• 상하수도학회지
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• 제33권1호
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• pp.9-16
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• 2019

The algal blooms in stagnant streams and lakes have caused many problems. Excessive algae leads to disturbance of ecosystem and overload of water treatment processes. Therefore, phosphorus(P), source of algal blooms, should be controlled. In this study, a filtration trench has been developed to convert dissolved phosphorus into hydroxyapatite(HAP) so that it could be crystallized on the surface of 'phosphorus removal granular material'; and residual particulate phosphorus could be removed by additional precipitation and filtration. The front and rear parts of filtration trench consisted of 'phosphorus removal granular material contact bed' and 'limestone filtration bed', respectively. As a result of the column test using phosphorus removal granular material and limestone serially, $PO_4-P$ was removed more than 90% when EBCT(empty bed contact time) of the contact bed was over 20 minutes; and T-P represented 60% of removal efficiency when total EBCT was over 1.5 hours. The results of column tests to figure out the sedimentation characteristics showed that more than 90% of particulate phosphorus could be removed within 24 hours. It was necessary to optimize the filtration part in order to increase removal efficiency of T-P additionally. Also, it was confirmed through the simulation of Visual MINTEQ that most of particulate phosphorus in the column tests is the form of HAP. Based on the results of the study, it could be suggested that the design parameters are over 0.5 hour of EBCT for phosphorus removal granular material contact bed and over 1.5 hours of EBCT for limestone filtration bed.

• 한국환경보건학회지
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• 제39권1호
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• pp.83-89
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• 2013

Objectives: The purpose of this experiment was to illuminate the relationship between the phosphorus removal rate of unit operation and the phosphorus removal rate of phosphorus volume loading in the Ferrous Nutrient Removal process, which consists of an anoxic basin, oxic basin, and iron precipitation apparatus. Methods: This study was conducted in order to improve the effect of nitrogen and phosphorus removal in domestic wastewater using the FNR (Ferrous Nutrient Removal) process which features an iron precipitation reactor in anoxic and oxic basins. The average concentration of TN and TP was analyzed in a pilot plant ($50m^3/day$). Results: The removal rate of T-N and T-P were 66.5% and 92.8%, respectively. The $NH_3-N$ concentration of effluent was 2.62 mg/l with nitrification in the oxic basin even though the influent was 17.7 mg/l. The $NO_3$-N concentration of effluent was 5.83 mg/l through nitrification in oxic basin even though the influent and anoxic basin were 0.82 mg/l and 1.00 mg/l, respectively. The specific nitrification of the oxic basin ($mg.NH_3$-Nremoved/gMLVSSd) was 16.5 and specific de-nitrification ($mg.NO_3$-Nremoved/gMLVSSd) was 90.8. The T-P removal rate was higher in the oxic basin as T-P of influent was consumed at a rate of 56.3% in the anoxic basin but at 90.3% in the oxic basin. The TP removal rate (mg.TP/g.MLSS.d) ranged from 2.01 to 4.67 (3.06) as the volume loading of T-P was increased, Conclusions: The test results showed that the electrolysis of iron is an effective method of phosphorus removal. Regardless of the temperature and organic matter content of the influent, the quality of phosphorus in the treated water was both relatively stable and high due to the high removal efficiency. Nitrogen removal efficiency was 66.5% because organic matter from the influent serves as a carbon source in the anoxic basin.

• 대한환경공학회지
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• 제22권5호
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• pp.861-867
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• 2000

무산소 조건에서의 인섭취를 이용한 질소, 인 화합물의 동시 제거 가능성을 연속회분식반응기(SBR)를 사용하여 고찰하였다. 혐기-호기상의 AO SBR 반응기에 점차적으로 무산소상을 도입함으로써 질산염을 전자수용체로 사용하여 탈질이 가능한 인섭취 미생물들(DPAOs)을 다량으로 축적하였다.(혐기-호기-무산소-호기상의 $(AO)_2$ SBR). 무산소상과 호기상에서의 인섭취율을 비교해 보았을 때, 전체 인제거 미생물 내에서 DPAOs의 비율이 약 10%에서 64%까지 증가하였다. $(AO)_2$ SBR은 안정된 질소, 인제거 성능을 보였으며, 유기물질, 질소, 인 화합물의 제거율은 각각 92%, 88%, 100%였다. $(AO)_2$ SBR의 운전결과와 회분식 실험으로 부터 아질산염은 무산소상에서의 인제거 반응에 어떠한 악영향도 미치지 않으며, 오히려 질산염과 함께 전자 수용체로 사용되어짐을 알 수 있었다.

