleung Basin from the region of Korean coast on isopycnal surfaces of 27.22 and 27.26 which was lower layer of the ESIW. The salinity distribution in the isopycnal layer of $27.14{\sim}27.26$ with acceleration potential on 27.22 up surface also showed clearly that the low salinity water flowed from the coastal area and intruded into the Ulleung Basin. This implies that the ESIW flows ken the north to the south along the east coasts of Korea and spreads into the Ulleung Basin in summer.

• Ocean and Polar Research
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• v.25 no.spc3
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• pp.393-397
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• 2003

The seawater exchange breakwaters can be effectively employed to conserve or enhance the water quality inside harbors by transmitting the exterior water into the harbor. In the present study, three shapes of the breakwater, that is, the flow conduit embedded type, the wave chamber type and the oscillating water channel type are compared far their water exchanging capability through regular wave experiments. The results show that the net influx of water appears differently depending on wave period for each breakwater type. The net influx of the wave chamber type is much greater than that of the flow conduit embedded type. It is also ascertained that the influx of the oscillating water channel type can be greatly enhanced by attaining the resonance condition inside the channel at the wave periods frequently occurring at the fields where the breakwaters are to be installed.

• Korean Journal of Microbiology
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• v.45 no.2
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• pp.119-125
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• 2009

To understand the ecological function of heterotrophic bacterial community in water column of large freshwater lakes in the permafrost zone, we investigated the structure and function of bacterial community in Lake Khuvsgul, Mongolia. Species composition of overall bacterial community was analyzed by denaturing gradient gel electrophoresis (DGGE) of 16S rRNA gene fragments, and bacteria that can be cultured at 10oC were isolated and characterized. Based on the depth profile of environmental parameters, thermocline and chemocline were recognized at the 5~10 m zone of the water column. The stratified DGGE profile indicated that the discontinuity of water properties might influence the structure of bacterial community: band profiles in the 0~5 m zone were diverse with large change by depth, but the profile was relatively stable at the $\geq$10 m zone, with predominance of the band identified as Acidovorax facilis. Bacterial cultures were screened for protease, cellulase, amylase and lipase activity, and 23 isolates were selected for high activity of the hydrolytic enzymes. The isolates were identified based on their 16S rRNA gene sequences. In the surface water (zero meter depth), Acidovorax defluvii and Sphingobacterium faecium with high cellulase activity were present. Flavobacterium succinicans, Mycoplana bullata and A. facilis were stably predominant isolates at 2 m, 5 m, and $\geq$10 m depths, respectively. F. succinicans isolates showed high protease activity while M. bullata isolates showed moderate levels of protease and celluase activity. A. facilis isolates showed either cellulase or lipase activity, exclusively to each other. According to the profile of growth rates of the isolates in the temperature range of $0\sim42^{\circ}C$, the surface-zone (0~5 m) isolates were facultative psychrophiles while isolates from $\geq$10 m depth were typical mesophiles. This stratification is believed to be due to stratified availability of organic materials to the bacterial decomposers. In the water column below the chemoline, the environment is extremely oligotrophic so that the trait of rapid growth in low temperature might not be demanded by deep-lake decomposers. The stratified distribution of community composition and decomposer activity in Lake Khuvsgul implies that ecological functions of bacterial community in lakes of cold region are sharply divided by water column stratification.

• Ocean and Polar Research
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• v.28 no.1
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• pp.1-12
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• 2006

Analyses of sedimentological and geochemical parameters from two radiocarbon-dated sediment cores (JM98-845-PC and JM98-818-PC) retrieved from the central part of Isfjorden, Svalbard, in the Arctic Sea, reveal detailed paleoclimatic and paleoceanographic histories over the last 15,000 radiocarbon years. The overconsolidated diamicton at the base of core JM98-845-PC is supposed to be a basal till deposited beneath pounding glacier that had advanced during the LGM (Last Glacial Maximum). Deglaciation of the fjord commenced after the glacial maximum, marked by the deposition of interlaminated sand and mud in the ice-proximal zone by subglacial meltwater discharge, and prevailed between 13,700 and 10,800 yr B.P. with enriched-terrigenous organic materials. A return to colder conditions occurred at around 10,800 yr B.P. with a drop in TOC content, which is probably coincident with the Younger Dryas event in the North Atlantic region. At this time, an abrupt decrease of TOC content as well as an increase in C/N ratio suggests enhanced terrigenous input due to the glacial readvance. A climatic optimum is recognized between 8,395 and 2,442 yr B.P., coinciding with 'a mid-Holocene climatic optimum' in Northern Hemisphere sites (e.g., the Laurentide Ice sheet). During this time, as the sea ice receded from the fjord, enhanced primary productivity occurred in open marine conditions, resulting in the deposition of organic-enriched pebbly mud with evidence of TOC maxima and C/N ratio minima in sediments. Fast ice also disappeared from the coast, providing the maximum of IRD (ice-rafted debris) input. Around 2,442 yr B.p. (the onset of Neoglacial), pebbly mud, characterized by a decrease in TOC content, reflects the formation of more extensive sea ice and fast ice, which might cause decreased primary productivity in the surface water, as evidenced by a decrease in TOC content. Our results provide evidence of climatic change on the Svalbard fjords that helps to refine the existence and timing of late Pleistocene and Holocene millennial-scale climatic events in the Northern Hemisphere.

• Toxicological Research
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• v.14 no.2
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• pp.171-176
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• 1998

The biological effects of the water extracts of Rhus Verniciflua Stokes (RVS) were evaluated by protection against hydroxyl radicals. Antioxidative activities were measured using both 1,1-diphenyl-2-picrylhydrazyl (DPPH) and thiocyanate method. Also we used the Glucose oxidase (GO) 20 mU/$\textrm{m}{\ell}$ hydroxyl radical generating system in mouse forebrain cell culture. Water was used for ex-traction from RVS as a solvent which has high polarity especially. In DPPH method, the antioxidative activities of the crude water extract were stronger than any other extracts of low polar-solvents. In the antioxidative effects of mouse forebrain culture using 20 mU/$\textrm{m}{\ell}$ GO, cell viabilities were evaluated 65.6%, 68.8% at 1 $\mu\textrm{g}$. 5 $\mu\textrm{g}$ addition of crude water extracts (30 mg/$\textrm{m}{\ell}$) respectively. 10 $\mu\textrm{g}$ addition of crude water extracts had more than 86.1% cell viabilities, P<0.0l significantly, compared with the group treated with GO alone. In comparison with the antioxidative activities of several commercial antioxidants (ascorbic acid, $\alpha$-tocopherol, catalase, serum), 273 $\mu\textrm{g}$/$\textrm{m}{\ell}$ addition of crude water extracts (300 $\mu\textrm{g}$/$\textrm{m}{\ell}$) showed equivalent antioxidative effect to 25 uM ascorbic acid.