• Title/Summary/Keyword: Phosphorus removal

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Anaerobic Digestion Biochemical Sludge Produced from Municipal Sewage Treatment Process (하수처리시설에서 발생된 약품 잉여슬러지의 혐기성 소화 특성)

  • Cho, Sang Sun;Kang, Ho;Lim, Bong Su
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.8
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    • pp.561-569
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    • 2014
  • This study was carried out to get the characteristics of anaerobic digestion for chemical/biological sludge produced from municipal sewage treatment plant for phosphorus. Anaerobic mesophilic batch tests showed that the ultimate biodegradability of waste activated sludge showed 31%, PACl sludge 24%, Alum sludge 26%, respectively. At the S/I 1.0, 75% of total biodegradable volatile solids (TBVS) of waste activated sludge was degraded with an initial rapid decay coefficient, k1 of $0.1129day^{-1}$ and 74% of TBVS of PACl sludge with k1 of $0.0998day^{-1}$, and 76% of TBVS of Alum sludge with k1 of $0.1091day^{-1}$ for 20 days. During the operation of SCFMRs, the 3 reactor (Control, PACl, Alum) pH maintained 6.7~7.0 and the reactor alkalinity maintained 1,800~ 2,200 mg/L as $CaCO_3$. The average biogas production rates of SCFMRs fed with PACl sludge and Alum sludge were 0.089 v/v-d and 0.091 v/v-d, respectively, which was 27~28% lower than that of the control (0.124 v/v-d) at an HRT (hydraulic retention times) of 20 days. And the methane content during the operation ranged 70~76% in 3 reactor. The average TVS removal efficiency of SCFMRs fed with PACl sludge and Alum sludge were 19.6% and 19.9%, respectively, at an HRT of 20 days, which showed 4% lower than that of the control (23.8%). The average BVS removal efficiency of SCFMRs fed with PACl sludge and Alum sludge were 25.8% and 26.9%, respectively, at an HRT of 20 days, which was 8~9% lower than that of the control (34.5%).

Distribution of Pollutant Content within Surface Sediment and Evaluation of Its Removal Efficiency in the Sihwa Constructed Wetland (시화호 인공습지에서 표층퇴적토의 오염물질 함량 분포와 제거효율 평가)

  • Choi, Don-Hyeok;Choi, Kwang-Soon;Kim, Dong-Sup;Kim, Sea-Won;Hwang, In-Seo;Lee, Mi-Kyung;Kang, Ho;Kim, Eun-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.9
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    • pp.755-764
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    • 2009
  • To estimate the pollutant removal efficiency by surface sediment, matter content within surface sediment and its release from the sediment were investigated at 12 sites in the Sihwa constructed wetland. The content of COD, TOC, IL, TN, and TP within sediment varied temporally and spacially, showing ranges of 4.1~7.7 mg/g, 0.29~2.81%, 1.88~8.15%, 0.03~0.35%, 362~1,150 ${\mu}g$/g, respectively. The contents of organic matter and TN were significantly highest in March and decreased towards fall (March${\geq}$May${\geq}$July${\geq}$September, p=0.003 for COD, p=0.001 for TOC, p=0.017 for IL, p=0.015 for TN), whereas TP content was not significant statistically in difference between sampling times. The contents of heavy metals also varied largely with sampling sites and times (As:3.5~3.9 ${\mu}g$/g, Cd:0.08~0.38 ${\mu}g$/g, Cr:51.8~107.0 ${\mu}g$/g, Cu:16.4~81.8 ${\mu}g$/g, Pb:26.~81.8 ${\mu}g$/g, Zn:85~559 ${\mu}g$/g). As compared with sediment quality guideline, the content of organic matter within surface sediment of the Sihwa constructed wetland was classified as unpolluted level. In contrast, the contents of TN, TP and heavy metals were classified as medium or severe pollution state, except some heavy metals (Cu and Pb). From the results of release experiment, TN, Pb, and Zn tend to be removed by surface sediment, but TP, Cd, and Cu have a tendency to released from sediment. Therefore, a relevant plan to improve the removal efficiency of pollutant (especially phosphorus) by surface sediment in the Sihwa constructed wetland is needed.

