• Journal of Conservation Science
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• v.30 no.1
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• pp.39-53
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• 2014

The decorative painting at court was practical and functional role by decorated the inside and outside of palace. Especially, the type of the Painting of sun, moon and five peaks and Heavenly peach were the one of representative decorative paintings, produced for authority of king and longevity wish. However, there are not clarify verification of production period and installation place in the Painting of sun, moon and five peaks and Heavenly peach, that made before $19^{th}$ century, in present. Therefore, this study has a meaning on find production period, installation place and techniques of paint through conservation scientific research of the Painting of sun, moon and five peaks and Heavenly peach that introduced the first time in National Museum of Korea. Double side paintings in two-panel folding screen style and tortoise shell shape of window is the first time research in the decorative painting at court. This study also explain that they were installed in Hamin Jeong from ChanggyeongGungyeonggeon Dogam Uigwe(1834) through research of the original measurement, contrast of palace in present and Uigwe record. It will be contributed to a study of the Painting of sun, moon and five peaks and Heavenly peach in the early $19^{th}$ century.

• Journal of Conservation Science
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• v.29 no.3
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• pp.261-277
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• 2013

This study aims to research the relationship between whitewares and their rare materials from the site of Yanggu and Bunwon through the componential characteristic of the excavated whitewares from the 1st and the 2nd kilns of Chiljeon-ri in Bangsan-myeon, Yanggu-gun. As a result, the sherds were devided according to the chemical compositions of the body and the glaze via their respective production era. However, it considered that the whitewares from Chiljeon-ri had been manufactured with geochemically similar materials and the production process, such as refining and combining materials, had been different. It assumed that the firing temperatures of the whitewares from Chiljeon-ri were around $1,100-1,200^{\circ}C$ and substantially lower than for general whitewares. In the componential analysis, there were disparate properties in the cobalt pigment, which contained trace elements and rare earth elements. A review of the literature revealed a correlation between the whitewares from the late Chosun kiln site in Bunwon-ri and the raw materials from Yanggu-gun, but this was there were various techniques for refining and combining materials in Bunwon-ri.

• Korean Journal of Heritage: History & Science
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• v.48 no.3
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• pp.46-59
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• 2015

This study was conducted focusing on the stability on materials of cultural property when the fumigant containing ethylene oxide was applied among some kinds of fumigant. Four kinds of specimens from paper, textile, metal and pigment were prepared to compare color difference, weight, surface condition before and after treatment and FT-IR analysis was carried out on specimens of paper and textile. In the case of fumigation treatment, it was conducted by two groups : one is made up of specimens with the non-fumigation as control groups, the other is made up of specimens treated with ethylene oxide + $HFC_{134a}$ and ethylene oxide + $CO_2$ as experimental groups. The result of color difference showed that there were color differences on the specimens of Hanji(Korean traditional paper), silver, cotton, ramie and yellow pigment. Especially, it was found out there was color change more than 6.0 on average from the silver specimen. However, in the silver specimen's case, color change in the non-fumigated specimen was relatively higher than those of fumigant-treated specimens, therefore, it is judged that fumigant doesn't have a decisive effect on color change in specimens, but required caution while fumigating. The result of weight measurement, there were totally 0~2% weight changes and the slightest change was found in the metal specimen, the biggest change in the papers. The result of microscopic observation on the surface of specimens showed color changes and especially, the biggest change on the silver specimen was observed. But no change in components was identified from FT-IR analysis of papers and textiles.

