• 제목/요약/키워드: Physical and chemical transformation

검색결과 38건 처리시간 0.027초

Physical property control for a batch polymerization reactor

  • Kim, In-Sun;Ahn, Sung-Mo;Rhee, Hyun-Ku
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1996년도 Proceedings of the Korea Automatic Control Conference, 11th (KACC); Pohang, Korea; 24-26 Oct. 1996
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    • pp.263-266
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    • 1996
  • A method to determine an optimal temperature trajectory that guarantees polymer products having controlled molecular weight distribution and desired values of molecular weight is presented. The coordinate transformation method and the optimal control theory are applied to a batch PMMA polymerization system to calculate the optimal temperature trajectory. Coordinate transformation method converts the original fixed-end-point, free-end-time problem to a free-end-point, fixed-end-time problem. The idea is that by making the reactor temperature track the optimal temperature trajectory one may be able to produce polymer products having the prespecified physical property in a minimum time. The on-line control experiments with the PID control algorithm have been conducted to establish the validity of the scheme proposed in this study. The experimental results show that prespecified polymer product could be obtained with tracking the calculated optimal temperature trajectory.

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음식물 쓰레기 소멸화에 관한 연구 (A Study on Reduction of Food Waste)

  • 서명교;이상봉;이국의;이상훈
    • 한국환경보건학회지
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    • 제27권1호
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    • pp.14-19
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    • 2001
  • The physical and chemical transformation and reduction degree of food waste were investigated in a food waste reduction machine using thermophilic bacteria. The first operation of the reduction machine for grain, vegetables, fishes and flesh wastes proceeded during three weeks. The first and second reduction percentages of the wastes were 98.3% and 93.2%, respectively. The residue of food waste was composed of fruits, fish, and vegetables. The temperature distribution of the reduction machine ranged between 30 and 6$0^{\circ}C$ appropriate for growth of thermophilic bacteria. At initial stage the pH in the reduction machine decreased with organic acids produced, but increased as the organic acids decomposed by different thermophilic bacteria. In the reduction machine, the moisture content of the food waste was reduced from 80-90% to 10-20% after 24 hours, and the salinity of residue was 0.29% after the second operation. The degree of odor was most high between 2 and 4 hours.

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Ginsenoside Rg3의 함량증가를 위한 변환 기술 (Transformation Techniques for the Large Scale Production of Ginsenoside Rg3)

  • 남기열;최재을;박종대
    • 한국약용작물학회지
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    • 제21권5호
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    • pp.401-414
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    • 2013
  • Ginsenoside Rg3 (G-Rg3) contained only in red ginseng has been found to show various pharmacological effects such as an anticancer, antiangiogenetic, antimetastastic, liver protective, neuroprotective immunomodulating, vasorelaxative, antidiabetic, insulin secretion promoting and antioxidant activities. It is well known that G-Rg3 could be divided into 20(R)-Rg3 and 20(S)-Rg3 according to the hydroxyl group attached to C-20 of aglycone, whose structural characteristics show different pharmacological activities. It has been reported that G-Rg3 is metabolized to G-Rh2 and protopanaxadiol by the conditions of the gastric acid or intestinal bacteria, thereby these metabolites could be absorbed, suggesting its absolute bioavailability (2.63%) to be very low. Therefore, we reviewed the chemical, physical and biological transformation methods for the production on a large scale of G-Rg3 with various pharmacological effects. We also examined the influence of acid and heat treatment-induced potentials on for the preparation method of higher G-Rg3 content in ginseng and ginseng products. Futhermore, the microbial and enzymatic bio-conversion technologies could be more efficient in terms of high selectivity, efficiency and productivity. The present review discusses the available technologies for G-Rg3 production on a large scale using chemical and biological transformation.

ABS수지 성능 최적화 방안 (The Optimum Solution for the Best Performance of ABS)

  • 문홍국;김대수
    • 폴리머
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    • 제31권2호
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    • pp.105-110
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    • 2007
  • ABS(acrylonitrile butadiene styrene)수지의 성능저하에 미치는 영향을 알아보기 위해 ABS, 도장, 도료, 사출 등 전 부문에 대한 영향도를 파악함으로써 ABS수지의 성능저하를 최소화하기 위한 최적화 방안을 수립하였다. ABS수지의 성능저하에 영향을 미치는 인자를 실험실 규모에서 검토한 결과 변형에 의한 기계적 요인보다는 사용된 화학물질의 화학적, 물리적 특성에 의한 요인이 지배적인 것으로 나타났다. ABS수지를 이용한 제조 현장에서 여러 인자(ABS수지, 사출, 화학물질, 도장 등)에 대해 검토한 결과 ABS수지 표면에 직접적으로 접촉하는 화학물질인 희석제 (시너)에 의한 영향도가 가장 큼을 확인할 수 있었다. 이번 연구 결과를 통해 수지의 성능저하에 미치는 각 인자별 영향도 수준 평가가 가능하게 되었으며, 이를 토대로 양산 시 나타나는 도장불량 등의 문제해결을 위한 관리 과정의 체계화 및 품질 변동요인의 제거 방안을 구체화할 수 있었다.

쌍극자모멘트 행렬요소를 계산하는 두가지 방법 (Two Method for Evaluation of the Dipole Moment Matrix Elements)

  • 안상운
    • 대한화학회지
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    • 제22권4호
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    • pp.229-238
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    • 1978
  • Spherical harmonic의 전개방법과 쌍극자모멘트의 행렬요소를 Mulliken의 overlap integral로 전환시키는 방법을 사용하여 쌍극자모멘트의 행렬요소를 계산하는 두가지 방법을 발전시켰다. 이 두 방법에 의하여 계산한 쌍극자모멘트행렬요소의 값은 서로 일치하였다.

