• 환경위생공학
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• 제13권1호
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• pp.44-56
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• 1998

This study was performed to investigate the reaction characteristics of piggery wastewater for biological nutrient removal. The reaction characteristics were discussed the fraction of organics, the behavior of nitrogen, nitrification, denitrification, and the behavior of phosphorus. The fraction of readily biodegradable soluble COD was 11-12 percent. The ammonia nitrogen was removed via stripping, nitrification, autotrophic cell synthesis, and heterotrophic cell synthesis. The removal percents by each step were 12.1%, 68.9%, 15.0%, and 4.0%, respectively. Nitrification inhibition of piggery wastewater was found to occur at an influent volumetric loading rate over 0.2 NH$_{3}$-N kg/m$^{3}$/d. Denitrification rates were the highest in the raw wastewater and the lowest in the anaerobic effluent. The denitritation of piggery wastewater came out to be possible, and the rate of organic carbon consumption decreased about 10 percent. The phosphorus removed was released in the form of ortho-p in the aerobic fixed biofilm reactor, it was caused by autooxidation. The synthesis and release of phosphorus were related to the ORP and the boundary value for the phase change was about 170mV. In the synthesis phase, the phosphorus removal rate per COD removed was 0.023mgP$_{syn}$/mgCOD$_{rem}$. The phosphorus contents of the microorganism were 4.3-6.0% on a dry weight basis.

• 한국농공학회지
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• 제45권7호
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• pp.49-56
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• 2003

Nonpoint source pollutant loading from watershed may cause a problem to the water quality of the reservoir and stream. The characteristics of stream flow and water quality were monitored to investigate the runoff loading of the Namdae-cheon watershed from May in 1999 to October in 2003. Stage-discharge rating curve at the stream gauging site was established, and annual stream runoff of the study watershed was estimated as 499.4∼1,330.8mm during four years. The concentrations of total-nitrogen and total-phosphorus of stream water quality ranged from 0.76 to 6.95mg/L and from 0.0010 to 0.2276 mg/L, respectively, where T-N was generally higher than the water quality standard 1.0 mg/L for agricultural water use. The loads by unit generation of pollutant mass with respect to population, livestock, land use in this watershed were calculated. The runoff pollutant loadings by concentrations of total-N and total-P were estimated during study period, where the annual runoff loading of total-P was much less than the load by pollutant mass unit generation. The relations between stream discharge and water quality were analysed, and there was a high correlation for total-N but low for total-P. These results will be used to develop the monitoring techniques and water quality management system of agricultural watershed.

• 한국환경농학회지
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• 제19권1호
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• pp.26-31
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• 2000

금강수계 상류에 위치하고 있는 전라북도 무주군 남대천 유역을 대상으로 1995년 7월부터 1998년 4월까지 32개월 동안 4개 지점의 수질시료에 대한 질적변화를 주기적으 로 조사하였다. 또한 남대천 유역의 인구, 가축 그리고 토지이용에 따른 원단위 오염부 하량과 실측 오염부하량을 비교 분석하였다. 수계 환경에 영향을 미칠 수 있는 영양물질을 대상으로 시기별 함량 변화를 조사한 결과, 전질소는 $1.8{\sim}5.8\;mg/L$의 범위로 평균 3.8 mg/L, 전인산은 $0.01{\sim}0.08\;mg/L$의 범위로 평균 0.05 mg/L를 나타내었다. 남대천 유역의 원단위 오염부하량은 질소 550.4 ton/yr, 인산 79.1 ton/yr로 나타났는데, 질소원의 경우 가축사육에 의한 부하량이 358.1 ton/yr로 전체의 65.1 %를, 토지이용에 의한 부하량이 129.3 ton/yr로 전체의 23.5 %를, 인구에 의한 부하량이 63.0 ton/yr로 전체의 11.4 %를 차지하는 것으로 조사되었다. 인산원의 오염부하량은 가축 사육에 의한 오염부하량이 60.6 ton/yr로 전체의 76.6 %를, 인구에 의한 부하량이 13.3 ton/yr 로 전체의 16.8 %를, 토지이용에 의한 부하량이 5.2 ton/yr로 전체의 6.6 %를 차지하였다. 각 조사지점별 질소와 인산의 실측 오염부하량은 질소 452.5 ton/yr, 인산 5.4 ton/yr로 나타 났는데 원단위 오염부하량과 비교시 인산의 경우 상당한 차이를 나타내고 있었다.

