• The Korean Journal of Pesticide Science
• /
• v.14 no.1
• /
• pp.37-48
• /
• 2010

The diacylhydrazine insecticides, methoxyfenozide, chromafenozide and tebufenozide are new-generation insecticides. These insecticides induce premature molting and cause the death of insects by mimicking their hormone. Also, these insecticides have already been widely used for vegetables planting in worldwide. Highperformance liquid chromatography (HPLC) is the most widely used procedure for determination of each compound residues in crops. However, simultaneous analysis method of these diacylhydrazine insecticides was not reported. The purpose of this study is to develop a simultaneous determination procedure of methoxyfenozide, chromafenozide and tebufenozide residue in crops using HPLC-UVD/MS method. These insecticide residues were extracted with acetone from representative samples of five raw products which comprised hulled rice, soybean, apple, pepper, and Chinese cabbage. The extract was diluted with saline water, and dichloromethane partition was followed to recover these insecticides from the aqueous phase. Florisil column chromatography was additionally employed for final cleanup of the extracts. The analytes were quantitated by HPLCUVD/MS, using a $C_{18}$ column. The crops were fortified with each insecticide at two levels per crop. Mean recoveries ranged from 89.0 to 104.8% in five representative agricultural commodities. The coefficients of variation were less than 3.9%. Quantitative limits of methoxyfenozide, chromafenozide and tebufenozide were 0.04 mg/kg in crop samples. A HPLC-UVD/MS with selected-ion monitoring was also provided to confirm the suspected residues. The proposed simultaneous analysis method was reproducible and sensitive enough to determine the residues of methoxyfenozide, chromafenozide and tebufenozide in agricultural commodities.

• Journal of the korean society of oceanography
• /
• v.37 no.3
• /
• pp.91-107
• /
• 2002

The wintertime upwind flow in the Yellow Sea has been investigated through a series of two-dimensional numerical experiments in an idealized basin. A total of 10 experiments have been carried out to examine the effects of wind forcing, bottom friction and the presence of oceanic currents sweeping the shelf of the East China Sea. A spatially uniform steady and periodic wind stresses are considered along with comparison of linear and quadratic formulations. The wind-driven flow in the absence of oceanic current has been computed using Proudman open boundary condition (POBC), while the wind-driven current in the presence of oceanic current has been computed using Flather’s radiation condition (FOBC). The oceanic currents to be prescribed at the open boundary have been simulated by specifying uniform sea level gradients across the Taiwan Strait and the eastern ECS shelf, Calculations show that, as seen in Lee et al. (2000), oceanic flow little penetrates into the Yellow Sea in the absence of wind forcing unless a unrealistically low rate of bottom frictional dissipation is assumed. Both steady and time-periodic wind stresses invoke the upwind flow along the central trough of the Yellow Sea, independently of the presence of the oceanic current. The presence of oceanic currents very marginally alters the north-south gradient of the sea surface elevation in the Yellow Sea. Changes in the intensity and direction of the wind-induced mean upwind flow are hardly noticeable in the Yellow Sea but are found to be significant near Cheju Island where the gradient is reduced and therewith contribution of Ekman transport increases. In case of steady wind forcing circulation patterns such as two gyres on the slope sides, a cyclonic gyre on the western slope and an anticyclonic gyre on the eastern slope persist and the upwind flow composes part of the cyclonic gyre in the Yellow Sea. While in case of the time-periodic wind stress the appearance and disappearance of the patterns are repeated according to the time variation of the wind stress and the upwind flow accordingly varies with phase delay, mostly intensifying near the time when the wind forcing is approximately near the middle of the decaying stage.

