• 제목/요약/키워드: Phases change

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BSCCO:2212-2223 박막의 엔탈피와 엔트로피 변화 (Transformation of the enthalpy and the entropy in BSCCO:2212-2223)

  • 천민우;박노봉;박용필
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.589-590
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    • 2005
  • BSCCO:2212-2223 thin films were fabricated by using the ion beam sputter with a evaporation method at various substrate temperatures, $T_{sub}$, and ozone gas pressures, $pO_3$. The correlation diagrams of the BSCCO phases with Tsub and $pO_3$ are established in the 2212 and 2223 compositional films. In spite of 2212 compositional sputtering, Bi2201 and Bi2223 as well as Bi2212 phases come out as stable phases depending on Tsub and $pO_3$. From these results, the thermodynamic evaluation of ${\Delta}H$ and ${\Delta}S$, which are related with Gibbs' free energy change for single Bi2212 or Bi2223 phase, was performed.

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방사선조사가 당뇨 백서의 치주조직에 미치는 영향 (Effect of irradiation on the periodontal tissues in streptozotocin-induced diabetic rats)

  • 박동신;황의환;이상래
    • Imaging Science in Dentistry
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    • 제35권3호
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    • pp.133-139
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    • 2005
  • Purpose To observe the histopathological changes in the periodontal tissues of mandibular molars in streptozotocin-induced diabetic rats after irradiation. Materials and Methods : The male Sprague-Dawley rats weighing approximately 250 gm were divided into four groups: control, diabetes, irradiation, and diabetes- irradiation groups. Diabetes mellitus was induced in the rats by injecting streptozotocin. Rats in the control and irradiation groups were injected with citrate buffer only After 5days, the head and neck region of the rats in irradiation and diabetes-irradiation groups were irradiated with a single absorbed dose of 10Gy. All the rats were sacrificed at 3, 7, 14, 21, and 28 days after irradiation. The specimen including the mandibular molars were sectioned and observed using a histopathological method. Results In the diabetes group, osteoclastic activity was observed in the alveolar bone and the root throughout the period of experiment. Also, osteoblastic and fibroblastic activities were markedly decreased. In the irradiation group, the osteoclasts were observed in the alveolar bone and the dilated capillaries were increased in the early experimental phases. However, vigorous osteoblastic activity was noted in the late experimental phases. In the diabetes-irradiation group, osteoblastic activity in the alveolar bone and the root was observed in the early experimental phases. However, there were no resorption and osteoblastic activity in the alveolar bone and the root in the late experimental phases, and obvious atrophic change of fibrous tissues was noted. Conclusion : This experiment suggests that osteoblastic activity was caused by irradiation in the late experimental phases, but atrophic change of the periodontal ligament tissues was induced after irradiation in diabetic state.

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Coexistence of quasi-1D ($7{\times}7$) and ($5{\times}5$) phases on vicinal Si(557) surfaces

  • Kim, Min-Kook;Oh, Dong-Hwa;Baik, Jae-Yoon;Jeon, Cheol-Ho;Park, Chong-Yun;Ahn, Joung-Real
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.361-361
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    • 2010
  • The separated quasi-one-dimensional ($7{\times}7$) and ($5{\times}5$) phases on vicinal Si(557) surfaces were successfully realized by changing the crystallographic orientation and thermal treatment conditions. A small change in the crystallographic orientation of the Si(557) surface stabilized the quasi-one-dimensional ($5{\times}5$) phase of a (111) facet on vicinal Si(557) surfaces and made it coexist with a quasi-one-dimensional ($7{\times}7$) phase after an optimal thermal treatment, whereas only the quasi-one-dimensional ($7{\times}7$) phase was stable on the Si(557) surface. Interestingly, this causes the (111) terraces with different widths (L) to prefer only one of the $5{\times}5$ (L=12) and $7{\times}7$ (L=9) phases resulting in long-range order of both phases along the step edge direction, which was observed by scanning tunneling microscopy (STM) and was supported by first principle calculations. In contrast, the quasi-one-dimensional ($5{\times}5$ and ($7{\times}7$) phases were arranged randomly across the step edge direction. The change of surface morphology of vicinal Si(557) surfaces will be discussed with STM images and theoretical calculations by changing crystallographic cutting angles and thermal treatment conditions.

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소집단 역할놀이와 토의를 통한 고등학생들의 천문개념 이해 (High School Students' Understanding of Astronomical Concepts Using the Role-playing and Discussion in Small Groups)

