• Journal of the Korean Chemical Society
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• v.40 no.5
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• pp.295-301
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• 1996

A series of solid solutions of the $CaGa_1-xFexO_3-y$ system with the compositions of x=0.25, 0.50, 0.75, and 1.00 has been prepared at $1150^{\circ}C$ under an atmospheric air pressure. The structure, nonstoichiometric chemical formula, and the distribution of cations for the solid solutions are determined by X-ray diffraction analysis, Mohr salt titration, Mossbauer spectroscopic analysis. Their physical properties are discussed with electrical conductivity and magnetic measurements. The crystal system of all the compositions is a brownmillerite orthorhombic system from the X-ray diffraction analysis and the reduced lattice volume increases linearly with x value except that of the composition of x=0.25. All the solid solutions do not contain $Fe^{4+}$ ion and the mole number of oxygen vacancies or y value is 0.50 from Mohr salt analysis. The oxidation state of Fe ion, the coordination state, the structure change in the Brownmillerite-type structure, and the distribution of $Ga^{3+}$ and $Fe^{3+}$ ions are discussed with Mossbauer spectroscopic analysis. The electrical conductivity increases and activation energy decreases, as x value increases. The traditional semiconducting property of this system is described in terms of band theory. The compositions of x=0.50∼1.00 show a thermal magnetic hysteresis in the magnetic measurement with the cooling conditions, which is discussed in terms of the space group and Dzyaloshinsky-Moriya interaction.

• The Korean Journal of Ceramics
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• v.6 no.2
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• pp.100-102
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• 2000

Co fine particles were dispersed in Au metal and $AlO_x$ amorphous matrices by vacuum evaporation and rf-sputtering, respectively, thus forming granular composite films having chemical compositions of $Co_{0.59}-Au_{0.41}$ and $Co_{0.52}/(AlO_x$)_{0.48}$. The films were annealed at 200~$500^{\circ}C$ to increase the size of the Co particles, from 30$\AA$ to 180$\AA$ in the Au matrix and 40$\AA$ to 180$\AA$ in the $AlO_x$ matrix, as revealed by X-ray diffraction analysis. The Co metal in as-deposited films have saturation magnetization equivalent to that of bulk Co, which is unchanged by the annealing, showing that the Co metal is not oxidized by the annealing. Magneto-optical Kerr rotation measured at $\lambda$=400-900nm for the $Co_{0.59}-Au_{0.41}$ film as deposited is larger than that calculated for the composition. The rotation increases as the film is annealed at $200^{\circ}C$ and $300^{\circ}C$, approaching to that of bulk Co. The Kerr rotation for the $Co_{0.52}-(AlO_x)_{0.48}$ film as deposited is smaller than that calculated for the composition based on Bruggeman effective medium theory. However, the rotation increases much, exceeding the rotation of the bulk Co as annealed at $300^{\circ}C$ and $400^{\circ}C$. As a possible origin of the marked magneto-optical enhancement a weak localization of light in granular structure is suggested.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.22 no.3
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• pp.145-150
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• 2022

An analytical model based on a modal transmission-line theory (MTLT) is developed to investigate the optical transmission through metal gratings. This model gives well physical meanings for the transmission as well as for the dispersion relations of the modes responsible for high transmission. These concepts provide accurate information even for real metals used in the visible~near-infrared wavelength range, where surface plasmon polaritons (SPP's) are excited. Furthermore, the dispersion relations allow the nature of the propagation modes to be assessed. The propagation modes are hybrid between Fabry-Pérot like modes and SPP's. It is important to consider different period and aspect ratio of metal gratings in order to determine the nature of the hybrid modes. In this paper, the sensing characteristics and mode propagation phenomena of high-performance plasma bio-sensors that depend on these variables were clearly analyzed.

• The Journal of Engineering Research
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• v.1 no.1
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• pp.5-14
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• 1997

The purpose of thesis is to analyze the radiation characteristics of an offset gregorian antenna in order to design the satellite-loaded antenna. In order to compute the radiation pattern of the sub-reflector, the reflected wave is obtained by GO(Geometric Optics) at an arbitrary shaped sub-reflector. Then the total radiation EM wave is obtained by summing the diffracted fields obtained by UTD(Uniform Geometrical Theory of Diffraction) and the GO fields. In order to calculate the far field radiation pattern of the main reflector, the radiation integral equation is derived from the induced current density on reflector surface using PO(Physical Optics). The kernel is expanded in terms of Jacobi-Bessel series for increasing the computational efficiency, then the modified radiation integral is represented as the double integral equation independent of observation points. When the incident fields are assumed to be x-or y-polarized field, the characteristics of radiation patterns in the gregorian antenna is analyzed in case of the main reflector having the focal length of 62.4$\lambda$, diameter of 100$\lambda$, and offset height of 75$\lambda$, and the sub-reflector having the eccentricity of 0.501, the inter focal length og 32.8$\lambda$, the horn axis angle of $9^{\circ}$ and the half aperture angle of $15.89^{\circ}$. The cross-polarized level and side lobe level in the offset geogorian reflector are reduced by 30dB and 10dB, respectively, in comparison with those of the offset parabolic antenna.