• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.310-315
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• 2008

Organic-inorganic hybrid solutions were made using glycidoxypropyl trimethoxysilane (GPTMS) and vinyltriethoxysilane (VTES) as starting materials by sol-gel method. Photochromic coating solutions were prepared by mixing the solution of photochromic dye (spiropyran) dissolved in ethylacetate with the organic-inorganic hybrid solutions. Photochromic films were prepared on polycarbonate sheets by spin coating and cured for 2 h at $100^{\circ}C$. The resulting films exhibited a reversible color change upon irradiation with UV light from transparent to blue. The color-fading speed and pencil hardness of the coating films increased with increasing the GPTMS content in the coating solutions.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.5
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• pp.628-636
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• 1997

Flow visualization technique incorporating photochromic dye is used to study the flow characteristics of the gravity driven laminar wavy film. The film thickness and wave speed are successfully measured by flow visualization. As the inclination angle increases, the waves have higher peaks and lower substrate thickness. The measured cross stream velocity at the free surface is up to 10% of stream wise velocity, which shows enhanced mixing in the lump of the film. The measured stream wise velocity profiles are close to parabolic profile near the substrate and the peak but show significant velocity defect near the rear side of the wave. The measured wall shear rate distributions show good agreement with the previous workers' numerical results.

• Journal of the Korean Graphic Arts Communication Society
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• v.10 no.1
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• pp.1-13
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• 1992

The recent results concerning the synthesis and application of spiroxazine dyes have been summerized., The absorption bands of usual spiroxazine dyes are changed from colorless to colored from by irradiation of ultraviolet ray. This mechanism is derived from the cleavage of oxazine ring. Such properties are dependent on its chemical structure and surrounded matrix of spiroxazine dyes. the chemical structure of this dye is similar to the well known spriopyran. But spiroxazine dyes have noticed recently, because of excellent high light-sensitivity and superior fatigue-resistant property. This dye are already applied as photochromic lens, cloths and UV light checker.

• Textile Coloration and Finishing
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• v.3 no.3
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• pp.1-5
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• 1991

Cationic azo dyes were synthesized by coupling aniline and its derivatives with 2,4-dimethyl imidazole as a coupler, and their photochromic behavior was investigated. The dyes exhibited little photochromism on wool, but to a considerable degree on Dacron T92(anionic modified polyester), the photochromism being prominent for the dye with electron-releasing substituent on diazo component. Little photochromism on wool can be attributed to a decreased mobility of dye by the various interactions between the dye and wool molecules, which interferes the cis-trans isomeriation of dye. On Dacron T92 there can not be any obstacle for the cis-trans isomerization of dye, hence reversible color change may occur. The electron-releasing substituent on diazo component may be helpful for the photochromism of dye by increasing the n-electron density of phenyl ring, which can stabilize the cis-form of the dye by the interaction with the positive charge of imidazole ring.

• Korean Chemical Engineering Research
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• v.49 no.5
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• pp.535-540
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• 2011

Organic-inorganic hybrid coating solutions were prepared starting from colloidal silica, lanthanum nitrate and ${\gamma}$-glycidoxypropyl trimethoxysilane by the sol-gel method. Also, spiropyran-doped hard coating solutions were prepared by mixing the spiropyran solution, obtained after dissolving spiropyran dye into tetrahydrofuran solvent, with the organic-inorgnic hybrid coating solutions. The spiropyran-doped hard coating solutions were applied as a thin layer to polycarbonate sheets, and their photochromic properties were investigated. The effect of amount of colloidal silica added into the coating solutions was investigated on the photochromic properties of coating films. Both decoloration rate and pencil hardness of the coating films were increased with increasing the amounts of colloidal silica.

• Journal of the Korean Graphic Arts Communication Society
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• v.12 no.1
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• pp.133-143
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• 1994

A new photochromic spiroxazine dye having a pyridinium s-triazine moiety has been prepared. It shows a reversible photochemical color change from colorless to reddish-purple in ethanol solution. In ethanol solution the half life time of the open form was 150sec, which was shortened by raising temperature. Silica-immobilized spiroxazine(6). Fine power of silica-immobilized spiroxazine was changed intensely blue from colorless by U.V. light or sunlight.

• Journal of the Korean Graphic Arts Communication Society
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• v.12 no.1
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• pp.159-168
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• 1994

The Aggregation State of thin vapor deposite Film made by Cyanine Dye were changed into Monomeric molecular state(M) and Dimeric Aggregation(D) at the acidic treatment, into reversible H-Aggregation (H) at alkalic gas or heat treatment. Photo-electric properties were higher H than D and M, this stats were effective in enhancing Photoelectric-conversion characteristic. Substitute group of Meso-Position being stronger electronic Donors, Electronic density is higher and Electric conductivity is enhanced, we confirmed Oscillator Strength calculated by PPP-Molecular Orbital Calculation and Absorption Spectra at solvent stats were agreed good.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2007.11a
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• pp.101-102
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• 2007

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.41 no.6
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• pp.53-58
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• 2004

A novel UV sensor was manufactured and characterized using evanescent field coupling between photochromic dye dispersed polymer waveguide and side polished fiber. The spiroxazine (photochromic dye) dispersed polymer was used as planar waveguides. The resonant wavelength was shifted owing to refractive index variation of planar waveguide on exposed UV because of its photo-functional properties. The sensitivities are $1.21{\mu}W/mw$ and $2.75{\mu}W/mw$ when UV intensities increased after exposure times were fixed at 3 seconds and 5 seconds, respectively. Output optical power according to UV intensity increases and saturation time decreases as the intensity of UV radiations increases.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.26 no.11
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• pp.1570-1577
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• 2002

In order to investigate the characteristics of two-phase slug flow, an electromagnetic flowmeter with 240Hz triangular AC excitation was designed and manufactured. The signals and noise from the flowmeter were obtained, and analyzed in comparison with the observations with a high speed CCD camera. The uncertainty of the flowmeter under single-phase flow was $\pm$ 2.24% in real-time. For two-phase slug flow, electromagnetic flowmeter provided real-time simultaneous measurements of the mean film velocity around Taylor bubble and the relative location and the length of the bubble. Besides, it is an easier and cheaper method for measuring mean film velocity than others such as photochromic dye activation method or particle image velocimetry.