• Korean Journal of Chemical Engineering
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• 제35권11호
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• pp.2296-2302
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• 2018

Internally plasticized PVC was prepared via chemical reaction of azide PVC and alkynyl group containing castor oil methyl ester. The chemical structure of alkynyl group containing castor oil methyl ester and internally plasticized PVC was characterized with FT-IR and $^1H$ NMR. Properties of internally plasticized PVC, including thermal stability, tensile tests and resistance to extraction in different solvents, was investigated. The results showed that alkynyl group containing castor oil methyl ester, as internal plasticizer of PVC, not only decreased the $T_g$ of PVC from $84.6^{\circ}C$ to $41.6^{\circ}C$ efficiently, but also presented no plasticizer loss in five different solvents. The tensile tests showed that elongation at break and tensile strength of internally plasticized PVC was 353.8% and 18.1 MPa. The internally plasticized PVC has potential application in replacing the traditional PVC material in PVC products with high durability.

• Bulletin of the Korean Chemical Society
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• 제15권10호
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• pp.836-841
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• 1994

The polymer matrix effect on the selectivity, response rate and reproducibility for coextraction type anion-selective optode membranes were investigated with DOA-plasticized PVC, PVC/hydroxylated PVC, PU/hydroxylated PVC and DOS-plasticized CTA matrices. Optode membranes were prepared with TDMACl and ETH2412 dissolved in one of the four solvent polymeric matrices. The PU/hydroxylated PVC and PVC-based membranes have almost the same selectivity coefficients, while the CTA-based membrane is more selective toward lipophilic anions. The membrane with PU/hydroxylated PVC adhered strongly to a glass surface, and showed highly reproducible and relatively rapid response. Very poor adhesion of PVC/hydroxylated PVC and CTA-based membranes limited the usability of those membranes as sensor components. Based on these results, and considering the biocompatibility for clinical samples, the optode made with PU/hydroxylated PVC was applied to determine the thiocyanate ion in human saliva. The results obtained with this simple device were comparable to those with rather complicated ISE methods.

• 한국고분자학회지:고분자과학과기술
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• 제6권6호
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• pp.604-609
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• 1995

• Elastomers and Composites
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• 제34권5호
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• pp.391-398
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• 1999

폴리염화비닐(PVC)에 프탈산계 가소제인 di-2-ethyl hexyl phthalate (DOP)와 아디프산계 가소제인 di-2-ethyl hexyl adiphate (DOA)를 혼련하였다. 혼련한 컴파운드의 비중, 인장강도, 신율, 경도, 내마모성, 내한굴곡성을 측정하였다. 먼저 PVC의 중합도에 따른 물성을 알아보면, 중합도 2500인 PVC를 사용한 컴파운드(이하 P2500계)가 중합도 1300인 PVC를 사용한 컴파운드(이하 P1300계)보다 인장강도, 경도에서 상대적으로 우수하게 나타났고, 신율, 내마모성, 내한굴곡성에서는 P1300계가 P2500계 보다 우수하게 나타났다. 그리고, 비중은 PVC의 중합도에 상관없이 비슷하게 나타났다. 또 가소제의 종류에 따른 PVC 컴파운드의 기계적 물성을 알아보면, 가소제로 DOP를 첨가한 PVC 컴파운드(이하 DOP계)가 DOA를 첨가한 PVC 컴파운드(이하 DOA계)보다 인장강도, 신율에서 우수하게 나타났고, 내마모성, 내한굴곡성에서는 DOA계가 상대적으로 DOP계보다 우수하게 나타났다. 그리고 경도는 DOP계가 높게, 비중은 DOA계가 더 낮게 나타났다.

• 약학회지
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• 제43권3호
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• pp.289-293
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• 1999

Many poly (vinyl chloride : PVC) membrane electrodes were investigated for the determination of basic drugs, chlorpromazine, amitriptyline, nortriptyline, etc. These electrodes are based on the use of the ion-association complexes of the basic drugs with eriochrome cyanine R, chromoxane cyanine, chrome azurol S and picric acid as ion-exchange sites in a plasticized PVC matrix. All ion-exchangers except picrate complex were not proper for use, because those complexes in plasticized membrane were excluded into aqueous working solution. These drug electrodes show excellent Nernstian responses in the concentration ranges $10^{-2}~10^{-6}$ mol $dm^{-3}$. Their selectivity with respect to each other, as well as their work-able pH range have been investigated. The major advantages of the proposed methods are their simplicity and speed.

• Bulletin of the Korean Chemical Society
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• 제19권2호
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• pp.207-211
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• 1998

Potentiometric characteristics of DOS plasticized PVC-based membranes containing upper-rim calix[4]crown neutral carrier to various metal cations and protonated alkylamines have been examined. Although the calix[4]crown-based membrane electrodes exhibited substantial emf responses to alkali and alkaline earth metal cations, their high detection limits (- log[Cs+]=4.5) and sub-Nernstian response slopes (48 mV/pCs+) to the most selective cation, cesium, indicate that the metal cation complexing ability of calix[4]crown is much weaker than that of macrocyclic crown ethers. However, the calix[4]crown-based membrane electrodes exhibited near-Nernstian response slopes (56 mV/decade for hexylNH3+) with low detection limits (log[hexylNH3+]= - 6.7) to most alkylammonium ions compared to those of blank (DOS plasticized PVC membrane with no ionophore) or crown ether-based membranes. While the selectivity patterns of blank and crown ether-based membranes are determined primarily by the lipophilicity of alkylammonium ions, the membranes doped with calix[4]crown ionophore could effectively discriminate the steric shapes of nonpolar alkyl groups of alkylammonium ions.