Remediation of Sediments using Micro-bubble (미세기포를 이용한 퇴적물 정화)

  • Kang, Sang Yul;Kim, Hyoung Jun;Kim, Tschung Il;Park, Hyun Ju;Na, Choon Ki;Han, Moo Young
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.8
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    • pp.420-427
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    • 2016
  • This study was conducted on the sediment remediation using micro-bubble to remove fine particles. For this study, characteristics of contamination and release in sediment were analyzed. And then, the characteristics of bubbles on removal efficiency was investigated at various operation conditions. In particle size distribution of the sediment used for the study, the proportion of clay and silt (<0.075 mm) was about 7.7%, sand (0.075~4.75 mm) was about 67.8%, and gravel (${\geq}4.75$) was 24.5%. Total nitrogen (TN) and total phosphorus (TP) of the sediment were 2,790~3,260, 261~311 mg/kg respectively. Ignition loss and water content were 4.1~9.6, 32.9~53.2% respectively. In analysis of removal efficiency according to operation conditions of micro-bubble, it was the highest when operation condition is pressure 6 atm, pressurized water ratio 30%, and coagulant dosage 15 ppm. At the time, the sediment's removal efficiency was 19.9%. Accordingly removal efficiency of TN and TP were 21.4, 22.6% respectively. Finally a research was found that fine particles in sediment were almost removed by micro-bubble, which led to decrease nutrients' release at about 20.1~64.3% in comparison to sediment including lots of fine particles.

Evaluation of Treatment Efficiencies of Pollutants under Different Pollutant Fractions in Activated Sludge-Constructed Wetland System for Treating Piggery Wastewater (활성슬러지-인공습지 공법에 의한 돈사폐수처리시스템에서 오염물질의 분획별 정화효율 평가)

  • Kim, Seong-Heon;Seo, Dong-Cheol;Park, Jong-Hwan;Lee, Choong-Heon;Choi, Jeong-Ho;Kim, Hong-Chul;Ha, Yeong-Rae;Cho, Ju-Sik;Heo, Jong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.31 no.4
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    • pp.344-350
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    • 2012
  • BACKGROUND: To design and develop a constructed wetland for effective livestock wastewater treatment, it is necessary to understand the removal mechanisms of various types of pollutants in constructed wetlands. The objective of this study was to evaluate the treatment efficiency of pollutants under different types of fraction in constructed wetland system for treating piggery wastewater. METHODS AND RESULTS: The piggery wastewater treatment plant that consisted of activated sludge tank, aerobic and anaerobic beds was constructed. The concentration of COD(Chemical oxygen demand) in effluent by fraction was 71.5 mg/L for soluble COD, 142 mg/L insoluble COD. The concentration of SS(Suspended solid) in effluent by existing form was 102 mg/L for volatile SS, 15.5 mg/L for fixed SS. The concentration of T-N(Total nitrogen) and T-P(Total phosphorus) in effluent by existing form were 12.8 mg/L and 3.05 mg/L for dissolved form, 35.0 mg/L and 1.93 mg/L for suspended form. The removal efficiencies of COD, SS, T-N and T-P in hot season(summer and autumn) were higher than those in cold season(spring and winter). The removal efficiencies of COD, SS, T-N and T-P in effluent were 98.0, 99.0, 98.2 and 99.2% for all seasons, respectively. CONCLUSION(S): The results indicated that removal types of pollutants were insoluble COD(ICOD), volatile SS(VSS), dissolved T-N(DTN) and dissolved T-P(DTP) in constructed wetlands for treating piggery wastewater.

