• Journal of the Korean Applied Science and Technology
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• v.14 no.2
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• pp.57-64
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• 1997

The symmetric naphthothiazolo carbocyanine is of industrial importance as green-sensitizing dye in the spectral sensitization of emulsion microcrystals in negative film-making. In this study, green-sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-5-phenyl-benzoxazolium(inner salt) with triethyl orthoacetate in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H$-NMR spectrometer, TGA and DSC. The maximum absorption peak in methanol solvent was 502nm. Therefore, it was concluded that benzoxazolo carbocyanine dye can be used as green-sensitizing dye for the spectral sensitization of photographic emulsion.

• Journal of the Korean Applied Science and Technology
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• v.16 no.3
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• pp.199-203
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• 1999

The symmetric benzoxazolo carbocyanine is of industrial importance as green-sensitizing dye in the spectral sensitization of emulsion microcrystals in positive paper and negative film-making. The stability on the solvents of benzoxazolo carbocyanine dye was measured by UV-Vis spectrophotometer, and then all of solvents were stabilized sensitizer. The maximum absorption peak range in methanol, acetonitrile, acetone, DMF, dichloromethane, chloroform solvents was $501nm{\sim}511nm$. But it was identified that only methanol can be used to photographic emulsion. The photographic characteristics have contrast of 2.8, speed of 50-55$(lux{\cdot}sec)^{-1}$, fog of 0.07-0.08, respectively.

• Journal of the Korean Applied Science and Technology
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• v.12 no.2
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• pp.5-11
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• 1995

In the study, sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-5-phenyl-benzoxazolium(inner salt) with ortho-ester in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^{1}H$-NMR spectrometer, TGA and DSC. Therefore, it was concluded that benzoxazolo carbocyanine dye can be used as green-sensitizing dye for the spectral sensitization of photographic emulsion.

• Journal of radiological science and technology
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• v.6 no.1
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• pp.43-67
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• 1983

In order to increase the sensitivity of the photographic emulsion, one of the chemical sensitizers hydroxymethane sulfonic acid sodium salt(HMS) was applied through the chemical ripening process and following four types of emulsion were prepared. Their grain sizes were determined through the electron microscope. The ranges of average grain sizes were $0.05-0.40{\mu}m$ for silver chlorobromide emulsion of low sensitivity $0.10-0.45{\mu}m$ for the silver chlorobromide emulsion of medium sensitivity, $0.60-1.05{\mu}m$ for the silver iodobromide emulsion of high sensitivity, and $0.90-1.55{\mu}m$ for the ammonical silver iodobromide emulsion of high sensitivity. Through the reduction sensitization with HMS, they showed significant sensitivity enhancement by the increment of HMS concentration above pH 5.5 and pBr 3.0. Required sensitivity was obtained above pH 6.2 and pBr 3.3 when sulfur and gold sensitization were applied. Fog formed along the reduction sensitization was successfully prevented by the addition of 5.5-dimethylhydantion.

• The Journal of Information Technology
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• v.7 no.2
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• pp.1-5
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• 2004

The symmetric 9-phenyl-5,5'-diphenyl-3,3'-bis-(3-sulfopropyl)-benzoxazolo carbocyanine triethyl ammonium salt is of industrial importance as green-sensitizing dye in the spectral sensitization of emulsion microcrystals in negative film and positive paper-making. The stability on the solvents of benzoxazolo carbocyanine dye was measured by UV-Vis spectrophotometer, and then dye was stabilized in various solvents. The maximum absorption peak range in various solvents was 507nm~515nm. It was identified that the solvents can be used to photographic emulsion.

• Journal of the Korean Graphic Arts Communication Society
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• v.1 no.1
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• pp.69-75
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• 1983

Among the gelatin hardness for photographic emulsion, the formal dehyde , dialdehydes, n-Methylol compounds, ketonea, carbonylic acid and carbamic acid derivatives, and s-Triazine derivatives were studied. The greater purts of hardeners formed cross-link by the reaction with ${\varepsilon}$-Amino group in the lysine and OH group in the hydroxylysine. Glutaraldehyde produced most stable cross-link due to the formation of pyridinum ion. 2.5 hexanedione and 3-hexone-2.5-dione possible to use as the ketone hardner . The sodium salt of 2.4-dichloro-6-hydroxy-S-Triazine was newly developed as the olefinic hardners for emulsion.lsion.

• Journal of the Korean Applied Science and Technology
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• v.18 no.2
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• pp.136-141
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• 2001

Naphthothiazolo carbocyanine is of industrial importance as red-sensitizing dye in the spectral sensitization of emulsion microcrystals in negative film-making. In this study, red-sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4,5-naphthothiazolium(inner salt) with triethyl orthoacetate in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, Mass spectrometer, $^{1}H-NMR$ spectrometer, TGA and DSC. The maximum absorption peak in methanol solvent was 573nm. Therefore, it was concluded that naphthothiazolo carbocyanine dye can be used as red0sensitizing dye for the spectral sensitization of photographic emulsion.

• Journal of the Korean Applied Science and Technology
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• v.31 no.3
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• pp.416-421
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• 2014

Naphthothiazolo carbocyanine is of industrial importance as red-sensitizing dye in the spectral sensitization. Sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4,5-naphthothiazolium (inner salt) with triethyl orthopropionate in the presence of triethylamine. The product was identified by using various analytical tools such as elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H$-NMR spectrometer, TGA and DSC. The maximum absorption peak in methanol solvent was 578nm. Therefore, it was concluded that naphthothiazolo carbocyanine dye can be used as sensitizing dye for the spectral sensitization of photographic emulsion and color cosmetics.

• Journal of the Korean Applied Science and Technology
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• v.15 no.3
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• pp.33-37
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• 1998

The hardening test of gelatin with 2,4-dichloro-6-hydroxy-1,3,5-triazine mono sodium salt was studied at pH 5, 7, 8 and about increasing temperature, respectively. The hardener was prepared by the reaction of cyanuric chloride with sodium hydroxide, disodium hydrogenphosphate-12-water and trisodium phosphate-12-water in the presence of water. The product was identified by elemental analyzer. IR spectrophotometer. Novel hardener can be used in photographic emulsion and showed very good hardening effect.

• Journal of the Korean Applied Science and Technology
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• v.13 no.1
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• pp.31-39
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• 1996

In this study, sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4, 5-naphthothiazolium(inner salt) with triethyl orthoformate in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H-NMR$ spectrometer, TGA and DSC. Therefore, it was concluded that naphthothiazolo carbocyanine dye can be used as red-sensitizing dye for the spectral sensitization of photographic emulsion.