• Journal of Korean Society of Water and Wastewater
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• v.26 no.5
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• pp.713-721
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• 2012

In many instances phosphorus is a limiting factor for eutrophication in streams, and lakes. Because wastewater treatment plant itself may be the main phosphorus source in a natural water body, removal of phosphorus in final effluent of wastewater treatment processes is required. Amongst various technologies for phosphorus removal in wastewater, adsorption technology was investigated using activated Ca-loess complex. Ca was added in loess to enhance adsorption capacity and intensity of phosphorus. Ca added loess was activated at a high temperature of $400^{\circ}C$ which turned out to be the optimum temperature. Activated Ca-loess complex below $400^{\circ}C$ had not enough strength to be applied as an activated Ca-loess pallet column in wastewater treatment process. Ca-loess complex which activated above $400^{\circ}C$ lost its adsorption capacity as the loess surface was glassified when the activation temperature reached above $400^{\circ}C$20. Even if adsorption capacity of activated Ca-loess was not very high due to the lack of abundant pores on its surface, adsorption intensity was still high because it was activated with added Ca in loess. Activated loess was made by pallets. The activated loess pallets were filled in a column, and were applied in wastewater treatment process. Using an activated Ca-loess pallet column, total phosphorus (T-P) was reduced from about 0.5 mg/l to lower than 0.1 mg/l in wastewater treatment, and ionic phosphorus (phosphate) was completely removed for the four months of pilot plant operation.

• Ocean and Polar Research
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• v.33 no.2
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• pp.99-111
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• 2011

To estimate the effects of limitation nutrients for phytoplankton growth and its influences on short-term variations of a winter phytoplankton community structure, we investigated the abiotic and biotic factors of surface and bottom waters at 20 stations of inner and offshore areas from 6 to 7 February in Gwangyang Bay, Korea. Also, several algal bio-assay studies were conducted to identify any additional nutrient effects on phytoplankton assemblage using surface water for the assay. The dominant species in the bay was diatom Skeletonema costatum, which occupied more than 70% of total species in most stations (St.1-16) of the inner bay. According to a cluster and multidimensional scaling (MDS) analysis based on phytoplankton community data from each station, the bay was divided into three groups. The first group included stations from the south-western parts of Myodo lsland, which can be characterized as a semien-closed eutrophic area with high phytoplankton abundance. The second group included most stations from the north-eastern part of Myodo lsland, influenced indirectly by surface water currents from offshore of the bay. The standing phytoplankton crops were lower than those of the first group. The other cluster was restricted to samples collected from offshore of the bay. In the bay, silicon (Si) and phosphorus (P) were not a major limiting factor for phytoplankton production. However, since the DIN: DIP and DSi: DIN ratios clearly demonstrated that there were potential stoichiometric N limitations, nitrogen (N) was considered as a limiting factor. Based on the algal bio-assay, in vivo fluorescence values in N (+) added experiments were higher compared to control and P added experiments. Our results suggested that nitrogen may act as one of the most important factors in controlling primary production during winter in Gwangyang Bay.

• Journal of Wetlands Research
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• v.10 no.2
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• pp.81-96
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• 2008

This study was performed to know about the characteristics of geochemicals of sampling sites in Suncheon bay. Salinity and parameters of water pollution as COD, DIN and DIP showed typical character of an estuary with its values higher at the end of estuary and gradually lowering at the up stream. The value of Excess DIN showed positive so the phosphorus appeared in a role as limiting nutrient. As quoted results of correlation analysis of SPSS and PCA, salinity was revealed as a main factor of control for water qualities at sampling sites in Suncheon bay. The Mz of wet lands and intertidal zone in Sun-cheon bay showed a variation of 6.74 to $8.52{\phi}$ and the sorting also to appeared poorly sorted to very poorly sorted. The fractional composition of phosphorus in phosphorus of sediments were high and appeared orderly as redisual-P> NAI-P> apatite-P> absorbed-P. The labile-Phosphorus showed high concentration then the other station. It means that phosphorus of these stations can easily move from the deposit to the water column than another station.

