• 제목/요약/키워드: Photovoltaic effects

검색결과 210건 처리시간 0.031초

HWCVD를 이용한 Amorphous Si 박막 증착공정에서 수소량에 따른 박막성장 특성 (Hydrogen-Dependent Catalytic Growth of Amorphous-Phase Silicon Thin-Films by Hot-Wire Chemical Vapor Deposition)

  • 박승일;지형용;김명준;김근주
    • Current Photovoltaic Research
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    • 제1권1호
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    • pp.27-32
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    • 2013
  • We investigated the growth mechanism of amorphous-phase Si thin films in order to improve the film characteristics and circumvent photo-degradation effects by implementation of hot-wire chemical vapor deposition. Amorphous silicon thin films grown in a silane/hydrogen mixture can be decomposed by a resistive heat filament. The structural properties were observed by Raman spectroscopy, FTIR, SEM, and TEM. The electrical properties of the films were measured by photo-conductivity, dark-conductivity, and photo-sensitivity. The contents of Si-H and $Si-H_n$ bonds were measured to be 19.79 and 9.96% respectively, at a hydrogen flow rate of 5.5 sccm, respectively. The thin film has photo-sensitivity of $2.2{\times}10^5$ without a crystalline volume fraction. The catalyst behavior of the hot-wire to decompose the chemical precursors by an electron tunneling effect depends strongly on the hydrogen mixture rate and an amorphous Si thin film is formed from atomic relaxation.

Effects of Triplet Excitons on Photocurrent of Polymer Photovoltaic Devices

  • Lee, Chang-Lyoul;Byeon, Clare. C.;Suh, Duk-Il;Kim, Bok-Hyeon;Yang, Xudong;Greenham, Neil
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.1133-1135
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    • 2009
  • The rolls of triplet excitons in a polymer based photovoltaic (PV) device are investigated for improving the efficiency of PV devices. Generally, the thick photo-absorbing layer can improve the PV device efficiency by increasing the photon absorption. However, in case of PV devices with singlet excitons, the efficiency is limited by the short exciton diffusion length, which depends on the mobility and lifetimes of excitons. Therefore, using the triplet excitons, which have a higher mobility and longer lifetime, can solve the problem of premature exciton dissociation caused by the shorter singlet exciton diffusion length in the thick photo-absorbing layer. In this study, the triplet exciton dynamics of a conjugated polymer in a phosphorescent dye blended polymer PV device is investigated by photo-induced absorption, and PV devices performance at various concentrations of phosphorescent dye are is also evaluated.

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Damage-Free Treatment of ITO Films using Nitrogen-Oxygen (N2-O2) Molecular DC Plasma

  • Kim, Hong Tak;Nguyen, Thao Phoung Ngoc;Park, Chinho
    • Current Photovoltaic Research
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    • 제3권4호
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    • pp.112-115
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    • 2015
  • In this study, the surface of ITO films was modified using $N_2-O_2$ molecular plasma, and the effects of oxygen concentration in the plasma on the ITO surface properties were investigated. Upon plasma treatment of ITO films, the surface roughness of ITO films seldom changed up to the oxygen concentration in the range of 0% to 40%, while the roughness of the films slightly changed at or above the oxygen concentration of 60%. The contact angle of water droplet on ITO films dramatically changed with varying oxygen concentration in the plasma, and the minimum value was found to be at the oxygen concentration of 20%. The plasma resistance at this condition exhibited a maximum value, and the change of resistance showed an inverse relationship compared to that of contact angle. From these results, it was conjectured that the chemical reactions in the sheath of the molecular plasma dominated more than the physical actions due to energetic ion bombardment, and also the plasma resistance could be used as an indirect indicator to qualitatively diagnosis the state of plasma during the plasma treatment.

