• Title/Summary/Keyword: Physico-chemical Properties

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Changes in physico-chemical properties of expanded tobacco leaves by $CO_2$ process according to the storage periods (저장기간에 따른 $CO_2$ 팽화처리 원료잎담배의 이화학적 특성 변화)

  • 김병구;이규서
    • Journal of the Korean Society of Tobacco Science
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    • v.22 no.2
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    • pp.143-150
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    • 2000
  • This study was carried out to investigate the effect of storage period on the physico-chemical properties of tobacco leaves expanded by $CO_2$. The flue-cured and burley tobacco leaves produced from 1996 to 1999 were processed, and stored for that year or 3 years in processing plant. As compared with 1996 crop, the expanded rate of flue-cured tobacco leaves in 1999 crop was higher approximately 18%, while that of burley was higher about 10%. The filling capacity of cigarettes was decreased as storage time became shorter, but the combustibility was improved. The rate of large particles (over 3.36mm) of expanded tobacco showed decreasing tendency as the storage period became longer. The change rate of chemical contents in tobacco leaves between before and after expansion had no significant difference among corp years. The tar and CO contents of cigarettes smoke were reduced in the case of flue-cured tobacco leaves as storage time became shorter, while they were slightly increased in the case of burley tobacco leaves. The ammonia content of burley leaves was decreased remarkably in 1996 and 1999 crop.

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Physico-Chemical Properties of Ginseng Leaf Tea As Affected by Decontamination Treatment (인삼엽록차의 살균처리에 따른 이화학적 특성 변화)

  • 김영회;권중호;변명우;이수정;조한옥
    • Journal of Food Hygiene and Safety
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    • v.6 no.1
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    • pp.49-56
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    • 1991
  • Physico-chemical properties were investigated on ginseng leaf tea which was decontaminated by the current ethylene oxide fumigation and gamma irradiation, respectively. Chemical components such as soluble matter, saponin and polyphenols were found to be stable to both treatments, while ascorbic acid and chlorophylls were relatively labile to fumigation and irradiation more than 5 kGy. Instrumental analysis has shown that EO fumigation causes apparent changes in pH and color of extracts and volatile profile of the sample, as compared to negligible changes in the irradiated sample at a decontaminating dose, 5 kGy.

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Physico-Chemical Properties of Soils at the Ground of Landscape Planting in Reclaimed Land from the Sea (임해매립지의 식재지반별 토양 물리·화학적 특성)

  • Kim, Do-Gyun
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.4 no.4
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    • pp.12-18
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    • 2001
  • This study was carried out to analyze physico-chemical properties of soils at the ground of landscape planting in reclaimed land from the sea on Kwangyang Bay, South Korea. Physico-chemical properties of soils at each planting grounds were tested by ANOVA and were significantly(P<0.01) different. The difference came from the soil properties of the covered soil, the disturbance applied to the soil with land use and the accumulation of organic matter after landscape planting. Soil hardness, pH, ECe, Na and K level were in a stable condition at high then low of ground height for landscape planting. Organic matter accumulation was greater at lower planting grounds then top and slope ground of big mounding. The planting grounds of favorable growth for landscape trees were determined as following order : the slope ground and the top ground of big mounding>the ground of medium mounding>the coved ground of improve soil>the lower ground of big mounding>the filled ground of improve soil.

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Environmental Distribution and Fate of Perfluorinated Compounds (PFCs) as Emerging POPs: Physico-Chemical Properties, Emission, Contamination Level, Inter-phase Distribution and Long-Range Transport (잠재적 POPs로서의 과불소화화합물의 환경 내 분포 및 거동: 물성, 환경 내 농도수준, 상 분배 및 장거리이동을 중심으로)

  • Kim, Seung-Kyu
    • Environmental Analysis Health and Toxicology
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    • v.23 no.3
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    • pp.143-164
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    • 2008
  • Concern about perfluorinated compounds (PFCs) is growing nationally as well as globally. PFCs could be considered emerging POPs due to their environmentally persistent, bioaccumulative, and potentially harmful properties. Moreover. perfluoroalkylates (PFAs) such as PFOS and PFOA are reported to experience long-range transport (LRT) to the Arctic in spite of their low volatility and strong solubility. The possible pathways contributing to LRT have been proposed but are still in debate in combination with unclear source definition and uncertain physico-chemical properties. The environmental fate of PFCs is more complicated because of the presence of precursors that are degraded to PFAs and are extremely different from their daughters, PFAs. in physico-chemical properties. To what extent and through what pathways are human and wildlife exposed is determined by the environmental fate and distribution of PFCs. To define uncertainties in fate and distribution thus is critical to prevent erroneous policy and/or determination related with exposure and risk reduction. This article aimed to review controversy and/or uncertain issues for the environmental fate and distribution of PFCs and to prospect research topics necessary to dissolve uncertainties.

