• Journal of Korean Society of Water and Wastewater
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• v.26 no.5
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• pp.713-721
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• 2012

In many instances phosphorus is a limiting factor for eutrophication in streams, and lakes. Because wastewater treatment plant itself may be the main phosphorus source in a natural water body, removal of phosphorus in final effluent of wastewater treatment processes is required. Amongst various technologies for phosphorus removal in wastewater, adsorption technology was investigated using activated Ca-loess complex. Ca was added in loess to enhance adsorption capacity and intensity of phosphorus. Ca added loess was activated at a high temperature of $400^{\circ}C$ which turned out to be the optimum temperature. Activated Ca-loess complex below $400^{\circ}C$ had not enough strength to be applied as an activated Ca-loess pallet column in wastewater treatment process. Ca-loess complex which activated above $400^{\circ}C$ lost its adsorption capacity as the loess surface was glassified when the activation temperature reached above $400^{\circ}C$20. Even if adsorption capacity of activated Ca-loess was not very high due to the lack of abundant pores on its surface, adsorption intensity was still high because it was activated with added Ca in loess. Activated loess was made by pallets. The activated loess pallets were filled in a column, and were applied in wastewater treatment process. Using an activated Ca-loess pallet column, total phosphorus (T-P) was reduced from about 0.5 mg/l to lower than 0.1 mg/l in wastewater treatment, and ionic phosphorus (phosphate) was completely removed for the four months of pilot plant operation.

• Journal of Microbiology and Biotechnology
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• v.13 no.3
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• pp.385-393
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• 2003

Microbial communities were analyzed in an anaerobic/aerobic sequencing batch reactor (SBR) fed with glucose as a sole carbon source. Scanning electron microscopy (SEM) showed that tetrad or cuboidal packet bacteria dominated the microbial sludge. Quinone, slot hybridization, and 165 rRNA gene sequencing analyses showed that the Proteobacteria beta subclass and the Actinobacteria group were the main microbial species in the SBR sludge. However, according to transmission electron microscopy (TEM), the packet bacteria did not contain polyphosphate granules or glycogen inclusions, but only separate coccus-shaped bacteria contained these, suggesting that coccus-shaped bacteria accumulated polyphosphate directly and the packet bacteria played other role in the enhanced biological phosphorus removal (EBPR). Based on previous reports, the Actinobacteria group and the Proteobacteria beta subclass were very likely responsible for acid formation and polyphosphate accumulation, respectively, and their cooperation achieved the EBPR in the SBR operation which was supplied with glucose.

• Journal of Environmental Health Sciences
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• v.31 no.2 s.83
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• pp.172-178
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• 2005

A laboratory experiment was performed to investigate simultaneous removal of phosphorus and nitrogen from raw sewage by intermittently aerated activated sludge process packed with aluminum and silver plate. Two continuous experimental process, i.e. an intermittently aerated activated sludge process, and an intermittently aerated activated sludge process with an aluminum and silver plate packed into the reactor were compared. The pitting corrosion of aluminum does not affect the performance of the biological treatment. The amounts of Al eluted from aluminum plate 17 mg to 60.6 mg in this experimental conditions, and Al/P mole ratio were from 3.31 to 11.25. The total nitrogen removal efficiency in Run E were $60.6\%$ at the HRT of 12 hours. The effluent $PO_4-P$ concentration as low as $1.0\;mg/\iota$ could have been obtained during the continuous experiment in Run E at HRT of 12 hours.

• Proceedings of the Korean Environmental Health Society Conference
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• 2003.06a
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• pp.98-101
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• 2003

The pilot scale experiment was performed to investigate phosphorus and nitrogen removal from sewage by intermittently activated sludge process combined with the electrochemical interaction (Localized Corrosion) of aluminum and silver. The average T-N removal rate for HRT of 24hr was 57.4%. It was possible to remove P in sewage to under 1 mg/L with a short HRT of 12 hr using Al and Ag plate but often required additional A1 plate supplement during the operation.

• Journal of Korean Society on Water Environment
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• v.22 no.6
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• pp.1031-1037
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• 2006

In order to improve water quality of the Juam Lake, a constructed wetland was implemented and operated for 2 years with the effluent of sewage treatment plant and diffuse pollutant discharged from agricultural area. During the summer season, average removal efficiencies for BOD and SS were 15.8% and 39.4%, respectively. Due to the mixed effect of vegetation, soil microbes and sediments, the higher nutrient removal efficiencies were obtained: average T-N and T-P removal efficiencies were 64.2% and 71.7%, respectively. The concentration of sediment was increased initially, and maintained constant throughout monitoring period. The highest nitrogen and phosphorus uptake were observed in Phragmites japonica. The nitrogen uptake was estimated as 0.235 DW mg/g while phosphorus uptake was estimated as 2.059 DW mg/g.

