• Title/Summary/Keyword: Photoluminescence spectrum

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A Study on Phosphor Synthetic and Low Temperature Photoluminescence Spectrum (저온 photoluminescence 스펙트럼 및 형광체 합성에 관한 연구)

  • Kim, Soo-Yong
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.4
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    • pp.10-16
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    • 2010
  • In this paper, synthesis here Mn add to Ar injection the state and a vacuum an atomosphere $ZnGa_2O_4$ : Mn, ZnO and $Ga_2O_3$ power of 1 : 1 mole ratio mixture. Manufacture a close examination of oxygen a component variation luminescence a specific character reach an in fluence of $ZnGa_2O_4$ : Mn, luminescence spectrum observation also an explanation of Mn site symmetry and at luminescence spectrum reach an influence from low temperature photoluminescence spectrum.

Polarization Ellipticity of Micro-photoluminescence in a Single GaAs/AlGaAs Quantum Ring

  • Kim, Minju;Jang, Juyeong;Lee, Seunghwan;Song, Jindong;Kyhm, Kwangseuk
    • Current Optics and Photonics
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    • v.5 no.1
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    • pp.72-76
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    • 2021
  • The polarized micro-photoluminescence spectrum was analyzed to investigate the anisotropic localized states in a single GaAs quantum ring. An energy difference of ~0.1 meV was observed from the perpendicularly polarized spectrum measured by a pair of linear analyzers. Spectral dependence of the polarized emission was also characterized in terms of rotation and ellipticity angles using four Stokes parameters. While the rotation angle indicates the symmetric axis of an anisotropic quantum ring with a small variation (± 2°), the ellipticity angle varies from 7.4° down to -2.5°. We conclude that optical anisotropy and birefringence are induced by the crescent-like lateral shape of localized states.

Characteristics of Electronic Absorption Spectrum and Photoluminescence in Cast-Poly(3-hexylthiophene) Films (캐스팅법으로 제작한 Poly(3-hexylthiophene)의 흡수스펙트럼에 따른 형광 특성)

  • 김주승;구할본;조재철
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.57-60
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    • 1998
  • Poly(3-hexylthiophene)(P3HT) was synthesized by use of FeCl$_3$ as a oxidizing agent at $25^{\circ}C$. The infrared spectrum of our polymer gave good evidence for the conjugation of 3-hexylthiophene monomer unit. P3HT contains the HT(head-to-tail) linkage larger than 64% based on NMR analysis. Electronic absorption and photoluminescence studies show that cast films of P3HT have three exciting state. Absorption spectrum was separated with three maximum peaks by Giese-French method and shifted to the shorter wavelength with increasing temperature. Separated absorption spectrum of P3HT is well adapted to PL peak appeared at longer wavelength. Low temperature PL spectrum is well separated at 669nm, 733nm and 812nm.

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A study on luminescence a specific character and ZnGa2O4:Mn phosphor synthetic (ZnGa2O4:Mn 형광체 합성 및 발광 특성에 관한 연구)

  • Kim, Soo Yong;Jee, Suk Kun
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2009.05a
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    • pp.703-708
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    • 2009
  • In this paper, synthesis here Mn add to Ar any a vacuum an atomosphere $ZnGa_2O_4$ : Mn, ZnO and $Ga_2O_3$ power of 1:1 mole ratio mixture. Manufacture a close examination of oxygen a component variation luminescence a specific character reach an in fluence of $ZnGa_2O_4$ : Mn, luminescence spectrum, the surface a picture and a component ratio measurement, also an explanation of Mn site symmetry and at luminescence spectrum reach an influence from low temperature photoluminescence spectrum.

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Photoluminescence of the Single Crystal MnF2(1.5% EuF3) (단결정 MnF2(1.5% EuF3)의 Photoluminescence)

  • Kwon, Soon-Hyuk;Nahm, Kyun;Kim, Chul-Koo
    • Journal of the Korean Magnetics Society
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    • v.17 no.1
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    • pp.1-5
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    • 2007
  • The 1R(Infra-Red) spectrum and PL(Photoluminescence) of the antiferromagnetic pure $MnF_2$ and the single crystal $MnF_2(1.5%\;EuF_3)$ with the rutile structures were measured. The detailed analysis of the measured PL data showed the differences of the optical property between the single crystal $MnF_2(1.5%\;EuF_3)$ and the pure $MnF_2$. It was found that the additional PL peak by the doping of the $EuF_3$ in $MnF_2$ is originated from the f-d transition of $Eu^{3+}$ from the temperature dependent intensity measurement.

A Study on the Mechanism of Photoluminescence in Poly(3-hexylthiophene) (Poly(3-hexylthiophene)의 PL 발광 메카니즘에 관한 연구)

  • 김주승;서부완;구할본
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.2
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    • pp.133-138
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    • 2001
  • We studied the optical properties of poly(3-hexylthiophene) for applying to the emitting material of organic electro luminescent device. The infrared spectrum and NMR of synthesized polymer gave good evidence for the conjugation of 3-hexylthiophene monomer unit. We confirmed that poly(3-hexylthiophene) contains the HT(head-to-tail)-HT(head-to-Tail) linkage larger than 65% based on NMR analysis. FTIR and raman spectroscopy show that poly(3-hexylthiophene) has two main vibration levels which have an energy about 0.18eV and 0.36eV. Electronic absorption spectra shifted to the shorter wavelength with increasing temperature, which is related to a conformational transition of the polymer. Photoluminescence spectrum generated at low temperature(10K) is separated at 669nm, 733nm and 812nm that it's because of phonon energy generated from the lattice vibration.

