• Advances in environmental research
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• 제3권2호
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• pp.163-172
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• 2014

Magnetite was chosen as a typical adsorbent to study its phosphate adsorption capacity in water body with low concentration of phosphorus (below $2mg\;PL^{-1}$). Magnetite was collected from Luoyang City, Henan Province, China. In this research, three factors have been studied to describe the adsorption of phosphate on magnetite, which was solution concentration (concentration ranging from 0.1 to $2.5mg\;PL^{-1}$), suspension pH (1 to 13) and temperature (ranging from $10^{\circ}C$ to $40^{\circ}C$). In addition, the modified samples had been characterized with XRD and FE-SEM image. The results show that iron ions contains in magnetite were the main factors of phosphorus removal. The behavior of phosphorus adsorption to substrates could be fitted to both Langmuir and Freundlich isothermal adsorption equations in the low concentration phosphorus water. The theoretical saturated adsorption quantity of magnetite is 0.158 mg/g. pH has great influence on the phosphorus removal of magnetite ore by adsorption. And pH of 3 can receive the best results. While temperature has little effect on it. Magnetite was greatly effective for phosphorus removal in the column experiments, which is a more practical reflection of phosphorous removal combing the adsorption isotherm model and the breakthrough curves. According to the analysis of heavy metals release, the release of heavy metals was very low, they didn't produce the secondary pollution. The mechanism of uptake phosphate is in virtue of chemisorption between phosphate and ferric ion released by magnetite oxidation. The combined investigation of the magnetite showed that it was better substrate for water body with low concentration of phosphorus.

• 접착 및 계면
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• 제20권2호
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• pp.61-65
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• 2019

본 연구에서는 인계 폴리올을 phenylphosphonic dichloride (PPDC), allylphosphonic dichloride (APDC)에 ethylene glycol (EG)을 반응시켜 합성하였고 분자량이 880~1,560 g/mol의 폴리올 얻었다. 이를 이용하여 polycarbonate diol (PCD)와 함께 4,4'-diphenylmethane diisocyanate (MDI)와 중합하여 인계 폴리우레탄을 얻었다. 합성한 인계 폴리우레탄의 인의 합량이 높아질수록 열분해 온도는 감소하였지만 챠 (char)의 발생과 발생양이 증가하는 것을 확인하였다. 또한 UL-94V 시험법을 통하여 APDC를 포함하는 인계 폴리우레탄 인의 함유량이 0.5 wt%이상일 때 V-0의 난연등급되는 것을 확인하였다.

• Applied Biological Chemistry
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• 제40권2호
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• pp.134-138
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• 1997

대기 $CO_2$ 상승시 인산공급이 대두식물체의 광합성 및 질소고정에 미치는 영향을 살펴보고저 Bradyrhizobium japonicum MN110을 접종한 대두 식물체를 인산결핍구(0.05 m-P) 및 대조구(1.0 mM-P)를 처리하여 정상 $CO_2(400\;{\mu}l/L)$와 상승 $CO_2(800\;{\mu}l/L)$의 조건인 phytotron에서 35일 동안 재배하였다. 인산결핍은 건물량을 정상 $CO_2$ 처리시 51%, 상승 $CO_2$ 처리시 64%를 감소시켰고 총 엽면적도 유의성있게 감소시켰으나 specific leaf weight는 증가시켰다. 광합성 속도 및 잎내부의 $CO_2$농도는 인산결집구에서 감소하였고 그 정도는 $CO_2$ 상승처리시 더욱 컸으며 질소고정능과 근류생체량도 인산결핍시 감소하였으나 잎의 질소농도는 인산대조구가 30% 감소하였다. 이러한 결과는 $CO_2$ 상승조건에서도 인산이 결핍될 경우 식물생육을 촉진시키지 못하며 인산은 정상 $CO_2$ 농도시 보다 $CO_2$ 상승조건에서 근류의 성장과 작용에 더욱 중요한 역할을 하는것으로 유추된다.

• 생태와환경
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• 제37권2호통권107호
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• pp.205-212
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• 2004

아시아 몬순지역에서 대형댐의 인순환(phosphorus cycle)과정의 특징을 파악하기 위하여 소양호를 대상으로 인순환 과정을 조사하였다. 또한, 이를 모의하기 위해 2차원 수질모델인 CE-QUAL-W2를 적용하여 수중생태계의 물질순환과정을 모의하였다. 소양호는 수심이 깊고성층이 강하여 수직적인 변이가 뚜렷한 인의 분포를 보였다. 인의 부하량은 유역면적의 90%를 차지하는 주유입하천인 소양강의 인농도를 측정하여 산정하였다. 소양강의 인농도는 강우시 유량 증가에 따라 크게 증가하는 변동을 보였으므로 인의 부하량은 간헐적으로 발생하는 폭우 유출에 집중되었다. 폭우시 유출수는 수온이 낮아지기 때문에 호수의 중층으로 잠류하여 중층 탁수대를 형성하는 것으로 관측되었다. 여름 우기가 끝난 후 중층에는 두께 20${\sim}$30m의 인함량이 높은 탁수층이 형성되었으며 이탁수층은 댐 중간수심에 만들어진 발전방류구를 통하여 서서히 방류되었다. CE-QUAL-W2 모델은 호우시 탁수의 잠류현상과 인함량이 높은 중층의 형성, 인의 수평수직분포 등의 인순환 과정이 잘 모의 하여,아시아 몬순지역의 댐에서 수질모델로서 육수학적 현상을 잘 모의하는 것으로 평가된다.