• 한국물환경학회지
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• 제20권6호
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• pp.571-576
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• 2004

Since anaerobic/anoxic/oxic process, which is a typical mainstream biological nitrogen and phosphorus removal process, utilizes influent organic matter as an external carbon source for phosphorus release in anaerobic or anoxic stage, influent COD/T-P ratio gives a strong influence on performance of phosphorus removal process. In this study, a bench scale experiment was carried out for SBR process to investigate nitrogen and phosphorus removal at various influent COD/T-P ratio and nitrate loadings of 23~73 and 1.6~14.3g $NO_3{^-}-N/kg$ MLSS, respectively. The phosphorus release and excess uptake in anoxic condition were very active at influent COD/T-P ratios of 44 and 73. However, its release and uptake was not obviously observed at COD/T-P ratio of 23. Consequently, phosphorus removal efficiency was decreased. In addition, the phosphorus release and uptake rate in anoxic condition increased as the nitrate loading decreased. Specific denitrification rate had significantly high correlation with organic materials and nitrate loadings of the anoxic phase too. The rate of phosphorus release and uptake in the anoxic condition were $0.08{\sim}0.94kg\;S-P/kg\;MLSS{\cdot}d$ and $0.012{\sim}0.1kg\;S-P/kg\;MLSS{\cdot}d$, respectively.

• Advances in environmental research
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• 제3권2호
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• pp.163-172
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• 2014

Magnetite was chosen as a typical adsorbent to study its phosphate adsorption capacity in water body with low concentration of phosphorus (below $2mg\;PL^{-1}$). Magnetite was collected from Luoyang City, Henan Province, China. In this research, three factors have been studied to describe the adsorption of phosphate on magnetite, which was solution concentration (concentration ranging from 0.1 to $2.5mg\;PL^{-1}$), suspension pH (1 to 13) and temperature (ranging from $10^{\circ}C$ to $40^{\circ}C$). In addition, the modified samples had been characterized with XRD and FE-SEM image. The results show that iron ions contains in magnetite were the main factors of phosphorus removal. The behavior of phosphorus adsorption to substrates could be fitted to both Langmuir and Freundlich isothermal adsorption equations in the low concentration phosphorus water. The theoretical saturated adsorption quantity of magnetite is 0.158 mg/g. pH has great influence on the phosphorus removal of magnetite ore by adsorption. And pH of 3 can receive the best results. While temperature has little effect on it. Magnetite was greatly effective for phosphorus removal in the column experiments, which is a more practical reflection of phosphorous removal combing the adsorption isotherm model and the breakthrough curves. According to the analysis of heavy metals release, the release of heavy metals was very low, they didn't produce the secondary pollution. The mechanism of uptake phosphate is in virtue of chemisorption between phosphate and ferric ion released by magnetite oxidation. The combined investigation of the magnetite showed that it was better substrate for water body with low concentration of phosphorus.

• 한국물환경학회지
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• 제28권1호
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• pp.50-56
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• 2012

In this study, loess composites, loess with lanthanum and with aluminum, were made and evaluated for treatment of phosphorus removal in natural water system. Desiccation method for production of loess composite was superior to centrifugation method in obtaining high concentrated composites of lanthanum and aluminum. Washing of loess lanthanum composite by water did not deteriorat the lanthanum concentration in the composite, but this lowered the aluminum concentration of loess aluminum composite. Total of 15 and 37.5% of aluminum contents were removed after first washing treatment in aluminum loess of 0.05% and 0.1% respectively. However, no more aluminum loss was monitored with increase of washing times. Phosphorus removal efficiencies were not decreased with washed loess aluminum composite. Phosphorus removal was successfully achieved by adsorption of phosphate to loess composite at pH range of 5.0 ~ 8.0. Freundlich and Langmuir adsorption isotherm was observed in the adsorption of phosphate for loess composite. Dosages of 0.05% and 0.1% lanthanum composite for 95% of phosphorus removal could reduce its usage amount to 25% and 50%, respectively, comparing with dosage of loess alone. Dosages of 0.05% and 0.1% aluminum composite could reduce its usage amount to 48% and 63%, respectively.