• Macromolecular Research
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• 제16권7호
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• pp.620-625
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• 2008

A novel nitrogen-phosphorus compound, diphenyl piperazine-1,4-diylbis(methylphosphinate)(DPPMP) was synthesized via a two step reaction and its flame retarding efficiency as a single component additive was investigated. The success of synthesis was confirmed by FTIR and $^1H$ and $^{31}P$ NMR analysis. The product was mixed with polycarbonate (PC), poly(butylene terephtalate) (PBT), ethylene-vinyl-acetate copolymer (EVA), and acrylonitrile-butadiene-styrene copolymer (ABS). The flame-retarding efficiency was evaluated using the limiting oxygen index (LOI) and the UL-94 vertical test methods. The addition of DPPMP enhanced the flame retardancy of the polymers and the V-0 ratings were obtained for the polymers examined in this study at a loading of 7-30 wt%. The gas-phase flame retardancy mode of action was suggested for this material from the thermogrametry experiment results.

• 한국농공학회:학술대회논문집
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• 한국농공학회 2000년도 학술발표회 발표논문집
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• pp.637-642
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• 2000

In order to control the water quality of freshwater lake in tidal reclaimed land, it is needed to evaluate accurate amount of pollutant loadings from reclaimed paddy field. This study was carried out to investigate the pollutant loading from a reclaimed paddy field. Site of the study was a paddy field located in Taeho reclaimed land, with an areas of 38.5 hectares. The runoff loadings of Total-Nitrogen, Total-Phosphorus, and Chemical Oxygen Demand were 49.5 kg/㏊/yr, 3.2 kg/㏊/yr and 154.0 kg/㏊/yr, respectively. The runoff loadings in Total-Nitrogen and Total-Phosphorus from this study were much higher values than the pollutant load factor of Total-Nitrogen and Total-Phosphorus from the paddy field published by the Ministry of Environment.

• 한국물환경학회지
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• 제20권1호
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• pp.24-31
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• 2004

This study was initiated to evaluate the efficiencies of DEPHANOX and Modified-DEPHANOX, which were devoloped to enhance nitrogen removal efficiency in municipal wastewater treatment. In the results, removal efficiency of organic matters was not affected much by increased loading rate of organic matters which is contained in influent. The nitrogen removal efficiencies according to the loading rate of influent TN was decreased drastically in conditions of over $0.2kg/m^3{\cdot}day$, which is T-N loading rate, and the DEPHANOX process was affected more sensitively than the M-DEPHANOX was. When the temperature was altered from $25^{\circ}C$ to $16^{\circ}C$ at HRT 6hrs, the removal efficiency of ammonia nitrogen was still over 90% and it was concluded that both DEPHANOX and M-DEPHANOX were strong enough to endure temperature variation. Moreover, both processes showed over 90% in ammonia removal efficiencies in over HRT 5hrs, so it was concluded that they were strong in HRT variation. M-DEPHANOX process showed a higher value than DEPHANOX did in T-N removal efficiency to the extent of 4~21 %, which resulted from differency of denitrification rates and the biosorption efficiency of organic matter in both processes. In the condition of HRT less than 4hrs, concentrations of ammonia nitrogen contained in effluents and nitrification reactors, might be sensitively affected by biosorption efficiency of organic matters in first separation tank. In the effect of effluent nitrate concentration in phosphorus removal, the more effluent nitrate concentration was decreased, the more phosphorus removal efficiency was increased. This result is related to the decrease of concentration of effluent nitrate which resulted from nitrification inhibition by decreased HRT.

• 한국물환경학회지
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• 제20권6호
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• pp.571-576
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• 2004

Since anaerobic/anoxic/oxic process, which is a typical mainstream biological nitrogen and phosphorus removal process, utilizes influent organic matter as an external carbon source for phosphorus release in anaerobic or anoxic stage, influent COD/T-P ratio gives a strong influence on performance of phosphorus removal process. In this study, a bench scale experiment was carried out for SBR process to investigate nitrogen and phosphorus removal at various influent COD/T-P ratio and nitrate loadings of 23~73 and 1.6~14.3g $NO_3{^-}-N/kg$ MLSS, respectively. The phosphorus release and excess uptake in anoxic condition were very active at influent COD/T-P ratios of 44 and 73. However, its release and uptake was not obviously observed at COD/T-P ratio of 23. Consequently, phosphorus removal efficiency was decreased. In addition, the phosphorus release and uptake rate in anoxic condition increased as the nitrate loading decreased. Specific denitrification rate had significantly high correlation with organic materials and nitrate loadings of the anoxic phase too. The rate of phosphorus release and uptake in the anoxic condition were $0.08{\sim}0.94kg\;S-P/kg\;MLSS{\cdot}d$ and $0.012{\sim}0.1kg\;S-P/kg\;MLSS{\cdot}d$, respectively.