Sulfurization 온도와 Cu/(In+Ga) 비가 Cu(In,Ga)Se2 박막 내 S 함량에 미치는 영향 (Effects of sulfurization temperature and Cu/(In+Ga) ratio on Sulfur content in Cu(In,Ga)Se2 thin films)

  • 고영민;김지혜;신영민;;안병태
    • Current Photovoltaic Research
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    • 제3권1호
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    • pp.27-31
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    • 2015
  • It is known that sulfide at the $Cu(In,Ga)Se_2$ ($CIGSe_2$) surface plays a positive role in $CIGSe_2$ solar cells. We investigated the substitution of S with Se on the $CIGSe_2$ surface in S atmosphere. We observed that the sulfur content in the $CIGSe_2$ films changed according to sulfurization temperature and Cu/(In+Ga) ratio. The sulfur content in the $CIGSe_2$ films increased with increasing the annealing temperature and Cu/(In+Ga) ratio. Also Cu migration toward the surface increased at higher temperature. Since high Cu concentration at the $CIGSe_2$ surface is detrimental role, it is necessary to reduce the S annealing temperature as low as $200^{\circ}C$. The cell performance was improved at $200^{\circ}C$ sulfurization.

결정질 실리콘 태양전지 표면 역 피라미드 구조의 특성 분석 (Influence of Inverted Pyramidal Surface on Crystalline Silicon Solar Cells)

  • 양지웅;배수현;박세진;현지연;강윤묵;이해석;김동환
    • Current Photovoltaic Research
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    • 제6권3호
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    • pp.86-90
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    • 2018
  • To generate more current in crystalline silicon solar cells, surface texturing is adopted by reducing the surface reflection. Conventionally, random pyramid texturing by the wet chemical process is used for surface texturing in crystalline silicon solar cell. To achieve higher efficiency of solar cells, well ordered inverted pyramid texturing was introduced. Although its complicated process, superior properties such as lower reflectance and recombination velocity can be achieved by optimizing the process. In this study, we investigated optical and passivation properties of inverted pyramid texture. Lifetime, implied-Voc and reflectance were measured with different width and size of the texture. Also, effects of chemical rounding at the valley of the pyramid were observed.

최적 일체형 태양광 발전용 전력변환장치 PCS 특성에 관한 연구 (A Study on the Characteristics of PCS Using a Solar Cells Generation of Optimal Integrated)

  • 황락훈
    • 전기전자학회논문지
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    • 제23권3호
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    • pp.1003-1014
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    • 2019
  • 본 논문에서는 PV 시스템에서 사용되는 회로들을 쉽게 해석할 수 있도록 모델링하였다. 시뮬레이션 툴은 직관적인 전기회로 시뮬레이션이 가능한 PSPICE를 이용하였다. 모델링한 라이브러리를 이용하여 태양전지의 사용에서 간과하기 쉬운 온도와 공간방사의 영향에 대해서도 시뮬레이션을 수행하였다. 이와 더불어 태양광 발전 시스템의 완전한 동작을 위해 DC-DC 벅-부스트 컨버터와 MPPT 제어 시스템에 대한 완전한 동작 시스템에 대해 모델링하고 시뮬레이션을 수행하여 양호한 동작을 확인할 수 있었다. 또한 시뮬레이션의 동작을 입증하기 위하여 시뮬레이션에서와 동일한 조건의 실제 시스템을 구성하여 실험을 수행 하였으며 실험의 결과와 시뮬레이션의 결과가 동일한 동작을 수행하는 것을 확인할 수 있었다. 또한, 단상 3[kW] 계통연계형 태양광 전력변환기를 제안하였다.

