• Title/Summary/Keyword: Photochemical production

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A Study on the Calculation Method of the Elastomeric Bearing Life Cycle Inventory (LCI) Database to Improve Reliability of Evaluation of Environmental Load of Bridges (교량의 환경부하평가 신뢰성 향상을 위한 교량용 탄성받침 전과정목록 산정방법에 관한 연구)

  • Wie, Deahyung;Kim, Youngchun;Kwak, Inho;Hwang, Yongwoo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.37 no.4
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    • pp.681-691
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    • 2017
  • In this research, life cycle inventory database (LCI DB) was developed for elastomeric bearing employing life cycle assessment (LCA) methodology additionally the reliability improvement rate in the evaluation of the environmental load of the bridge was analyzed. As are result of impact assessment by 6 major impact categories, production of elastomeric bearing puts on environmental impact in the order of resource depletion, global warming, photochemical oxidant creation. and among a wide variety of input, steel plates contributes in most of the impact categories. As a result of applying the elastomeric bearing LCI database constructed in this study, the environmental loads increased by 0.53% on average, and the cut-off based on the cost of input materials increased by 11.36%. It is anticipated that it will be possible to improve the credibility and to provide data based on current production technology, such as estimating GHG emissions and evaluating environmental load, by constructing elastomeric bearing LCI DB.

Hydrogen Production from Photocatalytic Splitting of Methanol/water Solution over Ti Impregnated WO3 (티타늄 함유 텅스텐 산화물 광촉매를 이용한 메탄올/물 분해로부터 수소제조)

  • Lee, Gayoung;Park, Yujin;Park, No-Kuk;Lee, Tae Jin;Kang, Misook
    • Clean Technology
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    • v.18 no.4
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    • pp.355-359
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    • 2012
  • For effectively photochemical hydrogen production, Ti ions (0.01, 0.10, 0.50 mol%) impregnated $WO_3$ ($Ti/WO_3$) nanometer sized particles were prepared using a impregnation method as a photocatalyst. The characteristics of the synthesized $Ti/WO_3$ photocatalysts were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence spectra (PL), atomic force microscope (AFM), and electrostatic force microscope (EFM). The evolution of $H_2$ from methanol/water (1/1) photo-splitting over $Ti/WO_3$ photocatalysts was enhanced compared to those over pure $TiO_2$ and $WO_3$ photocatalysts; 3.02 mL of $H_2$ gas was evolved after 8 h when 0.5 g of a 0.10 mol% $Ti/WO_3$ catalyst was used.

Life Cycle Assessment on the Reuse of Glass Bottles (유리병 재사용에 대한 전과정평가)

  • Kim, Hyung-Jin;Kwon, Young-Shik;Choi, Yoon-Geun;Chung, Chan-Kyo;Baek, Seung-Hyuk;Kim, Young-Woo
    • Clean Technology
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    • v.15 no.3
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    • pp.224-230
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    • 2009
  • Life Cycle Assessment (LCA) has been studied on the reuse of glass bottles. The system boundary in this study encompassed from gate to gate such as production and transportation. A 360 mL volume of a glass bottle was selected as the functional unit. The environmental impact assessments was studied on 6 categories including abiotic resource depletion, acidification, eutrophication, global warming, ozone depletion, and photochemical oxidant creation. The results showed that the most significant impact categories were abiotic resource depletion (48.63%) and global warming (46.27%), and the rest categories revealed insignificant impacts. In the whole system, the chemicals used for the new bottle production revealed the major contribution to the environmental impacts (71.24%), followed by the use of electricity (16.74%) and transportation (11.8%). In addition, the environmental impact of sodium silicate to be put into the stage of the new bottle production was found to be 45.68%, causing severe influence on abiotic resource depletion and global warming.

Evaluation of Incremental Reactivity and Ozone Production Contribution of VOCs Using the PAMS Data in Seoul Metropolitan Area (수도권에서 오존생성 기여도 산출에 관한 연구)

  • Lee, J.H.;Han, J.S.;Yun, H.K.;Cho, S.Y.
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.3
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    • pp.286-296
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    • 2007
  • Ozone creation potentials suited for Seoul metropolitan area was derived by utilizing the PAMS monitoring data and the source inventory. A simple box model with variable height was developed to calculate the incremental reactivity for all the ozone episode days in the year 2003 and 2004. RIR (Relative Incremental Reactivity) was introduced as a measure of contribution to ozone generation in the Seoul metropolitan area. RIR was defined as a function of ratio of VOC to $NO_x$ and therefore it addresses both VOC and $NO_x$ limited regime. For the days that more than 10 monitoring stations out of 27 monitoring station in Seoul recorded the daily maximum ozone concentrations higher than 70 ppb, toluene had the highest RIR value in all the type II and type III PAMS site and m/p-xylene followed with the second highest RIR value. Analyses using MIR (Maximum Incremental Reactivity) and POCP (Photochemical Ozone Creation Potential) instead of RIR also yields dominance of toluene and m/p-xylene in generating ozone concentrations to demonstrate the validity of RIR.

