• Title/Summary/Keyword: Photovoltaic devices

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Improving the Charge Extraction of Organic Photovoltaics by Controlling the PCBM Overlayer/Active-Layer Interface (PCBM Overlayer/활성층 계면 제어를 통한 유기 태양전지의 전하 추출 개선)

  • Soonho Hong;Haechang Jeong;Hoseung Kang;Sunyoung Sohn
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.4
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    • pp.451-456
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    • 2024
  • Organic photovoltaic (OPV) devices have attracted attention due to their high efficiency and simple manufacturing process. Applying an overlayer to OPV devices is one way to improve their performance because it can improve charge extraction and suppress vertical phase separation. In addition, dichloromethane (DCM) was used as an orthogonal solvent to minimize the effect on other layers. However, an coating problems due to the use of DCM were found, which affects surface morphology as rough or peeling. Additional research efforts are needed to solve these problems, and optimal results are expected to be obtained by utilizing various buffer layers or selective organic solvents.

Electrical Properties of Organic Photovoltaic Cell using CuPc/$C_{60}$ double layer (CuPc/$C_{60}$ 이중층을 이용한 유기 광기전 소자의 전기적 특성)

  • Lee, Ho-Shik;Cheon, Min-Woo;Park, Yong-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.505-506
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    • 2007
  • Organic photovoltaic effects were studied in a device structure of ITO/CuPc/Al and ITO/CuPc/$C_{60}$/BCP/Al. A thickness of CuPc layer was varied from 10 nm to 50 nm, we have obtained that the optimum CuPc layer thickness is around 40 nm from the analysis of the current density-voltage characteristics in CuPc single layer photovoltaic cell. From the thickness-dependent photovoltaic effects in CuPc/$C_{60}$ heterojunction devices, higher power conversion efficiency was obtained in ITO/20nm CuPc/40nm $C_{60}$/Al, which has a thickness ratio (CuPc/$C_{60}$) of 1:2 rather than 1:1 or 1:3. Light intensity on the device was measured by calibrated Si-photodiode and radiometer/photometer of International Light Inc(IL 14004).

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Recent Progress and Prospect of Luminescent Solar Concentrator (발광형 태양광 집광기 최신 연구 동향)

  • Song, Hyung-Jun
    • Journal of the Korean Solar Energy Society
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    • v.39 no.4
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    • pp.25-39
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    • 2019
  • Luminescent solar concentrator (LSC), consisting of luminophore included glass or substrate with edge-mounted photovoltaic cell, is semi-transparent, energy harvesting devices. The luminophore absorbs incident solar light and re-emit photons, while the waveguide plate allows re-emitted photons to reach edge or bottom mounted photovoltaic cells with reduced losses. If the area of LSC is much larger than that of photovoltaic cell, this system can effectively concentrate solar light. In order to improve the performance of LSC, new materials and optical structures have been suggested by many research groups. For decreasing re-abosprion losses, it is essential to minimize the overlap between absorption and photoluminescence solar spectrum of luminophoroe. Moreover, the combination of selective top reflector and reflective optical cavity structure significantly boosts the waveguide efficiency in the LSC. As a result of many efforts, commercially available LSCs have been demonstrated and verified in the outdoor. Also, it is expected to generate electricity in buildings by replacing conventional glass to LSCs.

Study on Modeling of ZnO Power FET (ZnO Power FET 모델링에 관한 연구)

  • Kang, Ey-Goo;Chung, Hun-Suk
    • Journal of IKEEE
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    • v.14 no.4
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    • pp.277-282
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    • 2010
  • In this paper, we proposed ZnO trench Static Induction Transistor(SIT). Because The compound semiconductor had superior thermal characteristics, ZnO and SiC power devices is next generation power semiconductor devices. We carried out modeling of ZnO SIT with 2-D device and process simulator. As a result of modeling, we obtained 340V breakdown voltage. The channel thickness was 3um and the channel doping concentration is 1e17cm-3. And we carried out thermal characteristics, too.