• 임산에너지
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• 제17권1호
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• pp.36-46
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• 1998

이 연구는 점탄성 고분자재료를 사용하여 진동·충격음 흡수성능을 지니는 목질계 복합재료의 제조를 목적으로, 가소화 PVC의 동적점탄성 및 고분자 적층 복합체의 진동흡수성능에 미치는 고분자의 점탄성의 영향을 검토하였다. 가소제는 디옥틸프탈레이트(DOP)를 사용하여, 20∼140 phr까지 첨가하였다. 고분자의 동적점탄성의 측정은 Rheovibron을 사용하여 110Hzdml 인장진동을 가하여, -100∼150℃까지 매분 1℃를 상승시키면서 측정하였다. PVC와 DOP는 전조성에서 완전상용성이었으며, T(E"max)와 T(tan δmax)는 가소제의 첨가량이 증가함에 따라 저온 측으로 이동하였다. 고분자 적층 복합체의 진동흡수성능은 Rheovibron을 개조한 양단지지 중심하중에 의한 강제 휨진동법 및 공진법에 하나인 양단자유 휨진동법을 사용하였다. 샌드위치구조 복합체의 진동흡수계수(tanδc)는 고분자의 손실계수(tanδ)와 정의 상관성을 나타내었으며, 피복체의 진동흡수계수는 고분자의 손실탄성률(E")에 의존하는 경향을 나타내었다. 또한 샌드위치구조 복합체의 대수감쇠율(Δc)은 tanδc곡선과 유사한 곡선을 나타내었다.

• 한국축산식품학회지
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• 제23권2호
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• pp.103-108
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• 2003

돼지고기와 쇠고기를 다양한 조건으로 PVC 랩 필름으로 포장하고 저장하였을 때 시료로 이행된 DEHA 가소제의 양을 조사하였다. 돼지고기 등심과 등지방을 조합하여 지방 함량을 5.9, 13.9와 29.6%로 각각 만들어 랩 포장하고 5$^{\circ}C$에서 2일간 저장한 결과 지방함량이 높을수록 이행량은 증가되는 경향을 보였다. 돼지고기를 -2, 5와 1$0^{\circ}C$에서 각각 저장하였을 때 저장 기간이 연장되고 저장 온도가 상승할수록 이행량이 증가하는 경향을 보였다. 그리고 랩 포장된 돼지고기와 쇠고기 시료육에서 필름과 접촉된 표면으로부터 멀어질수록 이행량은 낮게 나타났으며 2 cm 이상의 깊이에서는 DEHA가 검출되지 않았다. 돼지고기 삼겹살을 랩 포장 후 5$^{\circ}C$에서 3일간 저장하였을 때 한 겹보다는 두 겹으로 포장 시 이행량이 높게 나타났다. 한편 2일 후 분쇄한 다음 새로 랩 포장하여 하루 더 저장하였던 시료에서는 앞의 두 시료들에서보다 이행량이 더 낮게 나타났다. 국내에는 DEHA 이행량에 대한 기준이 없지만 유럽연합의 기준치인 3 mg/d$m^2$ 또는 18 mg/kg에 근거하면 조사된 대부분의 시료들에서 이 기준치를 초과한 것으로 나타났다.

• 한국전기전자재료학회논문지
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• 제36권1호
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• pp.93-97
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• 2023

A triboelectric nanogenerator (TENG) is a device that converts mechanical energy into electrical energy, and has been considered as a substitute for continuous power supply due to its high performance, simple structure and eco-friendliness. Recently, it is important to develop a TENG using a non-toxic material in order to use it as a power source for wearable, attachable, and body-embeddable electronics. Here, we developed a human friendly TENG using polyvinyl chloride (PVC) gel containing acetyl tributyl citrate (ATBC), a non-toxic plasticizer. PVC gels were fabricated using various ratios of PVC and ATBC, and optimized by investigating dielectric properties, surface potential, output performance, and durability. The PVC gel based TENG generates output signals of 73 V and 4.3 μA, i.e., a 5-fold enhancement in the output power compared to pristine PVC-based TENG. In addition, the PVC gel can be stretched over 500% of strain. This study is expected to be helpful in the future development of non-toxic wearable TENG.

• Macromolecular Research
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• 제11권3호
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• pp.178-182
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• 2003

The thermal decomposition of phthalate alone and with poly(vinyl chloride) (PVC) was carried out under a nitrogen atmosphere in a 4-necked separable flask. The thermal decomposition of phthalate in the presence of PVC began at 150$^{\circ}$, about 10$0^{\circ}C$ lower than the decomposition of phthalate alone. The formation of octyl chloride indicated an interaction reaction between phthalate and PVC. From the analysis of the composition of commercially plasticized PVC sheet (film and board), the phthalates (dibutyl phthalate, dihexyl phthalate) and di(2-ethylhexyl) phthalate), 2-ethyl-1-hexanol, phthalic anhydride, and 2-ethylhexyl hydrogen phthalate were identified. The mutage-nicities of these decomposition products were higher than those of phthalic diesters (phthalates).