• 한국수산과학회지
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• 제29권6호
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• pp.779-786
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• 1996

The main purpose of this study was to estimate the role of dissolved inorganic nitrogen (DIN) released from sediment and denitrification process in sediment on the nitrogen budget of Hiroshima Bay by means of collecting data on distributions and budgets of nitrogen and phosphorus in the bay, DIN fluxes across sediment-water interface and denitrification rates in the sediments of the same area. The TN : TP and DIN:DIP atomic ratios of the discharged freshwater were about 26 and 21, respectively. The standing stocks in the seawater of the TN : TP atomic ratio varied from 8 to 14 with an annual mean value of 11, while the DIN : DIP atomic ratio varied from 10 to 15 with an annual mean value of 12 in the bay. The residence time of nitrogen and phosphorus were estimated to be about 109 days and 200 days in the bay, respectively. The proportion of DIN released from sediment and denitrification rate to the loading of total nitrogen into Hiroshima Bay were $45\%\;(37\~82\%)\;and\;13\%(0.0\~37\%)$, respectively, and the amount of nitrogen through denitrification process was 6.5 times larger than the outflow of nitrogen from the bay. The results show that DIN released from sediment and denitrification process in sediment play important roles on the nitrogen budget in Hiroshima Bay.

• 한국환경보건학회지
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• 제39권1호
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• pp.83-89
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• 2013

Objectives: The purpose of this experiment was to illuminate the relationship between the phosphorus removal rate of unit operation and the phosphorus removal rate of phosphorus volume loading in the Ferrous Nutrient Removal process, which consists of an anoxic basin, oxic basin, and iron precipitation apparatus. Methods: This study was conducted in order to improve the effect of nitrogen and phosphorus removal in domestic wastewater using the FNR (Ferrous Nutrient Removal) process which features an iron precipitation reactor in anoxic and oxic basins. The average concentration of TN and TP was analyzed in a pilot plant ($50m^3/day$). Results: The removal rate of T-N and T-P were 66.5% and 92.8%, respectively. The $NH_3-N$ concentration of effluent was 2.62 mg/l with nitrification in the oxic basin even though the influent was 17.7 mg/l. The $NO_3$-N concentration of effluent was 5.83 mg/l through nitrification in oxic basin even though the influent and anoxic basin were 0.82 mg/l and 1.00 mg/l, respectively. The specific nitrification of the oxic basin ($mg.NH_3$-Nremoved/gMLVSSd) was 16.5 and specific de-nitrification ($mg.NO_3$-Nremoved/gMLVSSd) was 90.8. The T-P removal rate was higher in the oxic basin as T-P of influent was consumed at a rate of 56.3% in the anoxic basin but at 90.3% in the oxic basin. The TP removal rate (mg.TP/g.MLSS.d) ranged from 2.01 to 4.67 (3.06) as the volume loading of T-P was increased, Conclusions: The test results showed that the electrolysis of iron is an effective method of phosphorus removal. Regardless of the temperature and organic matter content of the influent, the quality of phosphorus in the treated water was both relatively stable and high due to the high removal efficiency. Nitrogen removal efficiency was 66.5% because organic matter from the influent serves as a carbon source in the anoxic basin.

• 한국물환경학회지
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• 제28권1호
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• pp.63-70
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• 2012

This study was carried out to investigate change in influent concentration of domestic wastewater flowed from a newly constructed separate sewer system (SSS) and biological nutrients removal efficiency of a full scale Air-vent sequential batch reactor (SBR, $600m^3/d$). The average concentration of $BOD_5$, SS, T-N and T-P from SSS were 246.5 mg/L, 231.6 mg/L, 42.974 mg/L, 5.360 mg/L, respectively which corresponds to 2.2times, 1.2times, 1.8times and 2.1times higher than those from the conventional combined sewer system (CSS). The removal efficiency of $BOD_5$, SS, T-N, and T-P for the Air-vent SBR operated with influent from SSS averaged 99.1%, 99.0%, 91.2%, and 93.5%, respectively. Especially the respective nitrogen and phosphorus removal was 15% greater than that of the SBR operated with influent from CSS. Simultaneous nitrification and denitrification (SND) was observed in an aerobic reactor(II) as a result of DO concentration gradient developed along the depth by the Air-vent system. In order to achieve T-N removal greater than 90%, the C/N ratio should be over 6.0 and the difference between $BOD_5$ loading and nitrogen loading rate be over 100 kg/day (0.130 kg $T-N/m^3{\cdot}d$). Even with high influent T-P concentration of 5.360 mg/L from SSS (compared with 2.465 mg/L from CSS) T-P removal achieved 93.5% which was 15.5% higher than that of the SBR with influent from CSS. This is probably due to high influent $BOD_5$ concentration from SSS that could provide soluble carbon source to release phosphorus at anaerobic condition. In order to achieve T-P removal greater than 90%, the difference between $BOD_5$ loading and phosphorus loading rate should be over 100 kg /day (0.130 kg $T-N/m^3{\cdot}d$).