• Korean Journal of Medicinal Crop Science
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• v.2 no.1
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• pp.67-72
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• 1994

From the leaves of Erythronium japonicum(Liliaceae) fieve aromatic compounds including four flavonoids were isolated and characterized as di -0-n-decyphthalate, kaempferol, quercetin, astragalin and isoquercitrin on the basis of spectroscopic evidences.

• Journal of the Korean Chemical Society
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• v.19 no.4
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• pp.280-285
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• 1975

The degradation mechanisms of naphthoquinone-1,2-diazide-5-sulfonyl esters(PGND, BEND and PVAND) of polyglyceryl phthalate (PG), bisphenol A-epichlorohydrin (BE) and polyvinyl alcohol (PVA) were studied by infrared absorption spectra. Absorption band due to C=N=and C=O of o-quinonediazide group decreased or disappeared after sufficient exposing to light. And also, absorption band C=O of indene carboxylic acid was increased. From the results, it may be concluded that the above photosensi tive polymers were dissociated to indene carboxylic acid soluble in aqueous alkali solution. Further, the effect of sensitizers were examined by the variation of intensity in infrared absorption spectra of sensitized and unsensitized samples.

• Applied Chemistry for Engineering
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• v.34 no.3
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• pp.252-257
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• 2023

In this study, to replace phthalate-based plasticizers known as endocrine disruptors, compounds as plasticizer candidates were synthesized by using alcohols containing rings and fatty acids extracted from animal and vegetable oils, and their properties as plasticizers, including their plasticization efficiency, were evaluated. Nine compounds synthesized by esterification of fatty acids (caprylic acid, capric acid, lauric acid) and alcohols (solketal, benzyl alcohol, cyclohexanol) were identified by ¹H-NMR. The nine synthetic compounds were evaluated for their plasticity by adding them to PVC resin, and compared with the commercial plasticizers DEHP, DINCH, and ESO. According to the results, plasticization efficiency was 0.96 to 1.02 times higher than DEHP, 0.94 to 0.98 times higher than ESO, and 1.05 to 1.10 times higher than DINCH. Thermal stability was somewhat lower than that of DEHP and DINCH, but showed better results than ESO. The results of the solvent extraction test showed that both aqueous and oily solvents showed higher values than DEHP and DINCH but showed similar or superior properties to ESO.

• Bulletin of the Korean Chemical Society
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• v.28 no.3
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• pp.432-438
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• 2007

Environmentally important phthalic esters have been analyzed by GC-MS in terms of individual phthalic esters or total phthalic esters directly or after derivatization. Derivatization improves the chromatographic characteristics of the highly polar phthalic esters. This study focused on the GC-MS determination of the total phthalic esters and the individual phthalic esters simultaneously. The phthalic esters were hydrolyzed to phthalate and corresponding alcohols in 1 M NaOH solution at 90 oC for 30 min followed by extraction with ethyl acetate after acidifcation. The phthalic acid and alcohols were simultaneously silyl derivatized using bis(trimethylsilyl)trifluoroacetamide (BSTFA) to their corresponding silyl ester and ethers in the mixture of 60% acetone and 40% ethyl acetate at room temperature within 30 min. Because of the high reactivity of BSTFA with the phthalic acid and alcohols effective silyl derivatization was possible simultaneously. GC-MS analysis of the silyl derivatives of phthalic acid and alcohols was performed. The total phthalic ester content was estimated from the analytical result of phthalic silyl ester, while the individual phthalic ester was quantified from the analytical results of alcoholic silyl ethers. This technique was applied to spiked tab water and real seawater samples from the Lake Shihwa in Korea. The results were checked against the results from the direct GC-MS analysis of the phthalic esters and reasonable recoveries with high sensitivity were achieved. The recoveries were higher than 75% with low relative standard deviation (below 10%).

• Journal of the Korean GEO-environmental Society
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• v.9 no.7
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• pp.5-11
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• 2008

The paper presents the results of qualitative analysis of phthalate esteres in Miho stream in of Cheongju city. Phthalate esters (Di-2-ethylhexylphthalate, Di-n-butylphthalate) are widely used as plasticizers to increase the flexibility and workability of high-molecular-weight polymer. For water phase, DEHP concentration in upper stream and down stream were $12-18{\mu}g/{\ell}$ and $11-21{\mu}g/{\ell}$, respectively. For sediment phase, DEHP concentration in upper stream and down stream were $0.07-0.82{\mu}g/g$ (dry) and $0.06-0.92{\mu}g/g$ (dry), respectively. Also, DnBP concentration of sediment in same site were $0.04-0.25{\mu}g/g$ (dry) and $0.08-0.34{\mu}g/g$ (dry), respectively. DEHP and DnBP concentration of water phase in the small stream of industrial area were $13-28{\mu}g/{\ell}$ and $2-8{\mu}g/{\ell}$, respectively. DEHP and DnBP concentration of sediment phase in the small stream of industrial area were $0.12-0.7{\mu}g/g$ (dry) and $0.17-2.16{\mu}g/g$ (dry), respectively. Phthatlate esteres in water and sediments phase of Miho stream were lower than water bodies around the world.