  • 정남식;우종옥;정진우
    • 한국과학교육학회지
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    • 제16권1호
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    • pp.61-76
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    • 1996
  • The purpose of this study was to apply the instructional strategies for conceptual change prescribed by Posner et al(1982) to the astronomic content domain taught in the elementary and middle school and to analyze the characteristics of students' knowledge revealed in the test before, during and after the instruction. Also, it was to investigate the intercorrelation of cognitive levels, spatial ability and science achievement. The major findings of this study are as follows: 1. Students had a great variety of misconceptions related to the motion of the moon before the instruction, that is, the phases, the names of phases and the cause of changing phases by the moon's orbit about the earth, the moon's appearance and location at the given time, the relative positions of earth, moon and sun during a lunar eclipse, the cause that a full moon is not at the line of node once a month. In the analysis of students' responses concerning the cause of changing phases of the moon and a lunar eclipse, the results indicate that the great majority of students had rote learning rather than meaningful learning in the middle school. 2. Students' reponses during the instruction concerning the changing phases of the moon and the predictive knowledge about the motions of the earth and the moon were analyzed. 1) According to the results of the test given before and after experiment, after discussion, achievement score of the whole of subjects and groups in both preformal and formal cognitive levels appeared to increase linearly. 2) There was no statistically significant differences of achievement scores before and after experiment, after discussion between preformal group and formal group in cognitive levels. 3. Distribution of achievement scores according to the whole of subjects and groups in preformal and formal cognitive levels shows that there was a statistically significant difference between pretest and posttest. 4. Types of conceptual changes concerning the cause of changing phases of the moon that occurred from pretest to posttest were classified as accommodation, incomplete accommodation, assimilation, no change and no model. Six of the seven students starting instruction with alternative frameworks didn't sustain those alternative models throughout instruction. Five of these six students accommodated completely and the last one partially. Seventy-nine percentage of students taking instruction with fragmental models assimilated correct propositions at the end of the instruction. These results suggest that conceptual change model prescribed by Posner et al(1982) has promised the meaningful learning to students taking with fragmental models, especially in cases where students with misconception enter instruction. 5. High correlation between achievement score of simple-recall items and that of written items in pretest and posttest indicates that the higher students got the score in simple-recall items the better they also performed in written items. However, there was no statistically significant differences among cognitive levels, spatial ability and science achievement in the whole of subjects and groups according to the cognitive levels.

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우리나라 식물계절 시기의 변화 경향에 관한 연구 (A Study on Plant Phenological Trends in South Korea)

  • 이경미;권원태;이승호
    • 한국지역지리학회지
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    • 제15권3호
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    • pp.337-350
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    • 2009
  • 식물계절 시기의 변화는 지역의 기후변화를 파악하는 데 중요한 지표이며, 지구온난화로 인한 기온상승의 영향이 뚜렷하게 반영된다. 본 연구에서는 식물계절 관측 자료를 이용하여 식물계절 시기의 변화 경향 및 식물계절 시기의 변화와 기온변화의 관계를 분석하였다. 봄철의 발아와 개화시기는 -0.7${\sim}$-2.7일/10년의 변화율로 앞당겨지는 경향인 반면 가을철 단풍절정시기는 3.7${\sim}$4.2일/10년의 변화율로 늦어지는 추세이다. 한반도의 봄철 식물계절 시기는 2월에서 3월 평균기온과 높은 상관관계가 있으며, 2월에서 3월 동안의 평균기온이 $1^{\circ}C$ 상승함에 따라 봄철 식물계절은 3.8일씩 앞당겨지는 경향이다. 가을철 식물계절 시기는 10월 평균기온과 상관관계가 높고 10월 평균기온이 $1^{\circ}C$ 상승함에 따라 3.1일씩 늦어지는 추세이다.

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고 망간강 2상 혼합조직의 열적 안정성에 관한 연구 (A Study on the Thermal Stability of Duplex High Mn-Steel Structure)

  • 위명용
    • 열처리공학회지
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    • 제5권1호
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    • pp.13-22
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    • 1992
  • The thermal stability of duplex high Mn-steel structure have been investigated using 15%Mn~1.0~2.4%C steels which are composed of ${\gamma}$-and ${\theta}$-phases in the range of temperature from 900 to $1100^{\circ}C$, and time from 50 to 300h. The results are as follows ; 1) The grain growth in single-phase region proceeds by grain boundary migration and the relation between mean radius $\bar{r}$ and annealing time t is described as follows ; $\bar{r}^2-{\bar{r}_0}^2=k_0{\cdot}t$ 2) The grain growth of duplex, (${\gamma}+{\theta}$), strucrure is slower than that single phase because the chemical composition of ${\gamma}$-and ${\theta}$-phases differs esch others. 3) The grain of (${\gamma}+{\theta}$) duplex structure grow slowly in a mode of Ostwald ripening. Because grain boundaries of ${\gamma}$-phase migrate under a restriction of pinning by ${\theta}$-phases. 4) In the duplex structures. the dispersed structures change to the dual-structures, as the volume fraction of the dispersed second-phase increase. Consequently, the growth-law, which is controlled by boundary-diffusion change to that of the volume diffusion-mechanism.

