• Title/Summary/Keyword: Phenol resin

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The Rheological Properties of Printing Ink and its printability with the Molecular Weight of Rosin Modified Phenol Resin (로진 변성 페놀 수지의 분자량 변화에 따른 인쇄 잉크의 유변학적 특성과 인쇄적성에 관한 연구)

  • Lee, Kyu-Il;Kim, Sung-Bin
    • Proceedings of the Korean Printing Society Conference
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    • 2007.11a
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    • pp.1-12
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    • 2007
  • The rheological properties of an ink relate to its performance on the press and to the printing quality. So it is necessary to analyze the relationship between printability and the rheological properties of ink. Transfer rate of ink is one of the important factor deciding print quality. And it is concerned with rheological properties of ink. Thus, in this study, according to the molecular weight of rosin modified phenolic resin the rheological properties of ink were measured by rotational rheometer and then transfer equation of ink, density and gloss were mesured in order to examine the printability of ink.

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Rheology of Emulsified Ink and Printability With Different Molecular Weights of Rosin Modified Phenol Resin (로진 변성 페놀 수지의 분자량 변화에 따른 유화 평형잉크의 유변학적 특성과 인쇄적성)

  • Lee, Kyu-Il;Kim, Tae-Hwan;Kim, Sung-Bin
    • Journal of the Korean Graphic Arts Communication Society
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    • v.26 no.1
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    • pp.1-16
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    • 2008
  • The rheological properties of emulsified ink must be maintained adequately at various shear rates or shear stress. So it is necessary to understand its rheological properties in order to regulate the printability of eumulsified ink on the performance. In this study, the rheological properities and printability of emulsified ink are investigated according to the molecular weights of rosin-modified phenolic resin.

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Deep UV Photoresists;Dissolution Inhibitor

  • Shim, Sang-Yeon;Crivello, James V.
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.3
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    • pp.188-191
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    • 2000
  • A new class of deep UV Photoresist based on the principles of chemical amplification was developed. This photoresist consists of three basic elements: a copolymer, blocked tetrabromobisphenol-A as a dissolution inhibitor and a photosensitive onium salt as a photoacid generator. On irradiation followed by a post exposure bake, tert-butoxycarbonyloxy phenyl group is converted to phenol group. Thus the initially base insoluble resin is converted under UV irradiation to a base soluble resin which may be preferentially removed by dissolution. This new photoresist display high sensitivity, 10 $mJ/cm^{2}$.

Investigation of the Effect of Organoclay Additives on Mechanical Properties of PF resin and MPB-OSL using Creep Behavior Analysis and IB Test

  • Kim, Yong-Sik;Kadla, John F.
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.5
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    • pp.381-389
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    • 2011
  • The effect of organoclays on the mechanical properties of cured phenol formaldehyde resin and oriented strand lumber made from Mountain Pine Beetle killed pine strands was analyzed. Three organoclays were used: a natural montmorillonite, hydrophobic organically modified 10 A, and hydrophilic organically modified 30 B. The oriented strand lumber samples were less creep deformation as well as improved internal bonding strength by adding organoclays in the order of 10 A 2% > MMT 2% > 30 B 2% > control. Furthermore, time-temperature superposition (TTS) analysis was proved to be able to predict the long-term creep behavior of MPB-OSL samples.

The Rheological Properties of Printing Ink and its printability with the Molecular Weight of Rosin Modified Phenol Resin (로진 변성 페놀 수지의 분자량 변화에 따른 인쇄 잉크의 유변학적 특성과 인쇄적성에 관한 연구)

  • Lee, Kyu-Il;Kim, Sung-Bin
    • Journal of the Korean Graphic Arts Communication Society
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    • v.25 no.2
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    • pp.1-13
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    • 2007
  • The rheological properties of an ink relate to its performance on the press and to the printing quality. So it is necessary to analyze the relationship between printability and the rheological properties of ink. Transfer rate of ink is one of the important factor deciding print quality. And it is concerned with rheological properties of ink. Thus, in this study, according to the molecular weight of rosin modified phenolic resin the rheological properties of ink were measured by rotational rheometer and then transfer equation of ink, density and gloss were measured in order to examine the printability of ink.

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Development of Phenolic SMC for The Rail (철도차량 및 지하철 불연 내장재 페놀 SMC 개발)

  • Kim Young-keun;Shin Dong-hyok;Kim Young-min;Park Joung-wuk;Min Jae-Jun
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.04a
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    • pp.55-58
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    • 2004
  • Phenolin resin, prepared form phenol and formaldehyde, is one of the oldest thermosetting resins available. Phenolic resins are cured via condensation polymerization with evolution of water, which in molding process is a big problem. The use of phenolic resins in glass fiber composites is growing, primarily due to their low flame spread, low smoke generation and low smoke toxicity properties. SMC of phenolics has been rearched since the 1986. The technology challenge was to match resin viscosity, handling and cure with those for the polyester SMC to avoid any special processing for fabricators and end users. Phenolic SMC was chosen because of the ease of molding to the required shape with light- weight, thin wall structure and with excellent fire protection.

