• Korean Chemical Engineering Research
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• 제59권3호
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• pp.326-332
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• 2021

본 연구에서는 수열 합성법을 이용하여 나노 실리콘이 포함된 구형의 탄소 복합체를 합성하고, 석유계 피치로 코팅하여 제조된 음극 소재의 전기화학 특성을 조사하였다. 수크로스의 몰 농도를 변화시켜 수열합성한 후, 유기 용매로 THF를 사용하여 피치로 코팅된 음극 복합소재를 제조하였다. 제조된 음극 소재는 SEM, EDS, XRD 및 TGA를 사용하여 물리적 특성을 분석하였으며, 1.0 M LiPF₆ (EC : DMC : EMC = 1 : 1 : 1 vol%) 전해액에서 사이클, 율속, 순환전압전류 및 임피던스 테스트를 통해 리튬이차전지의 전기화학 성능을 조사하였다. 1.5 M의 수크로스와 피치를 사용하여 제조된 실리콘/탄소 소재는 구형 형태를 보였으며, 1756 mAh/g의 높은 초기 용량, 50 사이클 후 82 %의 용량 유지율 및 2 C/0.1 C에서 81%의 우수한 속도 특성을 확인할 수 있었다.

• Journal of Industrial and Engineering Chemistry
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• 제67권
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• pp.358-364
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• 2018

An isotropic pitch precursor for fabricating carbon fibres was prepared by co-carbonization of ethylene bottom oil(EBO) and polyvinyl chloride (PVC). Various pre-treatments of EBO and PVC, and a high heating rate of $3^{\circ}C/min$ with no holding time, were evaluated for their effects on the oxidative stabilization process and the mechanical stability of the resulting fibres. Our stabilization process enhanced the volatilization, oxidative reaction and decomposition properties of the precursor pitch, while the addition of PVC both decreased the onset time and accelerated the oxidative reaction. Aliphatic carbon groups played a critical role in stabilization. Microstructural characterization indicated that these were first oxidised to carbon-oxygen single bonds and then converted to carbon-oxygen double bonds. Due to the higher heating rate and lack of a holding step during processing,the resulting thermoplastic fibers did not completely convert to thermoset materials, allowing partially melted, adjacent fibres to fuse. Fiber surfaces were smooth and homogeneous. Of the various methods evaluated herein, carbon fibers derived from pressure-treated EBO and PVC exhibited the highest tensile strength. This work shows that enhancing the naphthenic component of a pitch precursor through the co-carbonization of pre-treated EBO with PVC improves the oxidative properties of the resulting carbon fibers.

• Korean Chemical Engineering Research
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• 제57권1호
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• pp.118-123
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• 2019

본 연구에서는 리튬이온전지 음극소재인 흑연의 낮은 이론 용량을 개선하기 위해 흑연/실리콘/피치 음극 복합소재의 전기화학적 특성을 조사하였다. 흑연의 표면에 양친성 물질인 Polyvinylpyrrolidone (PVP)을 코팅한 후 (3-Aminopropyl)triethoxysilane(APTES)로 표면 처리된 실리카를 결합시켜 흑연/실리카를 합성하였으며, 실리카의 질량비에 따라 피치 소재로 코팅한 후 마그네슘 열 환원법을 통하여 실리카를 실리콘으로 환원시켜 흑연/실리콘/피치 복합소재를 제조하였다. 흑연/실리콘/피치 음극소재는 XRD, SEM과 TGA를 통해 물리적 특성을 분석하였으며, 전기화학적 특성은 1.0 M $LiPF_6$ (EC:DMC:EMC=1:1:1 vol%)의 전해액을 사용하여 충 방전 사이클, 율속, 순환전압전류, 임피던스 테스트를 통해 조사하였다. 제조된 흑연/실리콘/피치 복합소재의 실리카 비율이 28.5 wt% 일때 537 mAh/g의 높은 초기 방전 용량을 나타내었으며, 30 사이클까지의 사이클 성능은 95%로 매우 우수한 사이클 안정성과 율속 테스트에서 0.1 C/0.2 C 일 때 98% 회복을 나타냄을 확인하였다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 하계학술대회 논문집 B
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• pp.961-963
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• 2002

When high temperature superconducting(HTS) tapes are wound on former for HTS cable application, their critical characteristics are likely to be degraded seriously because of mechanical stress. In this study, prior to fabricate prototype HTS cables, we investigated the variation of critical characteristics of HTS tapes according to their pitch angles. For this work, we prepared the samples of HTS tapes on the former of which diameter is 3cm. Pitch angles of HTS tapes are $0^{\circ}$, $00^{\circ}$, $20^{\circ}$, $30^{\circ}$, $40^{\circ}$, respectively. We applied current up to 160 $A_{rms}$ to HTS tapes and investigated E-I characteristics. The critical current of HTS tapes was decreased as pitch angle increased. In addition, when the applied current was beyond their critical current, the rate of resistance increase of HTS tapes was in proportion to their critical current. Finally, We concluded that the pitch angles affected resistance increase of HTS tapes as well as critical current.

