• 대한기계학회논문집A
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• 제24권1호
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• pp.1-6
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• 2000

As dies and molds have become more and more complicated in the recent years, the demand for lower cost and shorter production time is also growing stronger. Rapid prototyping and Tooling technologies are expected to be used for more rapid and lower cost tool fabrication. However the rapid tooling methods have not yet reached the level of application to the manufacturing of metallic dies and molds which require high dimensional accuracy. As the rapid tooling technology, there are the slurry casting, the powder casting, the direct laser sintering, and so on. Generally, in the slurry casting, the alumina powder and the water soluble phenol were mainly used. However, the mechanical properties of the phenol were not good enough to apply to molds directly. In this study, pure epoxy and two types of aluminium powder reinforced resin are applied to the slurry casting. The mechanical and thermal properties are better than phenol because the epoxy is the thermosetting resin. And mechanical characteristics such as shrinkage rate, hardness, surface roughness are measured for the sake of comparison. Metal powder reinforced resin molds are better than the resin tool form the viewpoint of shrinkage rate and hardness. Finally, it has been shown that the application possibility of this process is high, because the manufacturing time and cost savings are significant.

• Journal of the Korean Wood Science and Technology
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• 제44권6호
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• pp.842-851
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• 2016

The objective of this study was to improve physical and mechanical properties of soft-inner part of oil palm trunk (S-OPT) after impregnation with phenol formaldehyde (PF) resin and densification by close system compression (CSC) method. Effect of different methods of PF resin impregnation (i.e., no vacuum-pressure, vacuum, and vacuum-pressure) was evaluated. The results showed that PF resin impregnation and CSC significantly improved the physical and mechanical properties of S-OPT up to: (1) 176% in density; (2) 309% in modulus of rupture (MOR); (3) 287% modulus of elasticity (MOE); and (4) 191% in the compressive strength. Physical and mechanical properties of S-OPT showed their best performances when PF resin impregnated with vacuum-pressure method as shown by higher weight gain, density, MOR, MOE, compressive strength, and lower recovery of set due to better penetration of PF resin into S-OPT. Combining PF resin impregnation and densification by CSC method could be a good method to improve physical and mechanical properties of S-OPT.

• 한국세라믹학회지
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• 제48권2호
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• pp.141-146
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• 2011

Successful coating of high quality glassy carbon is introduced by applying high pressure during the curing process of dip-coated phenol resin on graphite. The dependence of the applied pressure on the quality of the glassy carbon layer has not been reported so far. Pressure was changed from 0 to 400 psi during curing at $200^{\circ}C$. After carbonized at $1100^{\circ}C$ in inert atmosphere for the 400 psicured sample, as a promising result, a thick (~ 3 mm) and smooth glassy carbon layer could be obtained without any breakage, and the yield of carbonization was remarkably increased. It is believed that the cross-linking of resins results in decreasing volatile contents and, thus, increasing the yield of the glassy carbon. The origin of the improvement is discussed on the basis of several analytical results including FE-SEM, FT-IT and Raman spectrum.

• 한국정밀공학회지
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• 제15권8호
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• pp.39-45
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• 1998

In the previous study. the powder casting was attempted as the rapid tooling. The powder casting was the process to cast dry powder into the casting mold transferred from R/P model and infiltrate the liquid binder to solidify the powder. And then, the melted copper was infiltrated to control the shrinkage rate of the final mold Conseqently, the shrinkage rate was under 0.1% through that process. The mechanical characteristic was also excellent. Generally, in the slurry casting, the alumina powder and the water soluble phenol were mainly used. However, the mechanical property of the phenol was not good enough to apply to molds directly. In this study, aluminium powder filled with epoxy is applicated to the slurry casting to solve these problems. The mechanical and thermal properties are better than phenol because the epoxy is the thermosetting resin. We achieved a successful result that the shrinkage rate is shortened about 0.047%. Futhermore, the manufacturing time and cost savings are significant. Finally, we assume that the developing possibility of this process is very optimistic.

• Journal of the Korean Wood Science and Technology
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• 제26권3호
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• pp.48-52
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• 1998

Residues such as walnut, pinenut and peanut shells were used as a filler in adhesive for bonding radiata pine plywood. The nutshell residues were prepared by simply drying to 8% moisture content and grinding the dry material using a laboratory Wiley mill with a $75{\mu}m$ (200 mesh) screen. The nutshells residues were compared to a commercial filler commonly used in adhesives by the structural plywood and laminated veneer lumber industry in the United States. The adhesive mixes were made by following the recommended procedure of Georgia-Pacific Resins, Inc., using phenol-formaldehyde resin. For each filler type, three-ply plywoods, 6 mm nominal thickness and 30 by 30 cm in size, were fabricated at two press times (4 and 5 min) and around 30 minute assembly time. Evaluations of the nutshell residues were carried out by tension shear tests after cyclic boil tests on plywood. The results of the performance test included tension shear strength and wood failure. All plywoods made with the nutshell fillers were comparable to those made with the control filler. These results indicate that nutshell residues would be suitable as filler for plywood adhesives.