• Journal of the Korean Vacuum Society
• /
• v.9 no.4
• /
• pp.353-359
• /
• 2000

$(Bi_{0.15}Sb_{0.85})_2Te_3$ and $(Bi_{1-x}Sb_x)_2Te_3$ thermoelectric thin films were prepared by magnetron sputtering process, and their thermoelectric characteristics were investigated with variation of the sputtering condition and the $Sb_2Te_3$ content. The $(Bi_{0.15}Sb_{0.85})_2Te_3$ film, deposited by DC sputtering at $300^{\circ}C$ with rotating the Corning glass substrate at 10 rpm, was fully crystallized to $(Bi,Sb)_2Te_3$ phase with c-axis preferred orientation. This $(Bi_{0.15}Sb_{0.85})_2Te_3$ film exhibited the Seebeck coefficient of 185 $\mu$V/K which was higher than the values of other $(Bi_{0.15}Sb_{0.85})_2Te_3$ films fabricated with different sputtering conditions. With increasing the $Sb_2Te_3$ content, the Seebeck coefficient and electrical resistivity of p-type $(Bi_{1-x}Sb_x)_2Te_3$ (0.77$\leq$x$\leq$1.0) film were lowered. Among p-type $(Bi_{1-x}Sb_x)_2Te_3$ films, a maximum power factor of $0.79{\times}10^{-3}W/K^2-m$ was obtained at (Bi_{0.05}Sb_{0.95})_2Te_3$ composition..

• Korean Journal of Environmental Agriculture
• /
• v.39 no.3
• /
• pp.246-252
• /
• 2020

BACKGROUND: Pesticides are broadly used to control weeds and pests, and the residues remaining in crops are managed in accordance with the MRLs (maximum residue limits). Therefore, an analytical method is required to quantify the residues, and we conducted a series of analyses to select and validate the quick and simple analytical method for tolpyralate in five agricultural products using QuEChERS (quick, easy, cheap, effective, rugged and safe) method and LC-MS/MS (liquid chromatography-tandem mass spectrometry). METHODS AND RESULTS: The agricultural samples were extracted with acetonitrile followed by addition of anhydrous magnesium sulfate, sodium chloride, disodium hydrogencitrate sesquihydrate and trisodium citrate dihydrate. After shaking and centrifugation, purification was performed with d-SPE (dispersive-solid phase extraction) sorbents. To validate the optimized method, its selectivity, linearity, LOD (limit of detection), LOQ (limit of quantitation), accuracy, repeatability, and reproducibility from the inter-laboratory analyses were considered. LOQ of the analytical method was 0.01 mg/kg at five agricultural products and the linearity of matrix-matched calibration were good at seven concentration levels, from 0.0025 to 0.25 mg/L (R²≥0.9980). Mean recoveries at three spiking levels (n=5) were in the range of 85.2~112.4% with associated relative standard deviation values less than 6.2%, and the coefficient of variation between the two laboratories was also below 13%. All optimized results were validated according to the criteria ranges requested in the Codex Alimentarius Commission (CAC) and Ministry of Food and Drug Safety (MFDS) guidelines. CONCLUSION: In conclusion, we suggest that the selected and validated method could serve as a basic data for detecting tolpyralate residue in imported and domestic agricultural products.

• Korean Journal of Applied Biomechanics
• /
• v.26 no.1
• /
• pp.21-30
• /
• 2016

