• Macromolecular Research
• /
• 제17권11호
• /
• pp.894-900
• /
• 2009

This study examined the charge carrier photogeneration and hole transport properties of blends of poly (9-vinylcarbazole) (PVK), $\pi$-conjugated polymer, with different weight proportions (0~29.4 wt%) of (PEA)$VOPO_4{\cdot}H_2O$ (PEA: phenethylammonium cation), a novel organic-inorganic hybrid material, using IR, UV-Vis, and energy dispersive spectroscopy (EDS), thermogravimetric analysis (TGA), steady state photocurrent (SSPC) measurement, and atomic force microscopy (AFM). The SSPC measurements showed that the photocurrent of PVK was reduced by approximately three orders of magnitude by the incorporation of a small amount (~12.5 wt%) of (PEA) $VOPO_4{\cdot}H_2O$, suggesting that hole transport occurred through the PVK carbazole groups, whereas a reverse trend was observed at high proportions (>12.5 wt%) of (PEA)$VOPO_4{\cdot}H_2O$, suggesting that transport occurred via (PEA)$VOPO_4{\cdot}H_2O$ molecules. The transition to a trap-controlled hopping mechanism was explained by the difference in ionization potential and electron affinity of the two compounds as well as the formation of charge percolation threshold pathways.

• 대한전자공학회논문지
• /
• 제26권10호
• /
• pp.1528-1534
• /
• 1989

Photoeffects at the p-GaP semiconductor/CsNO3 electrolyte interface were investigated in terms of their current-voltage characteristics. The photoeffects at the semiconductor-electrolyte interfaces and their photocurrent variations are verified using Ar ion laser and continuous cyclic voltammetric methods. The mechanism of charge transfer at the photogeneration in the depletion layer rather than the photodecomposition of the p-GaP semiconductor electrode surface and/or the water photoelectrolysis. The adsorption of Cs+ ions at the interface is physical adsorption.

• 대한화학회지
• /
• 제37권7호
• /
• pp.642-647
• /
• 1993

순수 정제한 스쿠알렌 색소(DSSQ(4-distearylamino phenyl-4'-dimethylaminophenylsquaraine) 를 Langmuir Blodgett 방법으로 $SnO_2$ 전극위에 단분자막으로 도포하였다. DSSQ 용액의 최대 흡수 파장은 630 nm 이었으나, $SnO_2$ 전극에 도포한 상태는 최대흡광파장 위치가 530 nm로 이동되어 스쿠알렌 집합체를 나타내었다. 이 집합체를 열처리하였더니 최대흡광 위치는 620~680 nm 로 이동되었다. 스쿠알렌 집합체에서의 에너지 이동 관계를 알기 위하여 광전류를 측정하였다. 광전류의 action spectrum은 흡수스펙트럼과 거의 같은 경향을 보였으며, 열처리한 시료의 광전류 action 스펙트럼도 처리전과 같은 결과를 나타내었다. 이때의 양자수율은 약 0.3%이었다. 용액내의 빛의 tunneling 효과를 보기 위하여 $SnO_2$전극과 DSSQ 색소사이에 스테아린산을 2~8층으로 각각 도포하고 광전류를 측정하였더니, 광전류가 현저히 감소하였다. 2층을 더 도포한 시료에서는 광전류가 전혀 나타나지 않았다. 또한 전해질 용액에 질소를 통하였을 경우에는 광기전력이 현저히 감소하고, 산소를 통하였을 때는 같은 정도로 증가하는 것으로 보아 전해질의 용존 산소가 전자 주게 역할을 하고 있음을 추정할 수 있었다.

• 한국태양광발전학회지
• /
• 제4권2호
• /
• pp.6-13
• /
• 2018

최근 산업용 태양광 발전시장에서 주목 받고 있는 양면수광형 태양전지의 경우 지면 반사광(Albedo)의 영향으로 추가적인 광생성(Photogeneration)이 발생하여 태양전지의 전환효율(Conversion efficiency)을 증가시켜 주기 때문에 시장에서 수요가 증가하고 있다. 이러한 장점에도 불구하고 몇 가지 문제에 대한 논의가 진행되고 있는데 그 중에서 가장 중요한 부분은 양면수광형 태양전지의 효율을 정의하는 부분이다. 양면수광형 태양전지의 효율을 정의하기 위하여 여러 가지 연구가 진행되었지만 현재까지 국제적인 기준이 제정되지 않아 정확한 효율의 정의가 어려운 상황이다. 양면수광형 태양전지의 성능 확인을 위한 측정 방식은 단일광원(Single light source) 조사 방식, 단일광원 분할(Single light splitter) 조사 방식, 이중광원(Double light source) 조사 방식으로 나눌 수 있다. 본고에서는 이중광원 조사 방식을 이용하여 후면 반사광의 광원을 개별적으로 정의함으로써 실제 발전 환경과 동일한 조건의 광량 정의를 통하여 다양한 지면 반사 조건에 대하여 정확한 태양전지의 전환효율을 측정하고 이를 통하여 다이오드 특성을 추출할 수 있는 측정 방식에 대하여 논하고자 한다.