Effect of Acid Rain on Vegetation (산성(酸性)비가 식생(植生)에 미치는 영향(影響))

  • Lee, Jong-Sik;Kim, Bok-Young
    • Korean Journal of Environmental Agriculture
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    • v.13 no.3
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    • pp.346-358
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    • 1994
  • In this paper, the current knowledge on the formation of acid rain and its effect on vegetation are reviewed. The pollutants which were emitted into the air are oxidized by photochemical reaction and affect the vegetation by dry and wet deposition. Acid rain at pH 4.0 affected sensitive plants and when it was below pH 3.0, visible symptoms developed in most of the crops. The acid rain treatment at pH 2.0 decreased dry weight, leaf area and chlorophyll contents in soybean but it increased rate of photosynthesis and respiration rate. Rain treatment at pH 2.8 increased ethylene production, but it’s not a suitable indicator of sensitivity to acid rain. At pH 2.0 treatment, the contents of soluble Mn and Al were increased but the cultivated soil pH at upper layer(0-5cm) was significantly decreased. The pertubation of glandular trichome which is existed along the vein was developed at all treatment except the control(pH 6.0) and non-treatment. Histological pertubation of spiked trichome and disintegration of chloroplast were developed only on the leaves of sesame treated with SAR(simulated acid rain) of pH 2.0.

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Analysis of Tropospheric Carbon Monoxide using MOPITT data

  • Lee, Sang-Hee;Park, Gi-Hyuk;Lim, Hyo-Suk;Lee, Joo-Hee
    • Proceedings of the KSRS Conference
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    • 2002.10a
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    • pp.373-377
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    • 2002
  • The Measurement of Pollution in the Troposphere (MOPITT) instrument is an eight-channel gas correlation radiometer launched on the Earth Observing System (EOS) Terra spacecraft in 1999. Its main objectives are to measure carbon monoxide (CO) and methane (CH4) concentrations in the troposphere. This work analyzes tropospheric carbon monoxide distributions using MOPITT data in East Asia and compared ozone distributions. In general, seasonal CO variations are characterized by a spring peak and decreased in the summer. Also, this work revealed that the seasonal cycles of CO are spring maximum and summer minimum with averaged concentrations ranging from 118ppbv to 170ppbv. The CO monthly means show a similar profiles to those of O3. This fact clearly indicates that the high concentration of CO in spring is caused by two possible causes: the photochemical CO production in the troposphere, transport of the CO in the northeast Asia. The CO and O3 seasonal cycles in northeast Asia are influenced extensively by the seasonal exchange of the different types of air mass due to the Asian monsoon. The continental air masses contain high concentrations of O3 and CO due to higher continental background concentrations and sometimes due to the contribution of regional pollution. In summer the transport pattern is reversed. The Pacific marine air masses prevail over Korea, so that the marine air masses bring low concentrations of CO and O3, which tend to give the apparent minimum in summer.

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Surface Ozone in The Major Cities of Korea : Trends, Diurnal and Seasonal Variations, and Horizontal Distributions (한반도 주요 대도시지역의 지표오존 특성 : 추세, 일변화, 월변화, 수평분포)

  • 오인보;김유근
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.4
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    • pp.253-264
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    • 2002
  • Surface ozone concentrations measured at 40 monitoring sites in three major cities (Seoul, Busan, and Daegu) of Korea during 1993~2000 were analyzed to understand the characteristics of temporal and spatial distributions. Trends were analyzed for annual mean, 95th percentiles of daily 8-hour maximum and days exceeding 8-h ozone standard of 60 ppb. Three indicators exhibited increasing trends (+0.75 ppb yr$^{-1}$ , +2.20 ppb yr$_{-1}$ , and +5.35 days yr$_{-1}$ on average) throughout the study period at all cities. Diurnal and seasonal variations were the largest in Seoul followed by Daegue and Busan, due to the high photochemical production and titration of ozone (Seoul), strong wind and constant supply of background ozone from the ocean (Busan). In the urban centers and industrial areas at all cities, scavenging of ozone by NO reduces the daily 8-hour maximum ozone by 10 ppb on average. High concentrations of ozone have frequently occurred in downwind eastern (Seoul and Daegu) or northern (Busan) sides of the territory. In particular, the coastal area of Busan had relatively high ozone level due to the local sea land breeze circulation. The results indicated that the temporal and spatial variations of ozone concentration were non -uniform and were closely related to the local environments; emission levels, climates, and geographic locations.