• 한국세라믹학회지
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• 제45권4호
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• pp.196-203
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• 2008

Metal-carbon/$TiO_2$ composite photocatalysts were thermally synthesized through the mixing of anatase to metal(Cu, Zn) containing phenol resin in an ethanol solvent coagulation method. The BET surface area increases, with the increase depending on the amount of metal salt used. From SEM images, metal components and carbon derived from phenol resin that contains metal was homogeneously distributed to composite particles with porosity. XRD patterns revealed that metal and titanium dioxide phase can be identified for metal-carbon/$TiO_2$ composites, however, the diffraction peaks of carbon were not observed due to the low carbon content on the $TiO_2$ surfaces and due to the low crystallinity of the amorphous carbon. The results of a chemical elemental analysis of the metal-carbon/$TiO_2$ composites showed that most of the spectra for these samples gave stronger peaks for C, O, treated metal components and Ti metal compared to that of any other elements. According to photocatalytic results, the MB degradation can be attributed to the three types of synergetic effect: photocatalysis, adsorptivity and electron transfer, according to the light absorption between the supporter $TiO_2$, metal species, and carbon layers.

• Advances in materials Research
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• 제3권1호
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• pp.259-269
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• 2014

The boron-nitrogen-containing phenol-formaldehyde resin (BNPFR)/$SiO_2$ nanocomposites (BNPFR/$SiO_2$) were synthesized in-situ, and structure of BNPFR/$SiO_2$ nanocomposites was characterized by FTIR, XRD and TEM. The loss modulus peak temperature $T_p$ of BNPFR/$SiO_2$ nanocomposites cured with different nano-$SiO_2$ content are determined by torsional braid analysis (TBA). The thermal degradation kinetics was investigated by thermogravimetric analysis (TGA). The results show that nano-$SiO_2$ particulate with about 50 nm diameter has a more uniformly distribution in the samples. The loss modulus peak temperature $T_p$ of BNPFR/$SiO_2$ nanocomposite is $214^{\circ}C$ when nano-$SiO_2$ content is 6 wt%. The start thermal degradation temperature $T_{di}$ is higher about $30^{\circ}C$ than pure BNPFR. The residual rate (%) of nanocomposites at $800^{\circ}C$ is above 40 % when nano-$SiO_2$ content is 9 %. The thermal degradation process is multistage decomposition and following first order.

• 대한화학회지
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• 제39권5호
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• pp.379-383
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• 1995

Amberlite IRC-718 킬레이트 수지에서의 주석(II)이온의 PSA(phenol sulfonic acid) 리간드에 의한 용리현상을 연구하였다. 0.10 M $Sn^{2+}$ 용액 일정량을 흡착시키고 시료를 녹인 여러 가지 농도의 PSA 용리액으로 용리하면 $Sn^{2+}$이 두 개의 봉우리로 용리되고, 이 두 개의 봉우리 면적은 PSA의 농도에 따라 변한다. 이를 이용하여 $Sn^{2+}$와 PSA간의 착물의 안정도상수를 계산하였다. 그 값은 $2.0{\times}10^{-1}$이었다.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2004년도 추계학술발표대회 논문집
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• pp.96-99
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• 2004

Silica fillers were coated by plasma polymer coatings of 1,3-diaminopropane, allylamine, pyrrole, 1,2-epoxy-5-hexene, allyl mercaptan and allyl alcohol using RF plasma (13.56 MHz). The coated fillers were then mixed with biphenyl epoxy, phenol novolac (curing agent) and/or triphenylphosphine (catalyst), and subjected to DSC analyses in order to elucidate the chemical reaction between functional moieties in the plasma polymer coatings and the epoxy resin. Only the samples with 1,3-diaminopropane and allylamine plasma polymer coated silica fillers showed heat of reaction peaks when they were mixed with biphenyl epoxy resin only, while these samples as well as the samples with 1,3-diaminopropane, allylamine and pyrrole plasma polymer coated silica fillers exhibited heat of reaction peaks when mixed with both biphenyl epoxy and phenol novolac (curing agent).

• 한국안전학회지
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• 제12권1호
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• pp.71-76
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• 1997

In this paper, it was described results of study on curing safety of molding meterial, about the variation of phenol resin contents, wood flour contents and moisture of wood flour, under the same condition. The experimental results are summarized as follows ; 1) When the curing temperature was high, the curing time was short in the case of 4～8wt% moisture of wood flour, but in the case of more than l2wt% moisture of wood flour, the curing time was long. 2) The curing time for curing temperature was more short when 6wt% moisture of wood flour than 4wt% moisture of wood flour. 3) The more wood flour content and moisture of wood flour content, the longer curing time and the more mineral filler content, the shorter curing time. 4) When the phenol resin content of main matrix increase, the curing time was short.