• 생명과학회지
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• 제15권4호
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• pp.584-589
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• 2005

담체인 황토볼와 Chromobacterium WS 2-14을 이용하여 F-STEP공정(혐기${\rightarrow}$ 호기${\rightarrow}$ 무산소)에서 실제폐수에 존재하는 인산을 효율적으로 제거하기 위해 최적 황토볼 크기 및 소성 온도, 폐수의 초기 pH,폐수의 초기 인산염 농도, 운전온도, 그리고 통기를 검토했다. 최적 조건은 다음과 같다. 황토볼 크기 및 소성 온도, $2\~4mm,\;960^{\circ}C$; 실페수의 초기pH, 6.0; 실페수의 초기 인산 농도, 5.0mg/1. 운전온도, $30^{\circ}C$; 그리고 통기, 5.0L/min등이 얻어졌다. 그리고 최적 운전조건을 이용해서 pilot test을 65일 동안 진행했다. 인산 평균 제거율은 $92.0\%$였고. 또한 최종 유출수에서 COD와 BOD의 평균 제거율은 각각 77.1와 $74.2\%$였으며, SS의 경우는 평균 제거율이, $86.4\%$였다. 이상의 결과로부터 황토볼을 담체로 이용한 Biofilter System은 실제폐수에 존재하는 인산 제거 가능성을 암시했다.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2008년도 제38차 학술발표대회
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• pp.31-33
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• 2008

The study related that Red Phosphorus is surface coated by Al(OH)$_3$ using the proportion 1:1, 1:3, 1:5 respectively, and then take the coated red phosphorus as the core material, at the same time, use Melamine-Formaldehyde resin as the capsule materials for microcapsule processing. According to the TG analysis, the coated red phosphorus with the proportion 1:3 has the tiptop temperature of thermal decomposition, it reaches 376.20^{\circ}C$$. The same to the ratio of burning incomplete carbon it reaches 26.5%. The lowest moisture absorption ratio of the red phosphorus that used coated red phosphorus for microcapsule processing can reach 0.5% with the condition that thermal decomposition temperature decline 3.6%.

• 한국식품위생안전성학회지
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• 제12권2호
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• pp.107-110
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• 1997

To examine the effects of residual phosphorus content on color reversion and storage stability of corn germ oil, the changes of Lovibond total color and stability of oxidation were determined according to the different storage periods at room and incubating temperature, respectively. The residual phosphorus content and storage temperature had the synergistic effect on color reversion during short time storage. The extent of color change was the greatest when oils were stored for 1.0∼1.5 years at room temperature and thereafter gradually tended to reverse color reversion. It is supposed that the double bonds of carotenoids in oils were oxidized and then turned to the volatiles such as epoxide, ionone, and etc. In contrast, the residual phosphorus content increased oxidation stability of oils. The residual phosphorus content was closely correlated with the color reversion and storage stability, respectively.

• 한국물환경학회지
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• 제29권2호
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• pp.170-175
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• 2013

Achieving very low phosphorus levels in treated wastewater will require the installation of additional treatment. Phosphorus removal experiments by chemical coagulation were carried out for the effluent of wastewater treatment plant in this study. TP (total phosphorus) or phosphate were highly related to the addition of PAC (poly aluminium chloride) which is one of the inorganic coagulants. But, organic polymer did not significantly affect the phosphorus removal efficiency. Polymer affected the flocculation of particle especially particle matter less than 10 micrometer so, the number of micro particles was decreased by polymer dose. Chlorination would not affect on chemical coagulation process and TP and turbidity could be effectively removed by the co-addition of PAC and polymer.

• Macromolecular Research
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• 제13권2호
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• pp.128-134
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• 2005

The phosphorus comonomer [(6-oxido-6H-dibenz<1,2>oxaphosphorin-6-yl)methyl]-methyl butane-dioate (DOP-MBDA) was synthesized through the addition reaction of dimethyl itaconate (DMI) with 9,10-dihydro­9-oxa-10-phosphaphenan threne-10-oxide (DOP). A series of novel flame retardant poly(butylene terephthalate)s (PBTs) containing different amounts of phosphorus were prepared using DOP-MBDA as a comonomer. These novel polymers were characterized by $^{1}H-NMR$, IR, and differential scanning calorimetry (DSC). The novel phosphorus­containing poly(butylene terephthalate)s, referred to as FR-PBTs, exhibited interesting thermal and mechanical behavior, as well as superior flame retardancy. These properties are attributed to the effect of incorporating the rigid structure of DOP-MBDA and the pendant phosphorus group into the poly(butylene terephthalate) (PBT) homopolymer. The UL 94-V2 rating could be achieved with this novel flame retardant PBT, which has a phosphorus content as low as $0.5 wt\%$, and the FR-PBTs emitted less fumes and toxic gases than the PBT homopolymer.

• 한국환경보건학회지
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• 제35권2호
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• pp.116-123
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• 2009

Laboratory scale experiments were conducted to investigate the removal characteristics of nitrogen and phosphorus by the variation of aeration time in four sequencing batch reactors (SBRs). In R1 which has the shortest aeration time as 1 h, MLVSS concentration in reactor decreased by the wash-out of biomass because of the poor sedimentation. The TOC removal efficiencies were almost similar in 3 reactors except R1. At the low aeration time as 1 h, the nitrification was severely inhibited by the deficiency of oxygen. ${NH_4}^+$-N removal efficiency was decreased by the decrease of aeration time. At the aeration time over 2 h, the phosphorus removal efficiency was not affected by the variation of aeration time. The nitrification was inhibited but the phosphorus release and uptake was not inhibited by the decrease of low aeration time. Therefore, we can see that the phosphorus removal microorganisms are superior to nitrification microorganisms in oxygen utilization.