The Removal Properties of NO Using KOH-Treated ${\gamma}$ -Alumina (KOH로 처리된 ${\gamma}$} -Alumina를 이용한 NO의 제거특성)

  • 모세영;김만수;장홍기;안대현;손종렬
    • Journal of environmental and Sanitary engineering
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    • v.16 no.3
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    • pp.104-110
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    • 2001
  • NOx coming from combustion make photochemical smog and acid rain, cause chronic respiratory disease resulting in critical hazard to environment and human health. Most composition of NOx coming from combustion is NO and the remaining small amount of $NO_x$ is $NO_2$. Currently, many technologies are developed and used to control NO release. One of these technologies is control technology through use of the adsorbent. In this study, two methods were used to make the adsorbent and compared. KOH and ${\gamma}{\;}-alumina$ were mixed by using two methods. Then, the experimental conditions were as follows: the concentrations of KOH used were 1 mole, 0.5 mole, and 0.1 mole, respectively and the amount of ${\gamma}{\;}-alumina$$250^{\circ}C$. As a result, precipitation method, which is one of the production methods of the adsorbent, showed the most removal efficiency as KOH concentration as 1 mole and reaction temperature as $100^{\circ}C$ were used. This study shows 40 to 60% of micropores of ${\gamma}{\;}-alumina$ was lost by the reaction with KOH through the analysis of SEM and BET Finally, KOH is the most predominant factor to control the removal of NO rather than micropore of the adsorbent.

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Weathering of coal and kerogen : implications on the geochmical carbon and oxygen cycle and the environmental geochemical reactions (탄질 유기물과 케로젠의 풍화 : 탄소와 산소의 지화학적 순환 및 환경화학적 반응에 미치는 영향)

  • 장수범
    • Economic and Environmental Geology
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    • v.32 no.1
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    • pp.101-111
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    • 1999
  • Sedimentary organic matter, exposed to continental surficial environment, reacts with oxygen supplied from the atmosphee and forms carbon-containing oxidation products. Knowledge of the rate and mechanisms of sedimentary organic matter weathering is important because it is one of the major controls on atmospheric oxygen level through geologic time. Under the abiological conditions, the oxidation rate of coal organic matter by molecular oxygen is enhanced by the increase of oxygen concentration and temperature. At ambient temperature and pressure, aqueous coal oxidation results in the formation of dissolved $CO_2$ dissolved organic carbon and solid oxidation products which are all quantitatively significant reaction products. The effects of pH, ultraviolet light, and microbial activity on the weathering of sedimentary organic matter are poorly contrained. Based on the results of geochmical and environmental studies, it is believed that the photochemical reaction should play an important role in the decomposition and oxidation of sedimentary organic matter removed from the weathering profile. At higher pH conditions, the production rate of DOC can be accelerated due to base catalysis. These high molecular weight oranic matter can react with man-made pollutants such as heavy metal ions via adsorption/desorption or ion exchange reactions. The effect of microbial activity on the oxidative weathering of sedimentary organic matter is poorly understood and remains to be studied.

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Numerical Study on the Process Analysis of Ozone Production due to Emissions Reduction over the Seoul Metropolitan Area (수도권 배출량 저감에 따른 오존 발생 과정 분석에 관한 수치연구)

  • Jeong, Yeo-Min;Lee, Soon-Hwan;Lee, Hwa-Woon;Jeon, Won-Bae
    • Journal of Environmental Science International
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    • v.21 no.3
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    • pp.339-349
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    • 2012
  • In order to clarify the impact of emissions reductions on the air quality over Metropolitan area of Korean Peninsula, several numerical experiment and analysis of integrated process rate(IPR) of ozone were carried out. Numerical models used in this study are WRF for the estimate the meteorological elements and CMAQ for assessment of ozone concentration. As result in the sensitive test of VOC/NOx reduction experiments, although VOC reduction tends to induce the different impact on the advection and photochemical reaction rate of ozone in urban area and rural area, the mechanism of ozone appeared to be more sensitive to the reduction of VOC than that of NOx over the metropolitan and its surround area. So the control of VOC emission inventories is an effective means to decrease the ozone concentrations around this area.