• Journal of Environmental Science International
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• v.12 no.1
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• pp.55-61
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• 2003

This study was carried out to obtain the operating characteristics of SMMIAR process for biological nitrogenㆍphosphorus removal. SMMIAR was operated at HLR(Hydraulic loading rate) of 39.6, 52.8, 63.4 and 79.2 $\ell$/$m^2$/d respectively and the operating parameters such as intermittent aeration time ratio of aerobic/anoxic, DO and microorganism concentration were changed to confirm the optimum operating condition. The concentrations of the wastewater BOD, TN(Total nitrogen) and TP(Total phosphorus) were 150, 30 and 7.5mg/$\ell$ respectively. Achieving better removal efficiencies of BOD, TN and TP up to 90, 85.4 and 95.4% respectively, we must keep in operation condition of SMMIAR by 0.75 of time ratio of aerobic/anoxic and by minimum 45 minutes of oxic period simultaneously.

• Journal of Korean Society of Water and Wastewater
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• v.19 no.4
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• pp.455-461
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• 2005

This study was designed to investigate the fundamental aspects of a possible recovery of phosphorus strategy from wastewater by using the zirconium mesoporous structured materials as a new type of ion exchangers. Zirconium mesoporous structure material was synthesized by hydro-thermal synthesis. The synthesized zirconium mesoporous structure was examined by X-ray diffraction (XRD) and Transmission electron micrograph (TEM). From the results of XRD and TEM, it was found out that hexagonal mesoporous structure, pore size was about $47{\AA}$, was synthesized. Experimental results showed that the complex of zirconium sulfate tetrahydrate and surfactant micelles had very high ability for capture of phosphorus. The amount of phosphate ions exchanged into the solid was as great as 3.4mmol/g-ZS. And the ion exchange reaction was occurred between $PO_4{^{3-}}$ and $SO_4{^{2-}}$ and also between $PO_4{^{3-}}$ and $OH^-$. Therefore, it is possible to get the higher removal efficiency than other ion exchange media and adsorbent.

• Journal of Korean Society on Water Environment
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• v.27 no.6
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• pp.754-759
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• 2011

A sequencing batch reactor (SBR) was operated under different pH conditions to better understand the influence of pH to granulation in enhanced biological phosphorus removal systems. Granules from the SBR were also investigated using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). Considerable decreases in the amount of phosphorus released per substrate provided under anaerobic conditions and the content of biomass polyphosphate under aerobic conditions were observed when pH was changed from 7.5 to 7.0, followed by 6.5. Aerobic granulation was also observed at pH 7.0. A number of bacteria with the typical morphological traits of tetrad-forming organisms (TFOs) were observed at pH 7.0, including large members of cluster. Filamentous bacteria were also there in large numbers. The occurrence and growth of granules were further enhanced at pH 6.5. A SEM analysis showed that the aerobic granules had a compact microbial structure with shaperical shape and morphologically consisted of aggregates of small coccoid bacteria and filamentous bacteria encapsulated by extracellular polymeric substance. The main material ions identified by EDX moreover revealed that the structural materials for polyphosphate in the granules include phosphorus, potassium and calcium. Therefore, these results strongly suggested that PAOs are a dominant population in the microbial community of the aerobic granules.

• Journal of Microbiology and Biotechnology
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• v.10 no.4
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• pp.455-461
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• 2000

Abstract Spirulina platensis was grown in SWlUe waste to reduce inorganic compowlds and simultaneously produce feed resources. Spirulina platensis prefers nitrogenous compounds in Ibe order: $NH_4^{+}-N>NO_3^{-}-N>simple-N$ such as urea and simple amino acids. It even consumes $NH_4^{+}-N$ first when urea or nitrate are present. Therefore, the content of residual $NH_4^{+}-N$ in Spimlina platensis cultures can be determined by the relative extent of the following processes: (i) algal uptake and assimilation; (ii) ammonia stripping; and (iii) decomposition of urea to NH;-N by urease-positive bacteria. The removal rates of total nitrogen ffild total phosphorus were estimated as an indicator of the treatment effIciency. It was found that Spirulina platensis was able to reduce 70-93% of $P_4^{3-}-P$, 67-93% of inorganic nitrogen, 80-90% of COD, and 37-56% of organic nitrogen in various concentrations of swine waste over 12 days of batch cultivation. The removal of inorganic compounds from swine waste was mainly used for cell growth, however, the organic nitrogen removal was not related to cell growlb. A maximum cell density of 1.52 dry-g/l was maintained with a dilution rate of 0.2l/day in continuous cultivation by adding 30% swine waste. The nitrogen and phosphorus removal rates were correlated to the dilution rates. Based on the amino acid profile, the quality of the proteins in the Spirulina platensis grown in the waste was the same as that in a clean culture.ulture.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.3
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• pp.150-153
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• 2016

This study evaluates the efficacy of titanium tetrachloride ($TiCl_4$) on phosphorus (P) removal in synthetic wastewater. Jar test experiments were performed at various $TiCl_4$ concentration (0.25-0.59 mM), and intensities of slow (30-60 rpm) and rapid (100-250 rpm) mixings to determine the conditions at which P removal was most efficient. The P-removal efficiency was highest (about 99%) at $TiCl_4$ concentration $([TiCl_4])=0.39mM$ with rapid-mixing intensity=100 rpm and slow-mixing intensity=30 rpm. The slow-mixing intensity was more sensitive than the rapid-mixing intensity to the P removal efficiency when [$TiCl_4$] was low ($0.25{\leq}[TiCl_4]{\leq}0.27mM$).