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Fabrication of Mixed and Patterned Type of Remote Phosphors by Screen Printing Process and their Optical Properties

  • Kim, Byung-Ho;Hwang, Jonghee;Lee, Young Jin;Kim, Jin-Ho;Jeon, Dae-Woo;Lee, Mi Jai
    • Journal of the Korean Ceramic Society
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    • v.53 no.4
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    • pp.381-385
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    • 2016
  • Recently, white LEDs, especially, warm white LEDs have been intensively investigated due to outstanding optical properties, long term stability and low power consumption. In this study, mixed type and patterned type of remote phosphors were prepared by screen printing process employing green and red phosphor. Each type of remote phosphor exhibited distinctive photoluminescence spectrum. For example, the mixed type of remote phosphor exhibited unique spectrum, while the patterned type showed expectable spectrum depending on the concentration of phosphors. This indicates that a small amount of red phosphor dramatically reduced the green photoluminescence in the case of mixed-type remote phosphor, whereas the effect was negligible in the patterned-type remote phosphor. The possibility of undesirable chemical reaction was further investigated by using scanning electron microscopy and X-ray diffraction.

Photoluminescence Properties of Red Phosphors Gd1-xVO4:Eux3+ Subjected to Eu3+ Concentration (Eu3+ 농도에 따른 적색 형광체 Gd1-xVO4:Eux3+의 형광 특성)

  • Cho, Shin-Ho;Cho, Seon-Woog
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.3
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    • pp.193-197
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    • 2012
  • $Gd_{1-x}VO_4:{Eu_x}^{3+}$ red phosphors were synthesized with changing the concentration of $Eu^{3+}$ ion by using a solid-state reaction method. The crystal structure, surface morphology, and photoluminescence and photoluminescence excitation properties of the red phosphors were measured by using X-ray diffractometer, field emission-scanning electron microscopy, and florescence spectrometer, respectively. The XRD results showed that the main peak of all the phosphor powders occurs at (200) plane. As for the photoluminescence properties, the maximum excitation spectrum occurred at 306 nm due to the charge transfer band from ${VO_4}^{3-}$ to $Eu^{3+}$ ions and the maximum emission spectrum was the red luminescence peaking at 619 nm when the concentration of $Eu^{3+}$ ion was 0.10 mol.

Synthesis and optical properties of star-like ZnO nanostructures grown on with carbon catalyst (탄소 촉매에 의하여 성장된 별-모양 ZnO 나노 구조물의 합성과 광학적 특성)

  • Jung, Il-Hyun;Chae, Myung-Sic;Lee, Ui-Am
    • Journal of the Semiconductor & Display Technology
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    • v.9 no.2
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    • pp.1-6
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    • 2010
  • Star-like ZnO nanostructures were grown on SI(100) substrates with carbon(C) catalyst by employing vapor-solid(VS) mechanism. The morphologies and structure of ZnO nanostructures were investigated by Field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD) and Raman spectrum, Photoluminescence spectrum. The results demonstrated that the as-synthesized products consisted of star-like ZnO nanostructure with hexagonal wurtzite phase. Nanostructures grown at 1100 were mainly star-like in structure with diameters of 500 nm. The legs of the star-like nanostructures were preferentially grown up along the [0001] direction. A vapor.solid (VS) growth mechanism was proposed to explain the formation of the star-like structures. Photoluminescence spectrum exhibited a narrow emission band peak around 380 nm and a broad one around 491 nm. Raman spectrum of the ZnO nanostructures showed oxygen defects in ZnO nanostructures due to the existence of Ar gas during the growth process, leading to the dominant green band peak in the PL spectrum.

The Effect of Thermal Annealing and Growth of CdIn2Te4 Single Crystal by Bridgeman Method (Bridgeman 법에 의한 CdIn2Te4단결정 성장과 열처리 효과)

  • Hong, K.J.;Lee, S.Y.;Moon, J.D.
    • Korean Journal of Materials Research
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    • v.13 no.3
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    • pp.195-199
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    • 2003
  • The $p-CdIn_2$$Te_4$single crystal was grown in the three-stage vertical electric furnace by using Bridgman method. The quality of the grown crystal has been investigated by the x-ray diffraction and the photoluminescence measurements. From the photoluminescence spectra of the as-grown $CdIn_2$$Te_4$crystal and the various heat-treated crystals, the ($D^{\circ}$, X) emission was found to be the dominant intensity in the photoluminescence spectrum of the $CdIn_2$T $e_4$:Cd, while the ($A^{\circ}$, X) emission completely disappeared in the $CdIn_2$T $e_4$:Cd. However, the ($A^{\circ}$, X) emission in the photoluminescence spectrum of the $CdIn_2$T $e_4$:Te was the dominant intensity like an as-grown $CdIn_2$T $e_4$crystal. These results indicated that the ($D^{\circ}$, X) is associated with $V_{Te}$ acted as donor and that the ($A^{\circ}$, X) emission is related to $V_{cd}$ acted as acceptor, respectively. The $p-CdIn_2$T $e_4$crystal was found to be obviously converted into the n-type after annealing in the Cd atmosphere. The origin of ( $D^{\circ}$, $A^{\circ}$) emission and its TO phonon replicas is related to the interaction between donors such as $V_{Te}$ or $Cd_{int}$, and accepters such as $V_{cd}$ or T $e_{int}$. Also, the In in the $CdIn_2$X$CdIn_4$was confirmed not to form the native defects because it existed in the stable form of bonds.