• Journal of Korean Society of Water and Wastewater
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• v.16 no.6
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• pp.670-678
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• 2002

Since Korean government imposed a stricter regulation on effluent T-N and T-P concentrations from wastewater treatment plant, a new process has to be developed to meet these rules and this process should remove T-N and T-P, economically, from weak wastewater that is typical for Korea's combined sewer system sewage. In this study, a computer simulator, BioWin from EnviroSim, Inc. was used. Three processes - A2/O, Modified Johannesburg, UCT- had been simulated under same operational conditions and a new process - Parallel BNR Process - had been developed based on these simulation results. The Parallel BNR process consists of two rows of reactors: One row has anaerobic and aerobic reactors in series, and the other row has RAS anoxic1 and RAS anoxic2 reactors in series. In order to ensure anaerobic state in anaerobic tank, a part of influent is fed to RAS anoxic1 tank in second row. This process had been simulated under same conditions of other three processes and the simulation results were compared. The results showed that three existing processes could not perform biological phosphorus removal when the average influent was fed at any operation temperatures. However, the Parallel BNR process was found that biological phosphorus removal could be performed when both design and average influent were fed at any operation temperatures. This process showed the T-N concentration in effluent had a maximum value of 15mg/L when design influent was fed at $13^{\circ}C$ and a minimum value of 14mg/L when average influent was fed at $20^{\circ}C$. Also, T-P concentrations had a maximum value of 1.3mg/L when average influent was fed at $20^{\circ}C$ and a minimum value of 1.1mg/L when design influent was fed at $13^{\circ}C$. Based on these results, we found that this process can remove nitrogen and phosphorus biologically under any operational conditions.

• Journal of Korean Society on Water Environment
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• v.24 no.6
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• pp.741-749
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• 2008

Many small-scale ponds that serve as ecological habitat, recreation and irrigation are faced to eutrophication problem, which causes aesthetic nuisance and ultimately loss of their functions. Thus accurate evaluation of the trophic state of these ponds is essential to provide rational information to the stakeholders so that they can develop effective management actions. In this study, the trophic state of a small pond (Wonheung) that experiencing water quality degradation due to vicinity land development was assessed using various Trophic State Indexes (TSIs) and statistical analysis including Principal Components Analysis (PCA) based on the field monitoring data obtained from May to December, 2007. The results showed that the pond is under eutrophic state with average total nitrogen (T-N) and total phosphorus (T-P) concentrations of $708.1{\mu}g/L$ and $59.3{\mu}g/L$, respectively. The factor loading plot obtained from PCA showed distinct two influencing factors, PC 1 and PC 2. PC 1 was grouped by T-P, Chlorophyll a (Chl-a), suspended solids (SS), TN/TP ratio, and transparency that all strongly related to the eutrophication state, while PC 2 by temperature, conductivity, dissolved oxygen (DO) and turbidity that explains the seasonal water quality variations. The limiting factor was identified as light rather than phosphorus by both T-N/T-P ratio and TSI indexes analysis. The results and methodology adopted in this study can be used for water quality assessment for other small ponds and lakes.

• Korean Journal of Ecology and Environment
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• v.41 no.spc
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• pp.35-41
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• 2008

Nutrient Enrichment Bioassays (NEBs) were conducted in the laboratory during June $22{\sim}28$, 2006 in order to determine primary limiting factor on the phytoplankton growth. For the NEBs, the water was sampled using a 10L polyethylene-lined container and dispensed into 2.5L container in the laboratory. The algal growths response in the control (C) and three treatments of phosphorus (P), 2-fold phosphorus (2P), and nitrate nitrogen $(NO_3-N)$ were monitored during 7 days. In the cubitainers which were spiked as P (T1) and 2P (T2) Chl-${\alpha}$ concentrations were decreased during the test period and the final concentrations was low than initial values. However, Chl-${\alpha}$ in the cubitainers which were spiked as $NO_3$(T3) and $P+NO_3$(T4) showed significant increases compared to the initial values, indicating that in the short-term experiments, nitrogen seemed to be a primary limiting nutrient during the periods of NEBs experiment. Long-term ambient nutrient data of TP and TN, and TN:TP mass ratios, however, showed a potential phosphorus limitation on phytoplankton growth and previous other researchers showed a variations of limiting nutrients by nitrogen or phosphorus depending on the seasons sampled and locations. In this study nitrogen as primary limiting nutrient in the NEBs seem to be an seasonal effect rather than the consistent nitrogen limitation.