Microbial Influence on Soil Properties and Pollutant Reduction in a Horizontal Subsurface Flow Constructed Wetland Treating Urban Runoff (도시 강우유출수 처리 인공습지의 토양특성 및 오염물질 저감에 따른 미생물 영향 평가)

  • Chiny. C. Vispo;Miguel Enrico L. Robles;Yugyeong Oh;Haque Md Tashdedul;Lee Hyung Kim
    • Journal of Wetlands Research
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    • v.26 no.2
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    • pp.168-181
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    • 2024
  • Constructed wetlands (CWs) deliver a range of ecosystem services, including the removal of contaminants, sequestration and storage of carbon, and enhancement of biodiversity. These services are facilitated through hydrological and ecological processes such as infiltration, adsorption, water retention, and evapotranspiration by plants and microorganisms. This study investigated the correlations between microbial populations, soil physicochemical properties, and treatment efficiency in a horizontal subsurface flow constructed wetland (HSSF CW) treating runoff from roads and parking lots. The methods employed included storm event monitoring, water quality analysis, soil sampling, soil quality parameter analysis, and microbial analysis. The facility achieved its highest pollutant removal efficiencies during the warm season (>15℃), with rates ranging from 33% to 74% for TSS, COD, TN, TP, and specific heavy metals including Fe, Zn, and Cd. Meanwhile, the highest removal efficiency was 35% for TOC during the cold season (≤15℃). These high removal rates can be attributed to sedimentation, adsorption, precipitation, plant uptake, and microbial transformations within the CW. Soil analysis revealed that the soil from HSSF CW had a soil organic carbon content 3.3 times higher than that of soil collected from a nearby landscape. Stoichiometric ratios of carbon (C), nitrogen (N), and phosphorus (P) in the inflow and outflow were recorded as C:N:P of 120:1.5:1 and 135.2:0.4:1, respectively, indicating an extremely low proportion of N and P compared to C, which may challenge microbial remediation efficiency. Additionally, microbial analyses indicated that the warm season was more conducive to microorganism growth, with higher abundance, richness, diversity, homogeneity, and evenness of the microbial community, as manifested in the biodiversity indices, compared to the cold season. Pollutants in stormwater runoff entering the HSSF CW fostered microbial growth, particularly for dominant phyla such as Proteobacteria, Actinobacteria, Acidobacteria, and Bacteroidetes, which have shown moderate to strong correlations with specific soil properties and changes in influent-effluent concentrations of water quality parameters.

Phosphorus Phases in the Surface Sediment of the South Sea (남해 표층 퇴적물에서의 인의 존재상)

  • SON Jaekyung;LEE Tongsup;YANG Han Soeb
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.32 no.5
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    • pp.680-687
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    • 1999
  • To understand the role of shelf sediment in phosphorus biogeochemical cycle, we carried out sequential sediment extraction (SEDEX) of P and porewater analysis on 14 core samples collected in the South Sea of Korea, SEDEX classified P-pools into 5 phases and results are grouped into two categories: reactive P (loosely sorbed-P and Fe bound-P) and refractory P (detrital inorganic-p, authigenic mineral-P and organic-P). Total P concentrations are decreased with sediment depth in all samples as a result of dissolution to porewater. Reactive P comprises about $20\~50\%$ of total P, and iron bound-P is the major form consisting $70\~80\%$ of reactive P-pool. Iron bound-P decreases sharply with depth. Depth profiles of dissolved P concentration in porewater show mirror image of iron bound-P, revealing the role of FeOOH as a regulator of reactive P supply to overlying water column. Authigenic mineral-P consists less than $5\%$ of total P, thus removal of reactive P by converting into refractory P seems inefficient in shelf sediment. This implies that continental shelf sediment sequesters P temporarily rather than permanently. Results show local variation. Nakdong estuary receiving large amount of terrigenous input shows the highest concentration of total P and reactive P. Here iron oxyhydroxides at the surface sediment control the water column flux of P from sediment. Although total P content at the surface is comparable (500$\~$600 ${\mu}g{\cdot}g^{-1}$) between the South Sea and East China Sea, the former contains more iron bound-P and less derital inorganic-P than the latter. Reasons for the difference seem due in part to particle texture, and to biological productivity which depends roughly on the distance from land.