• 환경위생공학
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• 제13권1호
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• pp.44-56
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• 1998

This study was performed to investigate the reaction characteristics of piggery wastewater for biological nutrient removal. The reaction characteristics were discussed the fraction of organics, the behavior of nitrogen, nitrification, denitrification, and the behavior of phosphorus. The fraction of readily biodegradable soluble COD was 11-12 percent. The ammonia nitrogen was removed via stripping, nitrification, autotrophic cell synthesis, and heterotrophic cell synthesis. The removal percents by each step were 12.1%, 68.9%, 15.0%, and 4.0%, respectively. Nitrification inhibition of piggery wastewater was found to occur at an influent volumetric loading rate over 0.2 NH$_{3}$-N kg/m$^{3}$/d. Denitrification rates were the highest in the raw wastewater and the lowest in the anaerobic effluent. The denitritation of piggery wastewater came out to be possible, and the rate of organic carbon consumption decreased about 10 percent. The phosphorus removed was released in the form of ortho-p in the aerobic fixed biofilm reactor, it was caused by autooxidation. The synthesis and release of phosphorus were related to the ORP and the boundary value for the phase change was about 170mV. In the synthesis phase, the phosphorus removal rate per COD removed was 0.023mgP$_{syn}$/mgCOD$_{rem}$. The phosphorus contents of the microorganism were 4.3-6.0% on a dry weight basis.

• 한국물환경학회지
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• 제29권6호
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• pp.782-789
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• 2013

Enhanced biological phosphorus removal (EBPR) behavior and microbial characteristics in the anaerobic-aerobic SBR (PAO SBR) and the anaerobic-anoxic SBR (DPAO SBR) were examined in this research. For 392 days of operation, both SBRs have exhibited a good EBPR (or denitrifying EBPR) performance. $P_{release}/P_{influent}$ ratio was highest in both reactors after the stabilization, while the efficiency of phosphorus removal was decreased since the sludge granulation has been visually observed within the reactor. The comparative analysis of Pyrosequencing-based microbial population between PAO and DPAO sludges showed indirectly that Dechloromonas spp. could utilize $O_2$ and $NO_3{^-}-N$ as an electron acceptor and Accumulibacter phosphatis use only $O_2$ in EBPR system. Also, we concluded that Thauera spp. as a denitrifier contribute significantly to the anoxic phosphorus removal in the DPAO system.

• 한국환경과학회지
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• 제30권11호
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• pp.945-956
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• 2021

In this study, the effects of single and binary heavy metals toxicity on the growth and phosphorus removal ability of Bacillus sp.. known as be a phosphorus-removing microorganism, were quantitatively evaluated. Cd, Cu, Zn, Pb, Ni were used as heavy metals. As a result of analysis of variance of the half of inhibition concentration and half of effective concentration for each single heavy metal treatment group, the inhibitory effect on the growth of Bacillus sp. was Ni < Pb < Zn < Cu < Cd. And the inhibitory effect on phosphorus removal by Bacillus sp. was Ni < Pb < Zn < Cu < Cd. When analyzing the correlation between growth inhibition and phosphorus removal efficiency of a single heavy metal treatment group, a negative correlation was found (R² = 0.815), and a positive correlation was found when the correlation between IC₅₀ and EC₅₀ was analyzed (R² = 0.959). In all binary heavy metal treatment groups, the interaction was an antagonistic effect when evaluated using the additive toxicity index method. This paper is considered to be basic data on the toxic effects of heavy metals when phosphorus is removed using phosphorus removal microorganisms in wastewater.

• 한국환경농학회지
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• 제29권2호
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• pp.189-196
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• 2010

The removal of phosphorus (P) in the wastewater is essential for the prevention of eutrophication in the river and stream. This study was initiated to evaluate the effect of the various heavy metals on the growth and P removal capacity of Pseudomonas sp., which was well known as phosphorus accumulating microorganism(PAO's) in the EBPR(Enhanced Biological Phosphorus Removal) process. The five heavy metals used in the study were Cu, As, Zn, Ni, and Cd. The growth rate of Pseudomonas sp. was the greatest at $25^{\circ}C$, but the removal efficiency of P was the highest at $30^{\circ}C$. The $IC_{50}$ (median Inhibition Concentration) values of Pseudomonas sp. for the Cu, As, Zn, Ni, and Cd were 2.35, 11.04, 1.80, 4.92, and 0.24 mg/L, respectively. Therefore, it appears that the sensitivity of the heavy metals to Pseudomonas sp. was in the following order: Cd> Zn> Cu> Ni> AS. Also, the P removal efficiencies by Pseudomonas sp. were correspondingly decreased as the concentrations of heavy metals were increased.