• Title/Summary/Keyword: Photocontrolled reduction

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Homogeneously Dispersed Silver Nanoparticles on the Honeycomb-Patterned Poly(N-vinylcarbazole)-cellulose triacetate Composite Thin Films by the Photoreduction of Silver Nitrate

  • Kim, Kwang Il;Basavaraja, C.;Huh, Do Sung
    • Bulletin of the Korean Chemical Society
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    • v.34 no.5
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    • pp.1391-1396
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    • 2013
  • The photocontrolled reduction of silver nitrate to silver (Ag) nanoparticles on honeycomb-patterned poly(N-vinylcarbazole) (PVK)-cellulose triacetate (CTA) composite thin films was studied. The composites were prepared via the oxidative polymerization of N-vinylcarbazole with ferric chloride using different CTA concentrations. A honeycomb-patterned film was fabricated by casting the composite solution under humid conditions. Ag particles with a homogeneous distribution were produced by the composite film in a moderate CTA concentration, whereas aggregated Ag was obtained from the pure PVK film.