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Removal Efficiency of Water Pollutants and Malodor of Pig Slurry using Biofiltration System (여재순환장치를 이용한 돈분뇨 슬러리의 오염물질 및 악취제거 효율)

  • Choi, D.Y.;Kwag, J.H.;Jeong, K.H.;Park, K.H.;Huh, M.Y.;Kim, J.H.;Kang, H.S.;Jeon, K.H.;Park, C.H.;Jeong, J.W.
    • Journal of Animal Environmental Science
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    • v.15 no.3
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    • pp.217-224
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    • 2009
  • The pig slurry is one of important fertilizer source for production of crops in recent years, but it has many controversial points of utilization such as offensive odor, lack of spread equipment and farmland possession, respectively. This study was carried out in order to remove water pollutants and malodor of pig slurry using biofiltration system. The biofiltration system consists of pig slurry separator, mixing shift and attached blade for sawdust or ricehull, air injection nozzle and outlet for pig slurry and sawdust or ricehull. The characteristics pH, $BOD_5$ (Biochemical Oxygen Demand), $COD_{Mn}$ (Chemical Oxygen Demand), SS (Suspended Solid), T-N (Total Nitrogen), T-P (Total Phosphorus) of the untreated pig slurry used in this study were 7.2, 34,450, 24,604, 71,000, 4,194, $1,631\;ml/{\ell}$, respectively. The $NH_3$ (Ammonia) and $H_2S$(Hydrogen Sulfide) concentration were 70.0, 9.6 ppm, respectively. The initial total microorganisms of pig slurry were $5.0{\times}10^3\;cfu/ml$, and Salmonella, Bacillus were $5.8{\times}10^2$, $1.1{\times}10^3\;cfu/ml$, respectively. The filtration system was very effective on removal of water pollutants of pig slurry. The removal efficiency of the offensive odor of ammonia and hydrogen sulfide in sawdust was higher than those of ricehull. The total microorganisms and bacillus of pig slurry are on the increase by sawdust and ricehull, but Salmonella showed a tendency to decrease in number after that time. Accordingly, the filtration system was very effective to produce a good quality pig slurry.

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Photosynthetic Characteristics and Primary Production by Phytoplankton with Different Water Quality of Influent in Open Waters of Constructed Wetlands for Water Treatment (수질정화용 인공습지 개방수역에서 유입수질에 따른 식물플랑크톤의 광합성특성 및 유기물생산력)

  • Choi, Kwang-Soon;Hwang, Gil-Son;Kim, Dong-Sub;Kim, Sea-Won;Kim, Ho-Joon;Joh, Seong-Ju;Park, Je-Chul
    • Korean Journal of Ecology and Environment
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    • v.40 no.1
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    • pp.61-71
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    • 2007
  • The photosynthetic characteristics and primary production by phytoplankton in open waters of two wetlands (the Banwol and the Donghwa wetland) of Sihwa Constructed Wetland with different water chemistry were investigated to provide the information for the wetland management considering the water treatment efficiency. During the study period (from March to October, 2005) the primary productivity in open waters ranged from 481 to 11,275 mgC $m^{-2}$ $day^{-1}$, which is very high compared with the eutrophic level of 600mgC $m^{-2}$ $day^{-1}$. From the analysis of the photosynthesis-irradiance (P-I) model parameters, the photosynthetic characteristics may be affected by different concentration and ratio of nutrient (N and P) between two wetlands. Assimilation number (AN) was higher in the Donghwa wetland (average AN: 8.5gC $gChl^{-1}$ $hr^{-1}$) with high P and low N/P ratio than the Banwol wetland (average AN: 5.8gC $gChl^{-1}$ $hr^{-1}$) with high N and high N/P ratio. This result indicates that AN may be concerned with phosphorus than nitrogen and low NIP ratio. Positive correlation (R=0.81) was observed between the initial slope and AN, implying that AN was high in case of phytoplankton having more active photosynthesis ability under low light. On the other hand, maximum photosynthesis (Pmax) was related positively with chlorophyll a concentration showing correlation coefficient of 0.47. In this study, considering the high primary production through phytoplankton photosynthesis in open waters of Sihwa Constructed Wetland, the produced organic matter by phytoplankton may affect the water quality within wetland and its efficiency of water treatment. Also, the photosynthetic characteristics may be affected by different nutrient enrichment (especially phosphorus) of wetlands. This study suggests that the production by phytoplankton and its characteristics in open water of constructed wetland for water treatment should be considered to improve the removal efficiency of organic matter.