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시공(時空)과 음양오행(陰陽五行) -한의학의 사고체계- (Space-time and The theory of Eumyang-ohaeng -way of thinking in the standpoint of Oriental Medicine-)

  • 백상룡
    • 한국한의학연구원논문집
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    • 제9권2호
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    • pp.17-27
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    • 2003
  • Eumyang-ohaeng[陰陽五行-Eumyang and five phases], as a standing rule that establishes the theory of Oriental medicine and origin of the oriental philosophy, it provides the perspective of the oriental medicine's outlook of the world. Without knowing the Eumyang-ohaeng, we cannot discuss Oriental medicine, nor can we understand the oriental way of thinking. Time and Space is what the human being created in order to explain the existence and change of matters. There is a common denominator between this universal concept of time and space and the theory of Eumyang-ohaeng. Consequently this paper investigates how characteristics of Eumyang-ohaeng and that of time and space matches Eumyang represents all matter and its characteristic, by comparison with each other space, and Ohaeng shows the change of matter with time gradually and sequancely. But this separation is only a separation by words, they really melt into one like two sides of a coin is actually just one coin. After all the theory of Eumyang-ohaeng is a theory that leads us to realize time and space, matter and power are all just one. So consequently, despite the difference in mass or size or longevity of matters, Eumyang-ohaeng pulls all matter into one body. It's why Eumyang-ohaeng is defined as the unified theory of time and space.

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Partisil/Partisphere 이온 교환 컬럼 재생 가이드 (Column regeneration for Partisil/Partisphere ion-exchange columns)

  • Mark Fever;Gemma Howse
    • FOCUS: LIFE SCIENCE
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    • 제1호
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    • pp.5.1-5.3
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    • 2024
  • The document discusses the regeneration of Partisil/Partisphere ion-exchange columns in chromatography. It mentions that column efficiency can diminish with use due to the accumulation of sample and/or mobile phase impurities at the head of the column. This can lead to a change in back pressure, lower column efficiency, and sometimes a change in selectivity. The document outlines a procedure that may restore column performance. The document also provides everyday practices to enhance the lifetime of a column. These include using only high-purity HPLC solvents and buffers, using freshly prepared mobile phases and buffers, filtering mobile phases to remove particulates, using appropriate sample clean-up procedures, using a guard column or pre-column filter, and working within the pressure and flow rate limitations of the column. For the regeneration of Partisil/Partisphere SAX, SCX, WAX, and WCX columns, the document suggests passing 20 column volumes of various mobile phases through the column. These include a buffer wash, distilled water, an acid wash, a chelating wash, a methanol wash, and a buffer for separation. The document emphasizes that not all of these wash steps are required for every column clean-up and that some chromatographers require only a combination of certain steps.

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슈퍼 2상 스테인리스강에서 χ와 σ상의 석출거동에 미치는 W치환의 영향 (Effect of W Substitution on the Precipitation Behavior of χ and σ Phase in Super Duplex Stainless Steels)

  • 한현성;김성휘;강창룡
    • 한국재료학회지
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    • 제26권4호
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    • pp.200-206
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    • 2016
  • This study was carried out to investigate the effect of W substitution on the precipitation behavior of ${\chi}$ and ${\sigma}$ phases in super duplex stainless steel. The ${\chi}$ phase was precipitated at the interface of ferrite / austenite phases and inside the ferrite phase at the initial stage of aging. With an increase in the aging time, the volume fraction of the ${\chi}$ phase increased, and then decreased with the transformation from the ${\chi}$ phase to the ${\sigma}$ phase. The ${\sigma}$ phase was precipitated later than the ${\chi}$ phase, and the volume fraction of x phase increased with the increase in the aging time. The ferrite phase was decomposed into the new austenite (${\gamma}2$) and ${\sigma}$ phases by aging treatment. The decomposition of the ferrite phase into the ${\gamma}2$ and ${\sigma}$ phases was retarded by W substitution for Mo. The volume fraction of the ${\chi}$ phase increased and that of the ${\sigma}$ phase decreased due to W substitution. The ${\chi}$ and ${\sigma}$ phases were intermetallic compounds, which had lower nickel concentration, and higher chromium, molybdenum, and tungsten concentrations. The ${\chi}$ phase has higher molybdenum and tungsten concentrations than those of the ${\sigma}$ phase. The amounts of chromium and nickel in the ${\chi}$ and ${\sigma}$ phases did not change, but these phases have higher concentrations of molybdenum and tungsten due to W substitution for Mo.

Image Capturing of Dispersed Phases in DCHXs by Electric Tomography

  • Chun, Won-Gee;Kim, Min-Chan;Lee, Heon-Ju;Kang, Yong-Heack;Kwon, Hyok-Bo
    • 한국태양에너지학회 논문집
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    • 제21권2호
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    • pp.69-78
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    • 2001
  • This paper introduces the physical phenomena involved in Direct Contact Heat Exchangers (DCHXs) and also investigates the possibility of applying of EIT(Electrical Impedance Tomography) technique for capturing the images of dispersed phases as they stream through a stagnant body of water. A number of cases are studied where two dimensional cross-sectional static images are given for fictitious and actual masses present in a column of water(saline solution). In most direct contact liquid-liquid heat exchangers, oil or hydrocarbon with a density different(lighter or heavier) from water is normally used as dispersed working fluid. The main difficulty that arises with this arrangement lies in the elucidation of complicated flow field where the dispersed phase fluid tends to change its shape and size constantly during its journey through the other phase(water). This paper presents a number of results with different types of dispersed phases that are immiscible with water. The EIT technique has been employed in this context to test its applicability in capturing the dynamic images of dispersed phases. It shows static images of dispersed phases where dynamic images could be obtained by simply extending the algorithms and strategies employed in the present analysis.

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