• YAKHAK HOEJI
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• v.36 no.3
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• pp.205-211
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• 1992

A simple dignostic method using Fast Atom Bombardment mass spectrometry was applied to the characterization of green tea flavonols from the eluates of Sepahadex LH-20 column chromatography. From the ethyl acetate extracts, crude mixture of flavonol fraction(Fr.$1{\sim}4$) were separated by the stepwise gradient elution with 30, 45, and 60% aqueous acetone. Procyanidine B analogues were found to be typical constituents of Fr. 1. Main components of Fr. 2 were catechins and gallo-catechins. Fr. 3 contained mainly ester type compounds, catechin-gallates, gallocatechin-gallates with their analogues. Fr. 4 was contaminated with some phthalate esters.

• Journal of the Korean Chemical Society
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• v.19 no.3
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• pp.198-206
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• 1975

Polymers with photosensitive functional groups, the naphthoquinone-1,2-diazide-5-sulfonyl esters(PGND, BEND and PVAND) of polyglyceryl phthalate(PG), bisphenol A-epichlorohydrin polycondensate(BE) and polyvinyl alcohol(PVA), were prepared. The molecular weights of the starting materials were determined by the cryoscopic method, i.e., in the range of 650${\sim}$1200 for PG and 780${\sim}$1320 for BE, PGND, BEND and PVAND were prepared by esterification of PG, BE and PVA with naphthoquinone-1,2-diazidie-5-sulfonyl chloride, and the replacements of such a functional groups were confirmed by the infrared absorption spectra and elemental analyses. The good agreement between the observed values of elemental analyses (PGND, BEND and PVAND) and the calculated values, indicated that the degree of polymerization did not change in the course of esterification of PG, BE and PVA.

• Food Science and Preservation
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• v.12 no.1
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• pp.68-74
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• 2005

This study was carried out to analyze to the flavor components of Lindera obtusiloba BL leaf teas by different processing methods. 81 kinds of flavor components in the masted tea, 78 in the roasted tea after steaming, 88 in the withered tea, 86 in the fermented tea, 72 in the steamed tea, and 89 in the air dried tea ware by GC/MS. Hydrocarbones in Lindera obtusiloba BL leaf teas were 45 kinds of $\beta-piepne$, and 16 kinds of alcohols such as Linalool, n-octanoal, phenyl acetaldehyde, $(-)-\alpha-terpineol$, elemol, and cholest-5-en-3-ol. 11 kinds of ketones sachas 2-ethyl-2- propyl-cyclohexanone, and 8 kinds of aldehydes sach as phenyl acetaldehyde, tetradecanal, 10-undecanal, 4-Bromo-2-methylbutanal were found. Esters were methyl 9,12,15-octadecatrienate, didodecyl phthalace, 1,2-benzenediccarbaboxy acid-bis (2-ethylhexyl)ester and phenols was 2,6-bis(1,1-dimethylethyl)-4-methyl-phenol.

• Korean Journal of Pharmacognosy
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• v.40 no.4
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• pp.326-333
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• 2009

Fourteen compounds were isolated from the 70% ethanol extract of Lonicera Caulis (Caprifoliaceae) and their structures were identified as seven aliphatic compounds [long-chain alcohols (1, 2), trilinolein (3), hexacosanol (4), fatty acids (6), 9,12,13-trihydroxyoctadeca-10(E),15(Z)-dienoic acid (10), and pinellic acid (11)] and seven phenolics [bis(2-ethylhexyl) phthalate (dioctylphthalate, DOP) (5), coniferaldehyde (7), caffeic acid docosanoyl ester (8), caffeic acid (9), coniferyl aldehyde 4-O-glucoside (12), linarin (13), and coniferin (14)]. The chemical structures of these compounds were identified on the basis of spectroscopic methods and comparison with literature values. All the compounds except for caffeic acid (9) were isolated from this plant parts for the first time.

• Journal of the Korean Chemical Society
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• v.19 no.4
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• pp.269-279
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• 1975

Photosensitive properties of naphthoquinone-1,2-diazide-5-sulfonyl esters (PGND, BEND and PVAND) of polyglyceryl phthalate(PG), bisphenol A-epichlorohydrin condensate(BE) and polyvinyl alcohol(PVA) were investigated by the change of solubility before and after exposing to light. Various samples coated on glass or quartz plates were exposed to light under various conditions and steeped in aqueous alkali solution, and then the yield of residual film(W/W0) was determined. The yield of residual film, which was closely related to the sensitivity of the film, was affected by the degree of polymerization of the backbone resin, sensitizers and their concentration. In polymer homologs, the sensitivity was dependent on the degree of polymerization(the higher, the better). And also, it was most effective when 5 % of sensitizers to esters was used. The minimum exposed time was 0.6 min. for PGND-1, 1.0 min. for BEND-1, and 3.0 min. for PVAND-1. Most effective sensitizers for PGND, BEND and PVAND among those used here were benzanthrone, 5-nitroacenaphthene and picramide, respectively. The spectral sensitivities of PGND, BEND and PVAND were examined by comparing their spectrograms with UV-spectra in a solid state. Also, the sensitization and spectral sensitivity of the above polymers were studied. All the polymers containing the sensitizers showed optical sensitization. From the fact that in either case of sensitized or unsensitized sample, the ranges of absorption-maximum wave length were almost consistent with sensitivity maximum wave length, it was proved that the light absorbed by a sample served efficiently for photochemical reactions. Benzanthrone was found to be an excellent sensitizer for PGND.