용액성장법에서 자외선 조사를 이용한 CdS의 산소함량 제어 (Oxygen Control in CdS Thin Film by UV Illumination in Chemical Bath Deposition)

  • 백현지;오지아;서영은;신혜진;조성욱;전찬욱
    • Current Photovoltaic Research
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    • 제7권2호
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    • pp.33-37
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    • 2019
  • In this paper, we compared the performance of $Cu(In,Ga)(S,Se)_2$ (CIGSSe) thin film solar cell with CdS buffer layer deposited by irradiating 365 nm UV light with 8 W power in Chemcial Bath Deposition (CBD) process. The effects of UV light irradiation on the thin film deposition mechanism during CBD-CdS thin film deposition were investigated through chemical and electro-optical studies. If the UV light is irradiated during the solution process, the hydrolysis of Thiourea is promoted even during the same time, thereby inhibiting the formation of the intermediate products developed in the reaction pathway and decreasing the pH of the solution. As a result, it is suggested that the efficiency of the CdS/CIGSSe solar cell is increased because the ratio of the S element in the CdS thin film increases and the proportion of the O element decreases. This is a very simple and effective approach to control the S/O ratio of the CdS thin film by the CBD process without artificially controlling the process temperature, solution pH or concentration.

Reliability Analysis of the 300 W GaInP/GaAs/Ge Solar Cell Array Using PCM

  • Shin, Goo-Hwan;Kwon, Se-Jin;Lee, Hu-Seung
    • Journal of Astronomy and Space Sciences
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    • 제36권2호
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    • pp.69-74
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    • 2019
  • Spacecraft requires sufficient power in orbit to perform its mission. So as to comply with system requirements, the sufficient power should be made by a solar cell array by photovoltaic power conversion. A life time of space program depends on its mission considering parts reliability and parts grade. Based on the mission life time, power equipment might be designed to meet specifications. In outer space, solar cell array might generate the dc power by photovoltaic conversion effects and GaInP/GaAs/Ge solar cells are used in this study. Space programs that require more than five years should select parts for high reliability applications. Therefore, reliability analysis for high reliability applications should be performed to check its fulfilment of the requirements. This program should also require more five years for its mission and we performed its analysis using parts count method (PCM) for its reliability. Finally, we performed reliability analysis and obtained quantitative figures found out 99.9%. In this study, we presented the reliability analysis of the 300 W GaInP/GaAs/Ge solar cell array.

State of the Art Review of Shading Effects on PV Module Efficiencies and Their Detection Algorithm Focusing on Maximum Power Point

  • Lee, Duk Hwan;Lee, Kwang Ho
    • KIEAE Journal
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    • 제14권2호
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    • pp.21-28
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    • 2014
  • This paper provides the up to date review of the shading effects on PV module performance and the associated detection algorithm related to the maximum power point tracking. It includes the brief explanations of the MMP variations due to the shading occurrence on the PV modules. Review of experimental and simulation studies highlighting the significant impacts of shading on PV efficiencies were presented. The literature indicates that even the partial shading of a single cell can greatly drop the entire module voltage and power efficiency. The MMP tracking approaches were also reviewed in this study. Both conventional and advanced soft computing methods such as ANN, FLC and EA were described for the proper tracking of MMP under shaded conditions. This paper would be the basic source and the comprehensive information associated with the shading effects and relevant MPP tracking technique.

비정질 실리콘 태양전지에서 TCO/p층 계면 특성의 영향 (The effects of TCO/p-layer Interface on Amorphous Silicon Solar Cell)

  • 지일환;서성택;최병소;홍성민
    • 태양에너지
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    • 제8권1호
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    • pp.68-73
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    • 1988
  • In the glass/TCO/p-i-n a-Si/Al type of amorphous silicon solar cell, the effects on solar cell efficiency and metastability for the various kinds of TCO analyzed by SAM and ESCA, which was used to measure the diffusion profiles of In and Sn and the Fermi energy shifts in the TCO/p interface respectively. Indium which diffused into a-Si p-layer did not have any significant effects on the Fermi level shift of p-layer when the content of $B_2H_6/SiH_4$ in p-layer was at 1 gas%. The cell fabricated on $SnO_2$ turned out to have the best cell photovoltaic characteristics. ITO fabricated by electron beam deposition system, which was shown to have the greatest rate of diffusion of Indium in ITO/p interface produced the worst metastability among the cells tested.

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