Uptake Patterns of N and P by Reeds (Phragmites australis) of Newly Constructed Shihwa Tidal Freshwater Marshes (시화지구 인공습지에서 갈대에 의한 질소 및 인 흡수)

  • 노희명;최우정;이은주;윤석인;최영대
    • The Korean Journal of Ecology
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    • v.25 no.5
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    • pp.359-364
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    • 2002
  • This study was conducted to examine the seasonal pattern of N and P uptake by reeds (Phragmites australis) planted in newly constructed Shihwa tidal freshwater marshes. Reed and soil samples were collected from the wetland periodically from June 2000 to May 2002. Reed samples were analyzed for dry weight and content of N and P Soil organic matter content and salinity were also determined. Dry matter content of reed increased during the growing season but decreased in the fall and winter. However, this seasonal pattern was not so evident in the second year. In particular, throughout the measurement period, dry matter content of reed was lowest at a site showing high soil salinity. Regression analyses between dry matter content of reed and soil EC(1:5) suggested that dry matter content per unit square meter would decrease by 1.5 kg with every 1 dS m/sup -1/ increase in soil EC(1:5). The amount of N and P assimilated by reed significantly decreased from the fall and was lowest in the spring. Net decrease in N content from reed during the fall and next spring was calculated as 34.5 and 24.6 g m/sup -2/ in the first and second years, respectively, while the corresponding P loss was 4.0 and 1.8 g m/sup -2/. Soil organic mailer content increased in the fall and winter, but decreased in the spring and summer. The results of this study suggested that the removal of N and P by reed would be considerable during the growing season but the nutrients taken up by reeds would return as detritus to the marshes in the fall and winter. Based on the results of the study, therefore, the harvest of the reed at the latter part of the growth would be recommended to prevent further water quality degradation. However, the long-term effects of reed harvest needs further study.

Development and Operation of Canal-type CROM for Water Quality Improvement of Eutrophic Reservoir: Mussel Density Effect (부영양 저수지의 수질개선을 위한 수로형 CROM 개발 및 운영: 패류밀도의 효과)

  • Kim, Baik-Ho;Min, Han-Na;Lee, Song-Hee;Hwang, Soon-Jin
    • Korean Journal of Ecology and Environment
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    • v.43 no.3
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    • pp.369-376
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    • 2010
  • A novel or canal-type continuous removal of organic matter (C-CROM) with combined freshwater bivalves (Unio douglasiae and Anodonta woodiana) was developed to improve the water quality (IWQ) of eutrophic reservoirs. The first experiment was performed for 12 days to measure the IWQ using 256 individuals of combined bivalves (ca. 7:3), at the same density that distributed in the collection stream. The second experiment was conducted to evaluate the efficacy of IWQ with the addition of each 30% of two mussels for 14 days. Results indicated that a novel C-CROM significantly decreased suspended solids, chlorophyll-$\alpha$, transparency, total nitrogen and phosphorus, and increased ammonium and biodeposition (t-test, P<0.001 for all), while other dissolved inorganic nutrients such as $NO_2$, $NO_3$, and SRP did not change (t-test, P>0.5). Daily IWQ performances of C-CROM with combined mussels was about two times higher to the previous studies using single species where less suspended inorganic nutrients were released except for ammonia. Collectively, a C-CROM is more strategic to the water quality improvement of eutrophic lake.