• Journal of the Korean Society for Marine Environment & Energy
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• v.19 no.4
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• pp.274-285
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• 2016

In order to elucidate the spatiotemporal variations of marine environmental parameters, we collected seawater samples in the middle east coast of Korea in 2013-2014. A high temperature and low salinity were distinctively observed in the summer and a low temperature and high salinity pattern in the winter. The temperature of the bottom water was in the range of $2^{\circ}C$ to $7^{\circ}C$, with the temperature being relatively high in the winter, while the salinity was measured to be around 34, with no large differences across the seasons. The dissolved oxygen concentrations were in the range of $7mg\;L^{-1}$ to $12mg\;L^{-1}$, and it was relatively high in May compared to other seasons. The seawater temperature and dissolved oxygen concentration at the surface layer showed a significant negative correlation in the autumn and winter seasons, based on which it is seemed that water temperature is the main factor controlling the amount of dissolved oxygen in the autumn and winter seasons. The dissolved inorganic nitrogen (DIN) and silicate (DSi) increased 11- and 7-fold, respectively, in the winter compared to the summer. The DIN to DIP (dissolved inorganic phosphorus) ratio for the surface seawater was approximately 16, but it was relatively low in the spring season. On the other hand, the DIN to DIP ratio was relatively high in the summer. Based on this, it is seemed that nitrogen and phosphorus were the growth-limiting nutrients for phytoplankton in the spring and summer, respectively. Water quality was I (excellent) ~III (medium) level at the most stations except for some stations (level IV) during the autumn season, having low dissolved oxygen saturations.

• Journal of Life Science
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• v.21 no.8
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• pp.1183-1189
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• 2011

The present study is aimed at examining the effects of the physico-chemical environmental factors of water systems on water bloom at Homin and Gagok reservoirs in Pungcheon-Myeon, Andong, Gyeongsangbuk-do. The mean water temperature and the contents of chlorophyll-a, total-nitrogen, total-phosphorus and phosphate-phosphorus were higher at the Gagok reservoir. On the other hand, the pH mean value was higher at the Homin reservoir. The mean value of microelements (Na, K, Mg, Fe, Si) was higher at the Gagok reservoir. The cyanobacteria which was considered to be the cause of water bloom at the two reservoirs was Microcystis aeruginosa. It started to grow in May and showed the highest standing crop in August. Between the increase of standing crop of M. aeruginosa and the water quality, correlation values of $Na^+$ (r=-0.910, p<0.05), $Fe^{2+}$ (r=-0.855, p<0.05) and $Si^{4+}$ (r=0.989, p<0.01) at the Homin reservoir increased amount of standing crop. Meanwhile, at the Gagok reservoir, the contents of $Na^+$ (r=-0.776, p<0.05), $Si^{4+}$ (r=0.899, p<0.05) were highly related to the increase of standing crop. Interestingly, Si, which is the limiting factor for diatoms, has a high correlation with standing crop of cyanobacteria. In conclusion, the water blooming is caused not by a simple factor but a synergistic effect due to complex actions including high concentrations of nitrogen and phosphorus ions and many other environmental factors.

• KSBB Journal
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• v.14 no.4
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• pp.503-510
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• 1999

In order to analyze nutritional factors affecting in situ bioremediation of diesel degradation and cell viability were studied by varying nutritional conditions. In column experiments packed with diesel-contaminated soil, nitrogen was found to be the major limiting nutrient. When nitrogen was added to soil at four different levels of C : N (100 : 5, 100 : 10, 100 : 15, and 100 : 20 mg N/kg dry soil), the greatest simulation of microbial activity occurred at the lowest, rather than the highest nitrogen addition. However, no significant effects was observed when phosphorus and air were added. No matter how the incubation mode varied, less than 50% of the diesel was remained after 7 days of treatment, presumably because the residual hydrocarbons were adsorbed on soil particles, adsorption

• Journal of Korean Society on Water Environment
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• v.24 no.3
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• pp.333-339
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• 2008

This study was carried out to assay the relationships between empirical factors and water quality in 23 agricultural reservoirs. Based on the trophic state index (TSI) deviation analysis, phosphorus in type II and III was the primary limiting factor on algal growth. BOD, COD, TP and chl.a concentration in type III reservoirs showed higher concentration than those of other types, while SS and TN concentration was no noticeable difference among three types. Characteristics of type III reservoirs showed large reservoir surface and drainage area, large surface area to volume (SAV) ratio, small drainage area to reservoir area (DA/RA) ratio, relatively old age, large paddy field and upland field to drainage area ratio (Mean 17.4%) and high generation and discharge loads compared to other types of reservoirs. In type I and II reservoirs, trends of BOD, TN, TP concentration in water column, were similar to those of the discharge load of pollutants. Although type II reservoirs generally showed low phosphorus discharge loads compared to type I reservoirs, TP and chl.a concentration in water column was greater than that of type I. Characteristics of type II reservoirs showed relatively large SAV ratio and old age compared to type I reservoirs and was similar to those of type III including eutrophic reservoirs.