• 한국인쇄학회지
• /
• 제15권1호
• /
• pp.71-83
• /
• 1997

In recent years, various kinds of organic photoreceptors have been used for copy machines based on electrophotography. Most of them are constructed into layered devices in which a photogeneration layer is separated from a charge transport layer. They are usually used with application of negative charges. Organic pigment have received considerable attention with phthalocyanine, squaraine, and azo compounds being used to construct zerograpgic photoreceptors with enhanced long wavelength sensitivity, residual potential and zerograpgic gain of squaraine photoconductor were measured from the photoinduced discharge curve. Most of synthesized squaraine derivative couldn`t use for CGM(charge generation material), but it knew that a part of one was able to use it within the possibility. A few appliance is used it know about dependence on CTM(charge transport material) of squaraine derivative. It could know that experiment`s result is 2.5-bis(4-N-N`-diethylaminophenyl)-1,3,4-oxadiazole(OXD) is the bestproduct.

• Journal of Ginseng Research
• /
• 제14권3호
• /
• pp.416-420
• /
• 1990

Ultrastructural and anatomical features of the leaf were studied in Panax ginseng C.A. Meyer(ginseng). The ginseng leaf poorly developed palisade tissue and the size of mesophyll cell was larger and the chloroplast density was lower than that of Glycine max (soyben). Ginseng chloroplast was filled with highly stacked grana and condensely-arrayed thylakoid, so the stroma space was hardly absorbed. However, ginseng mesophyll tissue and chloroplast array did not reduce light energy entering the mesophyll chloroplast, and the high LHCP/CP ratio of ginseng thylakoid resulted in the absorption of excess photon. It is reasonable to assume that 1O1-photogenearation by excess light energy partially resulted from the anatomical and ultrastructural characteristics of the ginseng leaf.

• 한국정보디스플레이학회:학술대회논문집
• /
• 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
• /
• pp.1010-1013
• /
• 2006

To understand the exact charge carrier photogeneration properties of photoactive thin films consisting of a ${\pi}-conjugated$ polymer matrix and a triplet dopant, we prepared two types of polymer, poly(9-vinylcarbazole) (PVK) and poly[9,9-bis(2- ethylhexyl)fluorene-2,7-diyl] (PF2/6) doped with triplet emitters for organic light-emitting diodes (OLED), either iridium(III)fac-tris(2-phenylpyridine) $(Ir(ppy)_3)$ or iridium(III)bis[(4,6-fluorophenyl)- $pyridinato-N,C^2'$]picolinate (FIrpic), as thin film devices by using the conventional method. Those doped film devices, as well as pristine film devices, on ITO substrates were characterized by means of steady state photocurrent measurement for a wide spectral range.

• Advances in Energy Research
• /
• 제3권3호
• /
• pp.143-155
• /
• 2015

The Nile blue has been used as a photosensitizer with Arabinose as a reductant in photogalvanic cell for optimum conversion efficiency and storage capacity. Reduction cost of the photogalvanic cell for commercial utility. The generated photopotential and photocurrent are 816.0 mV and $330.0{\mu}A$ respectively. The maximum power of the cell is $269.30{\mu}W$ where as the observed power at power point is $91.28{\mu}W$. The observed conversion efficiency is 0.6095% and the fill factor 0.2566 has been experimentally found out at the power point of the photogalvanic cell, whereas the absolute value is 1.00. The photogalvanic cell so developed can work for 120.0 minutes in dark if it is irradiated for 200.0 minutes that is the storage capacity of photogalvanic cell is 60.00%. The effects of different parameters on the electrical output of the photogalvanic cell have been observed. A mechanism has also been proposed for the photogeneration of electrical energy.

• Journal of Photoscience
• /
• 제9권2호
• /
• pp.385-387
• /
• 2002

Direct EPR evidence of the photo-generation of superoxide radicals ( $O_2$$^{-.}$) was obtained by using spin trapping techniques in spinach photosystem II (PSII) membranes. $O_2$$^{-.}$ was detected by following the formation of 5-diethoxyphosphoryl-5-methyl-1 -pyrroline-N-oxide (DEPMPO) superoxide adducts, DEPMPO-OOH. The significant increase of the EPR signal amplitude of DEPMPO-OOH in N$H_2O$H-, CaC $l_2$- and NaCl-treated PSII membranes showed that the oxygen-evolving system has a close relation to the $O_2$$^{-.}$ production. PSII membranes with inactivated donor side could not prevent the $O_2$$^{-.}$ production efficiently. Treatments on PSII donor side also influence the maximum level and the kinetics of Chlorophyll (Chi) a fluorescence. Results suggested that manganese cluster and extrinsic proteins might affect Chi a fluorescence in ways different from that happens at the acceptor side of PSII.SII.SII.

• Bulletin of the Korean Chemical Society
• /
• 제33권3호
• /
• pp.795-802
• /
• 2012

Geminate electron-hole recombination in organic solids in the presence of a donor-acceptor heterojunction is studied by computer simulations. We analyze how the charge-pair separation probability in such systems is affected by energetic disorder of the media, anisotropy of charge-carrier mobilities, and other factors. We show that in energetically disordered systems the effect of heterojunction on the charge-pair separation probability is stronger than that in idealized systems without disorder. We also show that a mismatch between electron and hole mobilities reduces the separation probability, although in energetically disordered systems this effect is weaker compared to the case of no energetic disorder. We demonstrate that the most important factor that determines the charge-pair separation probability is the ratio of the sum of electron and hole mobilities to the rate constant of recombination reaction. We also consider systems with mobility anisotropy and calculate the electric field dependence of the charge-pair separation probability for all possible orientations of high-mobility axes in the donor and acceptor phases. We theoretically show that it is possible to increase the charge-pair separation probability by controlling the mobility anisotropy in heterojunction systems and in consequence to achieve higher efficiencies of organic photovoltaic devices.