• 음성과학
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• 제4권2호
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• pp.115-139
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• 1998

The aim of this study is to develop an the assessment program for the singing voice which is based on the physiological and acoustic methods. 22 sopranos, 6 mezzo sopranos, 4 tenors and 4 baritones participated to these experiments. The results measured by Visi-Pitch, spectrograph, and strobo-scope can be summarized as follows: (1) The maximum phonation time of singers must over 14 second higher with one deep inspiration (2) The parts classified by vocal range using Visi-Pitch: soprano between 167Hz $\sim$1,190Hz, mezzo soprano between 146Hz$\sim$956Hz, tenor between 75Hz$\sim$503Hz and baritone between 73 Hz and 385 Hz. (3) Longitudinal glottal size of singers decreases depending on the high-low pitch variation while lattitudinal glottal size increases depending on high-low pitch variation. (4) Well-trained singers show over 5 times the vibrato rate of untrained singers and regular pitch variation during measured periods. Vibrato's intensity do not over 3 dB. (5) Singer's formant indicates professional voice depending on the each parts: 3,207 Hz for soprano, 3,057 Hz for mezzo soprano, 2,754 Hz for tenor and 2,560 Hz for baritone.. (6) $F_1$ of singing voice is higher than that of speech while $F_2\;and\;F_3$ of singing voice are lower than those of speech.

• 설비공학논문집
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• 제9권2호
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• pp.180-188
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• 1997

The theoretical analysis and experiment with simulator were performed to obtain the temperature distributions in radiant heating panel and heat supply from hot water to heating space for the purpose of the development of comfortable living space from a point of view of the improvement of air quality and the enhancement of system efficiency. The relations of various parameters, such as pipe pitch, room temperature as well as flow rate and temperature of hot water and so on, with the rate of heat supplied, mean temperature and maximum temperature difference at panel surface were discussed. The effects of these parameters were also verified on the thermal performance of heating panel using the relations which could be used for the optimal design and operation of the radiant heating panel.

• 말소리와 음성과학
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• 제8권4호
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• pp.115-122
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• 2016

This study investigates the acoustic-phonetic features and speech intelligibility of Lombard speech in children with intellectual disability, by examining the effect of Lombard speech at 3 levels of non-noise, 55dB, and 65dB. Eight children with intellectual disability read sentences and played speaking games, and their speech were analyzed in terms of intensity, pitch, vowel space of /a/, /i/, and /u/, VAI(3), articulation rate and speech intelligibility. Results showed, first, that intensity and pitch increased as noise level increased; second, that VAI(3) increased as the noise level increased; third, that articulation rate decreased as noise intensity increased; finally, that speech intelligibility increased as noise intensity increased. The Lombard speech changed the VAI(3), vowel space, articulation rate, speech intelligibility of the children with intellectual disability as well. This study suggests that the Lombard speech will be clinically useful for the persons who have intellectual disability and difficulties in self-control.

• International Journal of Computer Science & Network Security
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• 제21권5호
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• pp.129-132
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• 2021

Two feature selection approaches are analyzed in this study. First Approach used in this paper is Filter Approach which comprises of correlation technique. It provides two reduced feature sets using positive and negative correlation. Secondly Approach used in this paper is the wrapper approach which comprises of Sequential Forward Selection technique. The reduced feature set obtained by positive correlation results comprises of Rate of Acceleration, Intensity and Formant. The reduced feature set obtained by positive correlation results comprises of Rasta PLP, Log energy, Log power and Zero Crossing Rate. Pitch, Rate of Acceleration, Log Power, MFCC, LPCC is the reduced feature set yield as a result of Sequential Forwarding Selection.

• 한국항공우주학회지
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• 제34권5호
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• pp.65-73
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• 2006

위성이 발사체로부터 분리될 때 초기 각속도가 발생한다. B-dot 로직은 일반적으로 위성의 초기각속도 제어에 사용되나, 상대적으로 제어시간이 많이 소요된다는 단점이 있다. 이런 문제를 해결하기 위해 본 논문에서는 피치 바이어스 모멘텀 방식을 사용하는 초소형 위성에 적용 가능한 디텀블링(detumbling) 방식을 새롭게 제안하였다. 제안된 디텀블링 방식은 제어시간이 약 20분 이내로 기존의 방식에 비해 상당한 시간을 줄일 수 있다. 본 논문에서 제안한 디텀블링 방식을 사용할 경우 기존의 모멘텀 휠 초기구동 방식을 사용할 수 없다. 따라서 휠의 속도를 안정적으로 공칭 속도까지 증가시키는 방식을 제안하고 시뮬레이션을 통해 비교, 검증하였다. 시뮬레이션 결과 기존의 방식과 비교했을 때 제어시간을 단축할 수 있었으며 휠의 공칭 속도와 3축 안정화를 이룰 수 있었다.

• Tribology and Lubricants
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• 제32권4호
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• pp.119-124
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• 2016

In the sapphire wafering process, lapping is a crucial operation in order to reduce the damaged layer and achieve the target thickness. Many parameters, such as pressure, velocity, abrasive, slurry and plate, affect lapping characteristics. This paper presents an experimental investigation on the effect of the plate groove on the material removal rate and roughness of the wafer. We select the spiral pattern and rectangular type as the groove shapes. We vary the groove density by controlling the groove shape dimension, i.e., the groove width and pitch. As the groove density increases to 0.4, the material removal rate increases and gradually reaches a saturation point. When the groove density is low, the pressing load is mostly supported by the thick film, and only a small amount acts on the abrasives resulting to a low material removal rate. The roughness decreases on increasing the groove density up to 0.3 because thick film makes partial participations of large abrasives which make deep scratches. From these results, we could conclude that the groove affects the contact condition between the wafer and plate. At the same groove density, the pitch has more influence on reducing the film thickness than the groove width. By decreasing the groove density with a smaller pitch and larger groove width, we could achieve a high material removal rate and low roughness. These results would be helpful in understanding the groove effects and determining the appropriate groove design.