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Flexural Modulus of Larch Boards Laminated by Adhesives with Reinforcing Material

  • Injeong LEE;Weontae OH
    • Journal of the Korean Wood Science and Technology
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    • v.51 no.1
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    • pp.14-22
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    • 2023
  • Economical use of larix (larch) boards (grade 3) in industries is lower than that of imported hardwood; thus, studies have been conducted toward performance improvement of larix boards. Herein, flexural modulus of larix board samples laminated with wood adhesives polyurethane resins, poly (vinyl acetate) resins, phenol-resorcinol-formaldehyde resins, melamine-formaldehyde resins, and urea-formaldehyde resins was compared with that of the samples bonded with adhesives reinforced with mesh-type basalt fibers. Moreover, the flexural moduli of the laminated samples bonded by mesh-type basalt fibers were compared with those of reinforced samples. The results showed that boards laminated with polyurethane and urea-formaldehyde resin adhesives had higher flexural modulus than those without the lamination. In particular, the increase in the flexural modulus was relatively significant for the 2- and 3-ply board structures laminated with polyurethane adhesives compared to those with reinforcement. The 3-ply board structure without reinforcement had the highest flexural modulus when the urea-formaldehyde resin adhesive was used.

Synthesis of Aminosilane treated Waterborne Poly Urethane/Epoxy Hybrid Resin used for Loudspeaker Damper (스피커 댐퍼용 아미노실란 처리 수분산 폴리우레탄/에폭시 하이브리드 수지의 합성)

  • Choi, Hyun-Seuk;Choi, Dong-Ho;Park, Ju-Yong;Huh, Man-Woo
    • Textile Coloration and Finishing
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    • v.29 no.1
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    • pp.25-36
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    • 2017
  • This study worked on the synthesis of waterborne polyurethane/epoxy hybrid resins containing aminosilane compound to replace conventional phenol resins used for a coating material for loudspeaker dampers, which are not harmful to human being. Waterborne polyurethane resins were synthesized from two diisocyanate of 4,4'-diphenylethane diisocyanate and toluene diisocyanate, two polyols of polyester polyols(PEP), polycarbonatediol(PCD), including and anionic center of dimethylol butanoic acid, a chain extenders of ethylenediamine(EDA), and a neutral agent of triethylamine. Synthesized polyurethane resins and commercially available bisphenol A type waterborne epoxy resin were blended in weight ratios of 80:20 to prepare polyurethane/epoxy hybrid resins. The synthesized waterborne polyurethane/epoxy hybrid resins were reacted with aminosilane compound to improve mechanical properties. Aminosilane-treated polyurethane /epoxy hybrid resins showed better mechanical properties.

Influence of Pyrolysis Conditions and Type of Resin on the Porosity of Activated Carbon Obtained From Phenolic Resins

  • Agarwal, Damyanti;Lal, Darshan;TripathiN, V.S.;Mathur, G.N.
    • Carbon letters
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    • v.4 no.2
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    • pp.57-63
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    • 2003
  • In polymer precursor based activated carbon, the structure of starting material is likely to have profound effect on the surface properties of end product. To investigate this aspect phenolic resins of different types were prepared using phenol, mcresol and formaldehyde as reactants and $Et_3N$ and $NH_4OH$ as catalyst. Out of these resins two resol resins PFR1 and CFR1 (prepared in excess of formaldehyde using $Et_3N$ as catalyst in the basic pH range) were used as raw materials for the preparation of activated carbons by both chemical and physical activation methods. In chemical activation process both the resins gave activated carbons with high surface areas i.e. 2384 and 2895 $m^2/g$, but pore size distribution in PFR1 resin calculated from Horvath-Kawazoe method, contributes mainly in micropore range i.e. 84.1~88.7 volume percent of pores was covered by micropores. Whereas CFR1 resin when activated with KOH for 2h time, a considerable amount (32.8%) of mesopores was introduced in activated carbon prepared. Physical activation with $CO_2$ leads to the formation of activated carbon with a wide range of surface area (503~1119 $m^2/g$) with both of these resins. The maximum pore volume percentage was obtained in 3-20 ${\AA}$ region by physical activation method.

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The Effects of the Tempered Materials on the Thermal Runaway Characteristics in the Resol Resin Synthesis Reaction (레졸수지 합성반응에서 온도조절 물질이 열폭주 특성에 미치는 영향)

  • Lee, Jung-Suk;Lee, Keun-Won
    • Journal of the Korean Institute of Gas
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    • v.18 no.4
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    • pp.27-34
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    • 2014
  • In this study, we evaluated an effect of the tempered materials on the thermal runaway characteristics in the resol resin synthesis reaction using the adiabatic calorimetry of vent sizing package 2(VSP2). The kinetic parameters, such as an activation energy and heat of reaction, were estimated using the test results. As the results, the instantaneous characteristics to express the intensity of runaway reaction decreased at the low solid content. However, the sudden loss of the tempered materials triggered the second runaway reaction rapidly. In this condition, the heat of reaction and the activation energy of phenol and p-formaldehyde were about 157 kJ/mol and 60 kJ/mol, respectively.