• Journal of Conservation Science
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• v.37 no.6
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• pp.712-722
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• 2021

This study presents a method for conserving shamanistic spirits in Chiseonggwang Buddha. Scientific investigation has revealed that these spirits have been subject to degeneration as a result of severe exfoliation and pollution. The materials and preservation treatment techniques used in create these shamanistic spirits were identified through visual inspection and using appropriate scientific equipment. The different types of background paper, background material, and color pigments used in create the shamanistic spirits were analyzed using a colorimeter, stereoscopic microscope, and SEM-EDS techniques. The analysis revealed that the pulp paper was used as the background and synthetic fiber polyester as the background material. In addition, the study of the pigment revealed that the color components were all synthetic, except for red lead [Pb₃O₄] and oyster shell white [CaCO₃]. Moreover, it was confirmed that the green pigment, identified as emerald green [Cu(C₂H₃O₂)₂.3Cu(AsO₂)₂], was a major component of shamanistic spirits in the late 19^th century. The shamanistic spirits in Chiseonggwang Buddha were conserved by identifying raw materials and pigments through this detailed analysis.

• Korean Journal of Heritage: History & Science
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• v.56 no.3
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• pp.118-135
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• 2023

Hanging boards of the Joseon royal court are hung on buildings related to the royal family, such as palaces and Jongmyo Shrine, to show the hierarchy and character of the building. In addition, the manufacturing method and materials are recorded in the royal protocols of the Joseon Dynasty, so it is an important material for studying the manufacturing method and material changes at that time. However, the hanging boards were restored several times due to fire or war, and it is presumed that there is a change in the original form and material of the hanging boards. In particular, many hanging boards of the Joseon royal court were written with calligraphy by kings, so there are many forms consisting of gold letters on a black background. This study tried to analyze the pigments remaining in the letters of 44 of the Joseon royal hanging boards, which are presumed to be gold letters, and to find out the changes in the hanging board production method and materials by referring to the analysis results. The letters of the hanging boards studied were classified according to the current state of the gold pigment and the detected components. As a result of the analysis of character pigments, 24 embossing techniques and 5 intaglio techniques were mainly detected with gold (Au), but 15 embossing techniques were detected with brass (Cu, Zn). Only blue-green substances, not gold pigments, remain in some of the hanging boards in which brass components were detected. A reproduction experiment was conducted because the pigments of the brass component were not recorded in the literature and were not currently used as Dancheong pigments. In the reproduction experiment, it was difficult to confirm the application and use of brass pigments due to the limitations of materials, but it is judged that research on the timing and method of using brass pigments is needed in the future.

• Korean Journal of Heritage: History & Science
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• v.48 no.1
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• pp.132-147
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• 2015

In this article, the research trends regarding the analysis and restoration of the pigments applied on colored cultural properties during past 25 years are reviewed and the future research direction in this field of study is proposed. There are over 100 different pieces of the colored cultural property samples that have been analyzed in Korea during the time and are increasing numbers of studies on comparative investigations as well. In addition, new analysis techniques have been introduced to surpass the limitation of the current analysis techniques and the database construction has been developed tremendously, which will enhance the analysis reliability, indicating fast growth in the related research areas. There are also studies on finding new materials to replace the traditional ingredients for producing color pigments and related other materials to overcome the limitation of the traditional ingredients on top of the steady number of studies on reproduction and restoration of the traditional pigments. These various research efforts will bring much development in this area of research. One suggestion to be made is that there need to be long term planned research works for certain type of studies. For instance, the effect to the colored cultural properties due to the environmental change is one of important research topics that should be carefully studied, which requires longer time period and also more patience than the research works in the current and past trends.

• Korean Journal of Food Science and Technology
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• v.33 no.5
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• pp.641-644
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• 2001

This study was performed for development of new analytical method of monascus pigments in foods. In this method, analysis of monascus pigment in foods has been carried out by detection of monascin and ankaflavin of the main color component of monascus pigment as indicator compounds. Monascin and ankaflavin were isolated and identified by TLC, HPLC, Prep. HPLC, $^{1}H-NMR$ and Mass spectrophotometer. The analysis of monascin and ankaflavin in foods such as massal, sausage, mixed press ham, mixed fish sausage, semi-dried sausage and syrup was performed by using reverse phase high performance liquid chromatograph with Capcell Pak C18 column at wave length 390 nm. The quantitative results of monascin were as follows : $0.01{\sim}3.31\;{\mu}g/g$ item in massal, $0.05{\sim}0.10\;{\mu}g/g$ in mixed fish sausage, and $0.34{\sim}0.35\;{\mu}g/g$ in semi-dried sausage. But the quantitative results of ankaflavin were as follows: $0.02{\sim}0.89\;{\mu}g/g$ in massal, ankaflavin were not founded in other samples.