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Synthesis of Cubic Boron Nitride by Al-Mg Solvents

  • Park, Jong-Ku;Park, S.T.;S.K. Singhal;S. J. Cui;K. Y. Eun
    • The Korean Journal of Ceramics
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    • 제3권3호
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    • pp.187-190
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    • 1997
  • The aluminum-magnesium (Al-Mg) aklloys have been proved to be an effective solvent for synthesis of cubic-phase boron nitride (cBN) from hexagonal-phase boron nitride (hBN) at the conditions of high pressures and high temperatures (HP/HT). Various kinds of hBN powders having different crystallinity have been tested for cBN synthesis with Al-Mg solvents. The conversion ratio from hBN to cBN and the shape of synthesized cBN crystals appeared to be affected strongly by chemical composition and added amount of Al-Mg solvents as well as crystallinity of BN powders. As the magnesium content increased in the Al-Mg solvents, the conversion ratio increased and the size of cBN crystals became larger. The crystal facets developed well in the specimens with solvents having high Mg content. It was observed that a hBNlongrightarrowcBN transformation occurred more easily in the specimens having well crystallized hBN powders. Amorphous BN having much $B_2O_3$ impurity exhibited a low threshold temperature for transformation to cBN, which was attributed to crystallization of amorphous BN to well crystallized hBN prior to transformation into cBN with help of $B_2O_3$.

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분말 소화약제가 흡착된 제올라이트의 소화 특성 (Extinguishing Characteristics of Zeolite adsorbed Dry Chemical Powder)

  • 신창섭;박호준
    • 한국안전학회지
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    • 제27권6호
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    • pp.59-63
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    • 2012
  • The use of dry chemical powder has been increased as it can be stored for a long period and sustain in stable condition compared to gas or liquid phase extinguishing agents. A new type of dry chemical powder using Zeolite was produced in the research. Chemical powder was adsorbed into Zeolite 13X, a porous material appearing negative catalytic effect, to create extinguishing powder obtaining core shell structure and measured physical properties and run a small scale fire extinguishment. SEM, XRD, TA analysis was also executed, and extinguishing characteristics were measured by fire extinguishing experiment on oil pool fire. The experiment showed that the average particle size of Zeolite 13X was equivalent, indicating about $3{\pm}1{\mu}m$ and thermal analysis result illustrated that Zeolite 13X showed exothermic reaction peaks at $900^{\circ}C$ due to solid-state transformation. Extinguishing characteristics on oil fire of $NaHCO_3$/Zeolite 13X and $NH_4H_2PO_4$/Zeolite were improved, influenced by adsorbed extinguishing powders on Zeolite 13X and Zeolite 13X that contains high phase transition temperature.

Study on Recycling of Scraps from Process of Silicon-single-crystal for Semiconductor

  • Lee, Sang-Hoon;Lee, Kwan-Hee;Hiroshi Okamoto
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.705-710
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    • 2001
  • So for the quartz-glassy crucible wastes which was used for pulling up silicon-single-crystal ingot have simply reused for refractory raw-materials, or exhausted. This study is concerned on the advanced recycling-technology that is obtained by the proper micro-particle preparation process in order to fabricate fine amorphous silica filler for EMC (Epoxy Molding Compound). Therefore, this paper will deal with the physical, chemical and thermal pre-treatment process for efficient impurity removal and with the proper micro-particle process for producing the amorphous silicafiller. In view of the results, if the chemical, physical and thermal pre-treatment process for efficient elimination of impurity was passed, the purity of wasted fused glassy crucible is almost equal to the its of first anhydrous quartz glass. Thus, it was understood that this wasted fused glassy crucible was sufficient value of recycling, though it was damaged. When the ingot was fabricated, Phase transformation of crystallization by heat treatment (heat hysteresis phenomenon) was not changed. So, it was understood that as fused silica in the amorphous state, as It is, recycling possibility was very high

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광섬유 센서를 이용한 초음파 검출 (A Fiber-Optic Sensor for Ultrasonic Measurement)

  • 심승환;이광식;이동인;이상훈;김달우
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2001년도 하계학술대회 논문집 C
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    • pp.1715-1717
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    • 2001
  • The partial-discharge(PD) is accompanied by physical and chemical phenomena, such as heat, light, noise gas, chemical transformation, electric current, and electromagnetic radiation. The PD can be detected by measuring one of these changes. Although some techniques are employed in this purpose, several obstacles interfere with an on-line measurement. Now, a fiber-optic sensor for detecting ultrasonics is suggested for the on line measurement system with high accuracy. This paper describes the basic principles fiber-optic sensor for ultrasonic measurement.

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광섬유 Mach-Zehnder 간섭계를 이용한 부분방전 초음파 검출특성 (Ultrasonic-detecting Characteristics by Partial Discharge using the Fiber Mach-Zehnder Interferometerin Insulating Oil)

  • 심승환;이광식;이상훈;김달우
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2002년도 학술대회논문집
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    • pp.325-328
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    • 2002
  • The partial-discharge(PD) is accompanied by physical and chemical phenomena, such as heat, light, noise, gas, chemical transformation, electric current, and electromagnetic radiation. The PD can be detected by measuring one of these changes. Although some techniques are employed in this purpose, several obstacles interfere with an on-line measurement. Now a fiber-optic sensor for detecting ultrasonics is suggested for the on line measurement system with high accuracy. In this paper, an optical fiber sensor utilizing the principal of Mach-Zehnder interferometer was proposed to detect the discharge signal.

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