• Journal of Photoscience
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• v.1 no.1
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• pp.67-68
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• 1994

INTRODUCTION : The photochemistry of nitro chromophore has been the subject of intense study only in recent years. Unlike the carbonyl functional group, of which the photochemistry has been quite extensively studied and fairly well understood, as a result of excellent work done by numerous physical and organic photochemists alike, the nature of photochemistry of nitro group has only recently been systematically explored. The photochemistry of nitro group exhibits general features of the photochemistry of the carbonyl groups such as hydrogen abstraction by the diradical species generated from the n-$\pi$$^*$ excited state of the nitro group. Other photochemical pathways common to the carbonyl group such as the biradical intermidiate formation, photocycloelimination, and cydoaddition reactions are also open for the nitro group. Of all the photochemical reactions of the nitro group mentioned above, hydrogen abstraction by the n-$\pi$$^*$ excited state of the nitro group has drawn much attention by synthetic organic chemists and polymer chemists. In the field of organic synthesis, above mintioned photochemical reaction has been utilized in the photoprotection-deprotection chemistry.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.2
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• pp.118-136
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• 2010

Photochemical characteristics of ozone ($O_3$) and its precursors such as $O_3$ budget and $O_3-NO_x$-VOC sensitivity were analyzed in different physico-chemical properties of air masses around the Mexico City Metropolitan Area (MCMA) using aircraft observations during March 2006. The physico-chemical properties of air masses were categorized into 5 groups: boundary layer (BL), biomass burning (BB), free tropospheric continent (FTCO) and marine (FTMA), and Tula industrial complex (TIC). Results from the $O_3$ budget analysis indicated that $O_3$ production for BL, FTCO, and FTMA (for BB and TIC) was mainly controlled by a photochemical production pathway, a reaction of NO with $HO_2$ (with $RO_2$), while the main pathway of photochemical $O_3$ destruction for BL, FTCO, and FTMA (for BB and TIC) was a reaction of $HO_2$ with $O_3$ (of $H_2$ with $O^1$(D)). In addition, most of air mass categories (especially FTCO) were estimated to be $NO_x$-sensitive for $O_3$ production with lower $NO_y$, higher ratios of the other indicator species (e.g., $O_3/(NO_y-NO_x$), $H_2O_2/HNO_3$, etc.), and the lower removal rate of radicals ($\leq$0.5) by the reaction of OH with $NO_2$ than those of the VOC-sensitive condition.

• Particle and aerosol research
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• v.9 no.3
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• pp.149-161
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• 2013

Experiments on photochemical reactions of purified air alone in an indoor smog chamber were carried out after flushing Teflon bags with purified air for many hours in order to check the level of contamination on the chamber wall. Ozone concentrations were linearly increased from <4 ppb up to about 8 ppb with irradiation time for four hours. Outgassing of NOx from the chamber wall was found to be less than 1 ppb. New ultrafine particles were formed and grown up to about 70 nm during the photochemical reactions, and then total number and mass concentrations of particles were increased from <10 particles/$cm^3$ up to about 4,000 particles/$cm^3$ and $1.3{\mu}g/m^3$, respectively. The wall conditions of these Teflon bags flushed with purified air might not severly affect the chamber experimental results for photochemical reactions of polluted urban ambient air. The difference of gaseous species between two chambers was 2.4 ppb of ozone at most, indicating that the wall cleaning performance of two chambers was nearly similar.

• Journal of the Korean Professional Engineers Association
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• v.9 no.4
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• pp.5-12
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• 1976

• Bulletin of the Korean Chemical Society
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• v.19 no.1
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• pp.128-131
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• 1998

• Journal of Environmental Science International
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• v.1 no.1
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• pp.19-33
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• 1992

The high oxidants, which occur the daily maximum concentrations in the afternoon, are transported into the other region via long range transport mechanisms or trapped within the shallow mixing boundary layer and then removed physically (deposition, transport by mountain wind, etc.) and chemically (reaction with local sources). Therefore, modeling formation of photochemical oxidants requires a complex description of both chemical and meteorolog ital processecs . In this study, as a part of air quality studies, we reviewed various aspects of photochemical modeling on the basis of currently available literature. The result of the review shows that the model is based on a set of coupled continuity equations describing advection, diffusion, transport, deposition, chemistry, emission. Also photochemical oxidant models require a large amount of input data concerned with all aspects of the ozone life cycle. First, emission inventories of hydrocarbon and nitrogen oxides, with appropriate spatial and temporal resolution. Second, chemical and photochemical data allowing the quantitative description of the formation of ozone and other photochemically-generated secondary pollutants. Third, dry deposition mechanisms particularly for ozone, PAN and hydrogen peroxide to account for their removal by absorption on the ground, crops, natural vegetation, man-made and water surfaces. Finally, meteorological data describing the transport of primary pollutants away from their sources and of secondary pollutants towards the sensitive receptors where environmental damage may occur. In order to improve our present study, shortcomings and limitation of existing models are pointed out and verification Process through observation is emphasized.

• Journal of the Korean Vacuum Society
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• v.3 no.2
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• pp.147-157
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• 1994

Valence or core electron excitations induced by Synchrotron radiation (SR) irradiation and ensuing chemical reactions can be applied for semiconductor processes i, e, deposition etching and modifications of thin film materials. Unique selectivity can be achieved by this photochemical reactions in deposition and etching. Some materials can be ecvaporated by SR irradiation which can be utilized for low temperature surface cleaning of thin films. Also SR irradiation significantly lowers the reaction temperature and photon activated surface reactions can be utilized for direct writing or projection lithography of electronic materials. This technique is especially effective in making nanoscale feature size with abrupt and well defined interfaces for next generation electronic devices.

• Bulletin of the Korean Chemical Society
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• v.30 no.12
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• pp.3053-3056
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• 2009

The title compound, ${\alpha},{\alpha}$-dichloro-o-methylacetophenone, was prepared and its photochemical behavior was investigated. Addition of an extra chlorine at alpha position to the carbonyl showed many different features from photochemical reactivities of mono chloro analogue, 2,5-dimethylphenacyl chloride. In benzene, a rearrangement product with a formal 1,5-Cl shift and a reduction product were formed beside indanone. In methanol, solvolysis and cyclization of a common dienol intermediate occurred at comparable reaction rates.

• Bulletin of the Korean Chemical Society
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• v.26 no.10
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• pp.1607-1610
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• 2005

• Journal of Environmental Science International
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• v.8 no.3
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• pp.287-292
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• 1999

This study was performed to investigate the characteristics of nocturnal maxiumu ozone occurrence and the meteorological relevance using to hourly ozone data and meteorological data for 1995~1996 in Pusan coastal area. Kwangbokdong showed the highest occurrence of nocturnal maximum ozone as 36.9%, and Deokcheondong showed the lowest occurrence(9.2%) for research period in Pusan. The occurrence rates of nocturnal maximum ozone concentration were decreased toward land area. The low maximum temperature, high minimum temperature, low diurnal range, high relative humidity, high wind speed, high could amount, low sunshine and low radiation were closely related to the main meteorological characteristics occuring the nocturnal maximum concnetration of ozone. It was shown that normal daily variation of ozone concentration by strong photochemical reaction at the before day of nocturnal maximum ozone. The concnetration of nocturnal maximum ozone were occured by entrainment of ozone from the upper layer of developed mixing layer. There are no ozone sources near the ground at night, so that the nighttime ozone should be entrained from the upper layer by forced convection.