Changes in Physico-Chemical Properties of Salted Sea Mustard (Undaria Pinnatifida) by Gamma Irradiation (염장미역의 감마선 조사에 따른 이화확적 특성 변화)

  • 변명우;권중호;이수정;남상명;조한옥
    • Journal of Food Hygiene and Safety
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    • v.6 no.3
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    • pp.165-169
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    • 1991
  • The effect of gamma irradiation on physico-chemical properties of salted sea mustard (Undaria pinnatifida) was investigated. Chlorophyll and carotenoid pigment of salted sea mustard were partially decreased by irradiation. However there was no significant difference in the retention rate of pigment between control and 2 kGy-irradiated samples after six months of storage at around $10^{\circ}C$, ranging values of 74 to 77% in chlorophyll and 54 to 56% in carotenoid. Total organic acids and volatile acids associated with the organoleptic quality of sea mustard increased in the samples of lower salt concentrations and of higher storage temperatures. The softening of sample tissue by irradiation was shown to be correlated with the extraction properties of alginic acid.

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The Soil Improvement and Plant Growth on the Newly-Reclaimed Sloped land VI. Relationship between annual change of soil phsico-chemical properties and yield of silage corn (신개간경사지 토양개량과 작물생육에 관한 연구 VI. 토양의 물리화학성 년차간 변화가 옥수수 청예수량에 미치는 영향)

  • 허봉구;김무성
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.11 no.1
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    • pp.22-29
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    • 1991
  • This study was experimented to obtain the basic information on the changeable aspect and improvement of soil fertility in newly-reclaimed sloped land. Silage corn was cultivated under the six different treatments for 4 years. The relation between the amount or ratio of annual changes of soil physico-chemical properties and yield of silage corn were analyzed. Soil bulk density was decreased in 3rd year at topsoil, but that decreased in 4th year at subsoil. Soil organic matter also decreased in 2nd year at topsoil, and decreased continuously at subsoil. Bulk density and hardness of soil depths showed significant negative simple correlation with dry matter yield and cation exchange capacity showed positive. Correlation coefficient of chemical properties with dry matter yield were low. The range of annual changes of moisture percent, hardness and organic matter were wider than the other properties. The significantly different of physical properties were higher than the chemical properties, and those of topsoil were higher than subsoil. According to multiple regression between yield and physico-chemical properties of subsoil, bulk density and cation exchange capacity were in the greatest contribution at the variations, but bulk density was greatest at the ratios.

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Changes in Physico-chemical Properties of Single or Mixture State of DMF, MEK and Toluene in Synthetic Leather Factories (합성피혁제조업에서 취급하는 DMF, MEK, Toluene의 단일과 혼합물질 상태에 따른 물리·화학적 특성 변화)

  • Kim, Ki-Woong;Won, Yong Lim;Park, Dong Jin;Lee, Jung-Suk;Han, In-Soo;Lee, Su-Hee
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.2
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    • pp.238-245
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    • 2014
  • Objectives: It was known that workers in synthetic leather company are mainly co-exposed to dimethylformamide(DMF) with methyl ethyl ketone(MEK) or toluene(TOL) instead of a single dimethylformamide. This study was examined to the physico-chemical properties in single DMF and binary mixture DMF with MEK or TOL. Materials: Physico-chemical properties were measured by Korean and American Standard Test Methods. Results: Boiling point, specific gravity and flash point in single DMF were significantly higher than binary mixture DMF with MEK or TOL and such difference was dependent on the mixing ratio of MEK and TOL, and low explosion limit in binary mixture DMF with TOL was only significantly lower than single DMF. However, Reid vapor pressure had significantly higher in binary mixture DMF with MEK or TOL compared with single DMF. Conclusions: Our results demonstrate that the binary mixture DMF with MEK or TOL synergistically increases volatilization of DMF. It was concluded that the interaction between DMF and MEK and/or TOL might play a key role in the volatilization process of DMF under environmental conditions of workplace.