• Korean Journal of Heritage: History & Science
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• v.54 no.4
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• pp.22-35
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• 2021

Recently, as the climate changes rapidly and the prevalence of airborne fine particulate matter increases, the pattern of pollutants in the atmospheric environment is also changing. Therefore, the importance of studying the stability of pigments used in colored cultural properties is emerging. Hoecheong is an inorganic blue glass pigment called smalt; it is made by using cobalt as a coloring element in potash glass, and was widely used in colored cultural assets, such as murals and paintings. In this study, we collected three other hoecheong pigments to analyze their properties. The percentage of Co and K contained are different according to the manufacturer, and the smalt-3 sample has a lower cobalt content (15.1 wt.%) and higher potassium content (29.6 wt.%). After this analysis, colored specimens were prepared. Prepared specimens were exposed to ultra-violet rays, CO₂/NO₂, and NaCl, which are known to have the greatest influence on the stability of pigments. We found that factors affecting the color stability were NO₂ gas, ultra-violet rays, and water-soluble salts (NaCl). Among them, NO₂ has the most severe impact on color change of the pigments. Results of the component analysis showed that the color change depends on the potassium and cobalt content of the hoecheong pigment. Among the specimens, smalt-3 showed the most vulnerability after exposure to NO₂ gas and water-soluble salts. Pigment film stability is affected by watersoluble salts, giving rise not only to color change, but also weakening the physical properties of the film. However, there was no significant change in composition and color after exposure to CO₂ gas. In conclusion, we found that hoecheong pigments underwent color change and increased instability of the coating film when exposed to any of the atmospheric environmental factors used in this study, except for CO₂.

• Analytical Science and Technology
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• v.24 no.6
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• pp.429-434
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• 2011

In this study, a wet-sampler was developed for collection in water and simultaneous fractionation of micron-sized particles (e.g., pigment, airborne, etc.). In this new device, three cylinders (partially filled with water) through which air was forced to pass for sample collection are connected in a series. Particles of different sizes are collected in different cylinders, allowing simultaneous fractionation. An uniqueness of this new device is that it does not use any membrane filter. Microparticles are collected directly in cylinders filled partially with water. Also the particles are simultaneously fractionated within this device while they are being collected. The new device was employed for collection of airborne particles. The collected airborne particles were fractionated by using sedimentation field-flow fractionation, SdFFF), and observed with an optical microscopy (OM) for size and shape analysis. Also AAS and ICP-AES were used for composition analysis of the airborne particles. It is expected that the new device is applicable to collection and analysis of size distribution of various types of microparticles.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.20 no.2
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• pp.71-77
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• 2015

High-Performance Liquid Chromatography (HPLC) is a widely used method for measuring the concentration of chlorophyll a as an indicator for estimating phytoplankton biomass and primary production and also for identifying carotenoids to determine phytoplankton composition. However, tissue grinding procedure requires a lot of time and experience in the analysis of multiple sample. Accordingly, we measured the concentrations of photosynthetic pigments before and after the grinding, in order to understand the grinding effects on the quantitative analysis of chlorophylls and carotenoids using samples from southwestern East Sea. When tissue grinding procedure was omitted, we found that Chl a concentrations were underestimated up to 45% in average. Also, concentrations of Zeaxanthin, 19'-butanoyloxyfucoxanthin, 19'-hexanoyloxyfucoxanthin, biomarkers of pico and nano-size phytoplankton, were underestimated up to maximum 77~85% without grinding. We found that the smaller the phytoplankton, the bigger underestimation of their biomarker pigments concentration is likely to happen due to the incomplete extraction. Thus, tissue grinding procedure should be included for HPLC analysis in all cases, to prevent the underestimation of not only Chl a but also carotenoids pigments.