• Title/Summary/Keyword: Phase transformation characteristics

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Phase Transition Characteristics in $Ge_xSb_{100-x}$ Film for Optical Storage Media

  • Park Tae-jin;Kang Myung-jin;Choi Se-young
    • 정보저장시스템학회:학술대회논문집
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    • 2005.10a
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    • pp.124-127
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    • 2005
  • Rewritable optical memory devices such as an CD-RW and DVD+RW are data storage media, which take advantage of the different optical properties in the amorphous and crystalline states of phase change materials. The switching property, structural transformation, transformation kinetics and chemical bindings of $Ge_xSb_{100-x}$($6{\le}x{\le}$34) were studied to investigate the feasibility of applying $Ge_xSb_{100-x}$ alloys in optical memory. The $Ge_xSb_{100-x}$ thin film was deposited by RF magnetron co-sputtering system and phase change characteristics were investigated by X-ray diffraction (XRD), static tester, inductively coupled plasma atomic emission spectrometer (ICP-AES) and atomic force microscopy (AEM). Optimum fiim composition of $Ge_xSb_{100-x}$ was studied and its minimum time fur laser induced crystallization and optical contrast fur phase transition was performed. These results might be correlated with the binding energies between Ge and Sb, and indicate that $Ge_xSb_{100-x}$ have an potential far optical memory applications.

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The Preparation of Seeded Alumina from Alkoxide (I): Powders (알콕사이드로부터 Seed가 첨가된 알루미나의 제조(I): 분말특성)

  • 김창은;임광일;이해욱
    • Journal of the Korean Ceramic Society
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    • v.29 no.5
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    • pp.367-376
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    • 1992
  • The powder characteristics of seeded alumina prepared from alkoxide by sol-gel method were studied. When ${\alpha}$-Al2O3 seeded powders used, these ${\alpha}$ phase transformation temperatures decreased than those of unseeded powders by 110$^{\circ}C$ and fine powders under 0.1 $\mu\textrm{m}$ could be obtained. When Fe-nitrate added powders used, fast transformation rate resulted from ionic effects of Fe3+, but hard aggregated morphology exhibited. When ${\alpha}$-Al2O3 and Fe nitrate simultaneously added, these powders represented lower transformation temperature but resulted in microstructure with aggregated particles.

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Effect of Phase Transformation Behavior of Electroless Nickel Plating Layer on Corrosion and Cavitation-Erosion with Heat Treatment (열처리에 따른 무전해 니켈 도금 층의 상변태 거동이 부식과 캐비테이션 침식에 미치는 영향)

  • Il-Cho Park;Seong-Jong Kim
    • Corrosion Science and Technology
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    • v.23 no.1
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    • pp.64-71
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    • 2024
  • The objective of this study was to investigate corrosion and cavitation-erosion characteristics of the electroless nickel plating layer with heat treatment. The crystallization temperature of the electroless nickel plating layer was about 410 ℃. The phase transformation energy was confirmed to be 12.66 J/g. With increasing heat treatment temperature, the amorphous electroless nickel plating layer gradually changed to crystalline Ni and Ni3P. At the same time, the crystal grain size was also increased. Additionally, when heat treatment was performed at a temperature above 400 ℃, NiO phase was observed due to oxidation phenomenon. As a result of the electrochemical polarization experiment, the corrosion resistance of the heat-treated electroless nickel plating layers was superior to that of the as-deposited plating layer. This was because crystal grains became larger and grain boundaries decreased during heat treatment. The cavitation-erosion resistance of heat-treated plating layers tended to be superior to that of as-deposited plating layers due to increased microhardness.

Characteristics of Surface Transformation Hardening for Rod-shaped Carbon Steels by Diode Laser (다이오드 레이저를 이용한 탄소강 환봉의 표면변태 경화특성)

  • Kim, Jong-Do;Kang, Woon-Ju;Lee, Su-Jin;Yoon, Hee-Jong;Lee, Jae-Hoon
    • Laser Solutions
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    • v.11 no.4
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    • pp.7-12
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    • 2008
  • Laser Transformation Hardening(LTH) is one branch of the laser surface modification processes. A lot of energy is needed for the LTH process to elevate workpiece surface to temperature of the austenite transformation($A_3$), which results from utilizing a beam with a larger size and lower power density comparatively. This study is related to the surface hardening for the rod-shaped carbon steel by the high power diode laser whose beam absorptivity is better than conventional types of lasers such as $CO_2$ or Nd:YAG laser. Because a beam proceeds on the rotating specimen, the pretreated hardened-phase can be tempered and softened by the overlapping between hardened tracks. Accordingly, the longitudinal hardness measurement and observation of the micro structure was carried out for an assessment of the hardening characteristics. In addition, a hardening characteristics as a hardenability of materials was compared in the point of view of the hardness distribution and hardening depth and width.