Objective: This study aimed to examine the characteristics of joint kinematics and synchronicity of rowing motion between elite and non-elite rowers. Methods: Two elite and two non-elite rowers performed rowing strokes (3 trials, 20 strokes in each trial) at three different stroke rates (20, 30, 40 stroke/min) on two stationary rowing ergometers. The rowing motions of the rowers were captured using a 3-dimensional motion analysis system (8-infrared camera VICON system, Oxford, UK). The range of motion (RoM) of the knee, hip, and elbow joints on the sagittal plane, the lead time ($T_{Lead}$) and the drive time $T_{Drive}$) for each joint, and the elapsed time for the knee joint to maintain a fully extended position ($T_{Knee}$) during the stroke were analyzed and compared between elite and non-elite rowers. Synchronicity of the rowing motion within and between groups was examined using coefficients of variation (CV) of the $T_{Drive}$ for each joint. Results: Regardless of the stroke rate, the RoM of all joints were greater for the elite than for non-elite rowers, except for the RoMs of the knee joint at 30 stroke/min and the elbow joint at 40 stroke/min (p < .05). Although the $T_{Lead}$ at all stroke rates were the same between the groups, the $T_{Drive}$ for each joint was shorter for the elite than for the non-elite rowers. During the drive phase, elite rowers kept the fully extended knee joint angle longer than the non-elite rowers (p < .05). The CV values of the TDrive within each group were smaller for the elite compared with non-elite rowers, except for the CV values of the hip at all stroke/min and elbow at 40 stroke/min. Conclusion: The elite, compared with non-elite, rowers seem to be able to perform more powerful and efficient rowing strokes with large RoM and a short $T_{Drive}$ with the same $T_{Lead}$.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.5 no.2
• /
• pp.86-94
• /
• 2000

In order to extract the spatio-temporal characteristics of long-term variability of the net heat flux on the sea surface in the East Asian marginal seas, empirical orthogonal function (EOF) analysis was conducted using data set calculated every 12 hours interval during 1978-1995. Among the first three modes explaining 73% of the total variance, the first mode having high peak at 1 year period indicates high variability area around the Sandong Peninsula and central and northeastern part of the East Sea. In the second mode which has spatial distribution of dipole type at the north and south, the peaks appear at 3.6 year and 2.3 year cycles. Time coefficient of the second EOF is believed to have close relation with the E1 Nino and has out-of-phase variation with NINO3 SST. Lagged correlation between NINO3 SST and time coefficient of the second EOF indicates four month time delay in the NINO3 SST. In the third mode which has opposite sign at the east and west, the periodicity of 6-9 year cycle has relatively clear appearance compared to other two EOFs. Also, high heat loss exceeding 800 W/$m^{2}$ in winter time occured at the south part of the Sandong Peninsula and Vladivostok. It reveals more frequent occurrence of about two times at the Sandong Peninsula than Vladivostok. The event is concentrated in January at Vladivostok, but it occurs primarily in December and January at the Sandong Peninsula.

• Journal of Pharmaceutical Investigation
• /
• v.31 no.4
• /
• pp.265-271
• /
• 2001

In order to elucidate the influence of intestinal and hepatic first-pass effect on the pharmacokinetics of triflusal, the biotransformation of triflusal in the gastrointestinal tract and liver was designed. Moreover, we tried to establish an HPLC method applicable for bioassay and available to pharmacokinetics, not only with the simultaneous determination of triflusal and its active metabolite, 2-hydroxy-4-trifluoromethyl benzoic acid (HTB), but also with improving sensitivity. After the administration of triflusal (10 mg/kg) and HTB (10 mg/kg) into femoral vein, portal vein (only triflusal) and oral route (only triflusal), pharmacokinetic parameters were investigated from the plasma concentration-time profiles of triflusal and HTB in rats. An HPLC method was developed for the simultaneous determination of triflusal and HTB in rat plasma, urine and bile. The HPLC analysis was carried out using a C18 column and acetonitrile-methanol-water (25:10:65, v/v/v) as the mobile phase and UV detection at 234 nm. Furosemide was used as the internal standard. The calibration curves were linear over the concentration range $0.05-5.0\;{\mu}g/ml$ for triflusal and $0.2-200.0\;{\mu}g/ml$ for HTB with correlation coefficients greater than 0.999 and with intra-day or inter-day coefficients of variation not exceeding 10.0%. This assay procedure was applied to the study of metabolite pharmacokinetics of triflusal and HTB in rats. It was supposed that triflusal was almost metabolized in vivo because urinary and biliary excreted amounts of triflusal could be ignored as it was lower than 1.2% of the administered dose. According to the gastrointestinal and hepatic biotransformation pathways of triflusal, it was found that triflusal was hydrolyzed by about 5% in intestine and metabolized by about 53% in liver, and that the bioavailability of triflusal after oral administration of triflusal was 0.44, and also that the fraction of total elimination rate of triflusal which formed HTB in liver $(F_{mi},\;%)$ was about 98%. These results showed that triflusal was almost metabolized in liver, and the total elimination of triflusal in the body was dependent to the formation rate of HTB from triflusal in liver.

