• Title/Summary/Keyword: Photocatalytic process

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A Study on the matter of Disinfection in UV/TiO2 Water Treatment process (UV/TiO2 수처리 공정에서의 살균에 관한 연구)

  • Lee, Gyu-Hwan;Lee, Sang-Jin;Lee, Yong-Jae;Rhee, Dong-Seok
    • Journal of Industrial Technology
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    • v.27 no.A
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    • pp.15-18
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    • 2007
  • This study investigated disinfection effect by general water purifier and water purifier with UV light disinfection. The results are as follows : (i) The general bacteria existed plentifully in a storage tank before treatment (ii) Water treated in water purifier did not meet the water treatment regulation standard since the presence of bacteria, whereas with UV light application the regulation standard is totally satisfied. (iii) Photocatalytic disinfection process with UV light in the presence of $TiO_2$ more effectively killed general bacteria than UV light only.

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Photocatalytic Oxidation of Arsenite Using Goethite and UVC-Lamp (침철석과 UVC-Lamp를 이용한 아비산염의 광촉매 산화)

  • Jeon, Ji-Hun;Kim, Seong-Hee;Cho, Hyen-Goo;Kim, Soon-Oh
    • Economic and Environmental Geology
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    • v.50 no.3
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    • pp.215-224
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    • 2017
  • Arsenic (As) is known to be the most toxic element and frequently detected in groundwater environment. Inorganic As exists as arsenite [As(III)] and arsenate [As(V)] in reduced and oxidized environments, respectively. It has been reported that the toxicity of arsenite is much higher than that of arsenate and furthermore arsenite shows relatively higher mobility in aqueous environments. For this reason, there have been numerous researches on the process for oxidation of arsenite to arsenate to reduce the toxicity of arsenic. In particular, photooxidation has been considered to be simple, economical, and efficient to attain such goal. This study was conducted to evaluate the applicability of naturally-occurring goethite as a photocatalyst to substitute for $TiO_2$ which has been mostly used in the photooxidation processes so far. In addition, the effects of several factors on the overall performance of arsenite photocatalytic oxidation process were evaluated. The results show that the efficiency of the process was affected by total concentration of dissolved cations rather than by the kind of those cations and also the relatively higher pH conditions seemed to be more favorable to the process. In the case of coexistence of arsenite and arsenate, the removal tendency by adsorption onto goethite appeared to be different between arsenite and arsenate due to their different affinities with goethite, but any effect on the photocatalytic oxidation of arsenite was not observed. In terms of effect of humic acid on the process, it is likely that the higher concentration of humic acid reduced the overall performance of the arsenite photocatalytic oxidation as a result of competing interaction of activated oxygen species, such as hydroxyl and superoxide radicals, with arsenite and humic acid. In addition, it is revealed that the injection of oxygen gas improved the process because oxygen contributes to arsenite oxidation as an electron acceptor. Based on the results of the study, consequently, the photocatalytic oxidation of aqueous arsenite using goethite seems to be greatly feasible with the optimization of process.

고효율 자외선/광촉매 시스템을 이용한 고농도 유기성 폐수처리

  • Jeong, Hyo-Gi;Kim, Jung-Gon;Kim, Si-Uk
    • 한국생물공학회:학술대회논문집
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    • 2005.04a
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    • pp.272-276
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    • 2005
  • Food wastewater derived from three-stages methane fermentation system showed high concentrations of sCOD, T-N and $NH_{3}-N$. To treat the organic wastewater, the optimal operating conditions for high efficiency $UV/TiO_{2}$ photocotalytic system have been investigated. In the first process, wastewater was pre-treated with $FeCl_{3}. The optimum pH and concentration for coagulation were 4.0 and 2000 mg/L, respectively. Through this process, 52.6% of $COD_{cr}$ was removed. The second process was $UV/TiO_{2}$ photocatalytic reaction. The optimum conditions for the operation of $UV/TiO_{2}$ photocatalytic system developed in this lab have been studied. In this process, CODcr was removed from 2890 to 184 mg/L and T-N was removed from 2496 to 914 for 24 hours, respectively.

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Photocatalytic Property of Nano-Structured TiO$_2$ Thermal Sprayed Coating - Part II: TiO$_2$ -WO$_3$ Coating - (나노구조 TiO$_2$용사코팅의 미세조직 제어 공정기술 개발과 광촉매 특성평가 - Part II: TiO$_2$- WO$_3$ 코팅 -)

  • 이창훈;최한신;이창희;김형준;신동우
    • Journal of Welding and Joining
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    • v.21 no.4
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    • pp.46-55
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    • 2003
  • TiO$_2$-WO$_3$(8.2wt%) coatings were prepared by the APS (Atmospheric Plasma Spraying) process to clarify the relationship between the process parameters(H$_2$ gas flow rate of plasma 2nd gas and spraying distance) of the APS coating and photo-decomposition efficiency kinetics of the MB(methylene blue) aqueous solution decomposition and to understand the effect of addition of WO$_3$ on photocatalytic properties of TiO$_2$ sprayed coating. Further, the temperature and velocity of flying particles were measured by DPV-2000 to investigate the relationship between microstructure of coatings and process parameters. Properties of coatins were investigated by XRD, SEM, XPS, RAMAN, UV/VIS spectrometer. In case of the TiO$_2$-WO$_3$(8.2wt%) coating, it had a lower anatase fraction than that of pure-TiO$_2$ coatings because of flying in the higher temperature plasma plume by the heavy weight of TiO$_2$, WO$_3$. And, when WO$_3$ added powders were spayed, the doping effects of W ions substituted into the Ti ion sites was not occured during melting and solidification cycles of spraying. It was found that the addition of WO$_3$ was ineffective effective on increasing photo-decomposition efficiency of TiO$_2$ sprayed coating.