Characterizing a Full Spectrum of Physico-Chemical Properties of Ginsenosides Rb1 and Rg1 to Be Proposed as Standard Reference Materials

  • Kim, Il-Woung;Hong, Hee-Do;Choi, Sang-Yoon;Hwang, Da-Hye;Her, Youl;Kim, Si-Kwan
    • Journal of Ginseng Research
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    • v.35 no.4
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    • pp.487-496
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    • 2011
  • Good manufacturing practice (GMP)-based quality control is an integral component of the common technical document, a formal documentation process for applying a marketing authorization holder to those countries where ginseng is classified as a medicine. In addition, authentication of the physico-chemical properties of ginsenoside reference materials, and qualitative and quantitative batch analytical data based on validated analytical procedures are prerequisites for certifying GMP. Therefore, the aim of this study was to propose an authentication process for isolated ginsenosides $Rb_1$ and $Rg_1$ as reference materials (RM) and for these compounds to be designated as RMs for ginseng preparations throughout the world. Ginsenoside $Rb_1$ and $Rg_1$ were isolated by Diaion HP-20 adsorption chromatography, silica gel flash chromatography, recrystallization, and preparative HPLC. HPLC fractions corresponding to those two ginsenosides were recrystallized in appropriate solvents for the analysis of physico-chemical properties. Documentation of the isolated ginsenosides was made according to the method proposed by Gaedcke and Steinhoff. The ginsenosides were subjected to analyses of their general characteristics, identification, purity, content quantitation, and mass balance tests. The isolated ginsenosides were proven to be a single compound when analyzed by three different HPLC systems. Also, the water content was found to be 0.940% for $Rb_1$ and 0.485% for $Rg_1$, meaning that the net mass balance for ginsenoside $Rb_1$ and $Rg_1$ were 99.060% and 99.515%, respectively. From these results, we could assess and propose a full spectrum of physicochemical properties for the ginsenosides $Rb_1$ and $Rg_1$ as standard reference materials for GMP-based quality control.

Physico-chemical Properties of Glucitol Fatty Acid Polyesters -Potential Fat Substitutes- (유지 대체물질로서 Glucitol Fatty Acid Polyesters의 이화학적 특성)

  • Chung, Ha-Yull;Yoon, Hee-Nam;Kong, Un-Young;Kim, Jung-Han
    • Korean Journal of Food Science and Technology
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    • v.25 no.5
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    • pp.438-443
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    • 1993
  • Physico-chemical properties of glucitol fatty acid polyesters (GPE)-one of the potential fat substitutes-were analyzed and compared with conventional edible oil. The refractive Index, apparent viscosity and melting point of S-GPE (soybean oil GPE) were 1.472, 103 cps. at $37^{circ}C\;and\;-53^{\circ}C$, respectively. S-GPE were liquid at room teperature and the Yellowness of S-GPE was slightly stronger than that of soybean oil. The acid value and smoke point of S-GPE were 0.06 and $200^{\circ}C$. To supplement the weak thermal stability of S-PEG, SP-GPE (soybean-palm blended oil GPE) was prepared with soybeanpalm blended oil (70% of soybean oil and 30% of palm oil). The appearance and color of SP-GPE was not much different from S-GPE but the smoke point of that was increased to $210^{\circ}C$. It means that thermal stability of GPE can be enhanced by increasing saturation of the fatty acid composing GPE. Because most of physico-chemical properties of S-GPE or SP-GPE were similar to conventional edible oil, they are expected to be considered as a potential fat substitute with further study for confirming the safety.

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Physico-Chemical Properties on the Management groups of Upland Soils in Korea (밭유형(類型)에 따른 토양(土壤)의 이화학적(理化學的) 특성(特性))

  • Rim, Sang-Kyu;Hur, Bong-Koo;Jung, Sug-Jae;Hyeon, Geun-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.30 no.1
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    • pp.67-71
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    • 1997
  • To grasp the physico-chemical properties on the management groups of upland soil, the data obtained from the detailed soil survey which conducted from 1964 to 1979 by Agricultural sciences Institute, were analyzed and classified. The clay content in A horizon soil was low in sandy textured and well adapted types and high in heavy clayey type, and that in B horizon was lowest in volcanic ash type and highest in heavy clayey type. High organic matter content was found in the volcanic ash and plateau type. The correlations among soil physico-chemical properties were significant. Especially canon exchange capacity of B horizon soil was highly correlated with the content of available water, clay, silt and organic matter positively.

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