• Journal of Korean Society for Geospatial Information Science
• /
• v.22 no.3
• /
• pp.113-119
• /
• 2014

The positioning accuracy of GNSS surveys deteriorates due to various error factor, and many users sometimes ignore Phase Center Variation (PCV) of antennas. IGS provides an ANTEX file which contains PCV correction information to correct for PCVs. But it is not directly applicable because PCV correction information is provided at 5-degree intervals in the azimuth and elevation directions for the case of receiver antennas, and at 1-degree intervals in the nadir angle for the case of satellite antennas. So, we devised new and optimal ways of interpolating PCV in any desired line of sight to the GNSS satellite. We used spherical harmonics fitting methods in terms of the azimuth and elevation angle for interpolation, and found an optimal degree and order. It is shown that the best accuracy was obtained from the 8 by 8 spherical harmonics. If one requires lower burden on computing resources, the order and degree less than 8 could produce resonable accuracy except for 1st and 5th order.

• Korean Journal of Environmental Agriculture
• /
• v.34 no.4
• /
• pp.309-317
• /
• 2015

BACKGROUND: An analytical method was developed using GC-ECD/MS to precisely determine the residue of fipronil, a phenylpyrazole insecticide used to control a wide range of foliar and soil-borne pests.METHOD AND RESULTS: Fipronil residue was extracted with acetone from representative samples of five raw products which comprised hulled rice, soybean, Kimchi cabbage, green pepper, and apple. The extract was diluted with saline water, and fipronil was partitioned into n-hexane/dichloromethane (20/80, v/v) to remove polar co-extractives in the aqueous phase. Florisil column chromatography was additionally employed for final purification of the extract. Fipronil was separated and quantitated by GC-ECD using a DB-17 capillary column. Accuracy of the proposed method was validated by the recovery from crop samples fortified with fipronil at 3 levels per crop in each triplication.CONCLUSION: Mean recoveries ranged from 86.6% to 106.0% in five representative agricultural commodities. The coefficients of variation were less than 10%. Limit of quantitation of fipronil was 0.004 mg/kg as verified by the recovery experiment. A confirmatory technique using GC/MS with selected-ion monitoring was also provided to clearly identify the suspected residue. Therefore, this analytical method was reproducible and sensitive enough to determine the residue of fipronil in agricultural commodities.

• Transactions of the Korean hydrogen and new energy society
• /
• v.9 no.4
• /
• pp.151-160
• /
• 1998

The variation of the hydrogen-storage properties of Mg contained in the mechanically-allyed mixture with the weight percentage of nickel in the sample is investigated. The weight percentage of nickel transformed into the Mg2Ni phase, on the basis of the nickel weight, is highest in the Mg-10 wt.%Ni sample. For the first hydriding cycle, the effect of mechanical alloying on the hydriding rate of Mg is highest in the Mg-25 wt.%Ni sample. After activation, the effects of mechanical alloying and hydriding-dehydriding cycling on the hydriding rate of Mg are highest in the Mg-10 wt.%Ni sample. After sufficient hydriding-dehydriding cycling, the effects on the hydrogen-storage capacity of Mg are highest in the Mg-10 wt.%Ni sample. The effects on the hydriding and dehydriding rates of Mg are highest in the Mg-25wt.%Ni sample. Mg-25wt.%Ni, followed by Mg-10 wt.%Ni, is the optimum composition which has the best effects on the hydrogen-storage properties of Mg contained in the sample. The mechanical alloying and the hydriding-dehydriding cycling produce many defects, which can act as active nucleation sites, and increase the specific surface area, shortening the diffusion distance of hydrogen.