Organic photovoltaic cells using low sheet resistance of ITO for large-area applications

  • Kim, Do-Geun;Gang, Jae-Uk;Kim, Jong-Guk
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.5.1-5.1
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    • 2009
  • Organic photovoltaic (OPV)cells have attracted considerable attention due to their potential for flexible, lightweight, and low-cost application of solar energy conversion. Since a 1% power conversion efficiency (PCE) OPV based on a single donor-acceptor heterojunction was reported by Tang, the PCE has steadily improved around 5%. It is well known that a high parallel (shunt)resistance and a low series resistance are required simultaneously to achieve ideal photovoltaic devices. The device should be free of leakage current through the device to maximize the parallel resistance. The series resistance is attributed to the ohmic loss in the whole device, which includes the bulk resistance and the contact resistance. The bulk resistance originated from the bulk resistance of the organic layer and the electrodes; the contact resistance comes from the interface between the electrodes and the active layer. Furthermore, it has been reported that the bulk resistance of the indium tin oxide (ITO) of the devices dominates the series resistance of OPVs for a large area more than $0.01\;cm^2$. Therefore, in practical application, the large area of ITO may significantly reduce the device performance. In this work, we investigated the effect of sheet resistance ($R_{sh}$) of deposited ITO on the performance of OPVs. It was found that the device performance of polythiophene-fullerene (P3HT:PCBM) bulk heterojunction OPVs was critically dependent on Rsh of the ITO electrode. With decreasing $R_{sh}$ of the ITO from 39 to $8.5\;{\Omega}/{\square}$, the fill factor (FF) of OPVs was dramatically improved from 0.407 to 0.580, resulting in improvement of PCE from $1.63{\pm}0.2$ to $2.5{\pm}0.1%$ underan AM1.5 simulated solar intensity of $100\;mW/cm^2$.

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Low-costBacksheet Materials with Excellent Resistance to Chemical Degradation for Photovoltaic Modules (태양전지모듈용 고내구성 저가형 백시트)

  • Pyo, Se Youn;Lee, Chang Hyun
    • Membrane Journal
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    • v.25 no.3
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    • pp.287-294
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    • 2015
  • Photovoltaic (PV) modules are environmentally friendly energy-conversion devices to generate electricity via the photovoltaic effect of semiconductors on solar energy. One of key elements in PV modules is "Backsheet," a multi-layered film to protect the devices from a variety of chemicals including water vapor. A representative Backsheet is composed of polyvinyl fluoride (PVF) and poly(ethylene terephthalate) (PET). PVF is relatively expensive, while showing excellent resistance to chemical attacks. Thus, it is necessary to develop alternatives which can lower its high production cost and guarantee lifetime applicable to practical PV modules at the same time. In this study, PET films with certain levels of crystallinity were utilized instead of PVF. Since it is well known that PET is suffering from trans-esterification and hydrolysis under a wide pH range, it is needed to understand decomposition behavior of the PET films under PV operation conditions. To evaluate their chemical decomposition behavior within a short period of times, accelerated decomposition test protocol is developed. Moreover, electrochemical long-term performances of the PV module employing the PET-based Backsheet are investigated to prove the efficacy of the proposed concept.

Low Cost High Power Density Photovoltaic Power Conditioning System with an Energy Storage System

  • Jang, Du-Hee;Han, Sang-Kyoo
    • Journal of Power Electronics
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    • v.12 no.3
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    • pp.487-494
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    • 2012
  • A new low cost high power density photovoltaic power conditioning system (PV PCS) with an energy storage system is proposed in this paper. Its high power density and cost effectiveness can be achieved through the unification of the maximum power point tracker and the battery charger/discharger. Despite the reduced power stage, the proposed system can achieve the same performance in terms of maximum power point tracking and battery charging/discharging as the conventional system. When a utility power failure happens, the proposed system cannot perform maximum power point tracking at the UPS mode. However, the predetermined battery voltage near the maximum power point of the PV array can effectively generate a reasonable PV power even at the UPS mode. Therefore, it features a simpler structure, less mass, lower cost, and fewer devices. Finally, to confirm the operation, validity, and features of the proposed system, a theoretical analysis and experimental results from a single phase AC 220Vrms/1.5kW prototype are presented.

Grid Connected Photovoltaic Inverter System Using a New Zero-Current- Transition Scheme (새로운 Zero-Current-Transition 기법을 이용한 계통 연계형 태양광 발전 인버터 시스템)

  • Choi, Young-Deok;Lee, Dong-Yun;Hyun, Dong-Seok
    • Proceedings of the KIEE Conference
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    • 2002.04a
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    • pp.213-215
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    • 2002
  • This paper presents grid connected photovoltaic inverter system using a new Zero-Current-Transition(ZCT) technique. The main switches of the proposed grid connected inverter are turned off under the zero current condition by operating the auxiliary circuit and also all semiconductor devices, switches and diodes, are applied to low rated voltage regardless of the load condition. In additionally, the proposed ZCT scheme has advantages, which are without the additional current stresses and the conduction losses on the main switches during the resonance period of the auxiliary circuit. The simulation was performed to verify the validity of the proposed grid connected photovoltaic ZCT inverter system.

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