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A Study of the Characteristics of Cast Ni-Ti Alloy for Biomaterial with Compositional Change (정밀 주조한 생체용 Ni-Ti합금의 조성변화에 따른 특성 연구)

  • 권오원;김교한
    • Journal of Biomedical Engineering Research
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    • v.14 no.3
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    • pp.283-290
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    • 1993
  • In thls study, the effects of the composltional change of cast Ni-Ti alloys on its characteristics including mechanical properties, phase transformation temperature, and ion releasing rate were investigated. brittle:behavior was shown in the stress-strain curve of the alloy containing low Ti content (Ni-44.0%Ti). By increasing the Ti content, the trend in stress-strain curves changed from that of superelasticity to that of shape memory effect(Ni-44.4%Ti, Ni-45.1%Ti, Ni-45, 5%Ti). Phase transformation temperature ($A_f, {\;}M_5$ point) increased with increasing the Ti content. lon releasing rate of four types of Mi-Ti alloys was very low compared to that of the dental commerical Ni-Cr alloy.

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Characteristic Analysis of Three Phase PWM Boost AC-AC Converter Using Circuit DQ Transformation (회로 DQ 변환을 이용한 3상 PWM Boost AC-AC 컨버터의 특성해석)

  • 최남섭
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.7 no.7
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    • pp.1514-1519
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    • 2003
  • This paper presents modeling and analysis of static and dynamic characteristics in three phase PWM Boost AC-AC converter used for input voltage sag compensation of custom power. Especially, using circuit DQ transformation technique, an equivalent circuit in fundamental frequency domain is obtained which has all the system characteristics. Moreover, voltage gain and input power factor is analytically induced and linearized state equation at the specific operating point is given. Finally, PSIM simulation results show the validity of the Nosed modelling and analyses.

Modeling and Analysis of Three Phase PWM Converter (3상 PWM 컨버터의 모델링 및 해석)

  • 조국춘;박채운;최종묵
    • Proceedings of the KSR Conference
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    • 1999.05a
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    • pp.328-335
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    • 1999
  • Three phase full bridge rectifier has been used to obtain dc voltage from three phase ac voltage source. The rectifier system has drawbacks that power factor is low and power flow is unidirectional. Therefore, when dc voltage increases due to regeneration of power the dynamic resister for dissipation of regeneration power must be installed. But three phase PWM converter can be controlled to operate with unity power factor and bidirectional power flow. Therefore when the PWM converter is used as do supply system, the dissipating resistor is not necessary. On this thesis, in order to design a controller having good performance, the hee phase PWM converter is completely modeled by using circuit DQ-transformation and thus a general and simple instructive equivalent circuit is obtained; the inductor set becomes a second order gyrator-coupled system and three phase inverter becomes a transformer as well. Under given phase angle(${\alpha}$) and modulation index(MI) of the three phase inverter, the dc and ac characteristics are obtained by analysis of the transformed equivalent circuit The validity of the equivalent circuit is confirmed through PSPICE simulation. And based on the dc and ac characteristics a controller with unity power factor is proposed.

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Effect of Thermal Cycle and Aging Heat Treatment on Transformation Characteristics of Cu-Zn-Al Shape Memory Alloys (Cu-Zn-Al계 형상기억합금의 변태특성에 미치는 열 Cycle 및 시효열처리의 영향)

  • Park, Pyeongyeol;Kim, Ickjun;Park, Seyun;Kim, Inbae;Park, Ikmin
    • Journal of the Korean Society for Heat Treatment
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    • v.2 no.4
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    • pp.47-55
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    • 1989
  • The effects of thermal cycle, aging heat treatment and Boron addition on the phase transformation characteristics and mechanical properties of the shape memory alloys of Cu-Zn-Al system, which was designed to operate about $80^{\circ}C$ by this research group, were studied. From the view point of the effects of thermal cycle on the phase transformation temperature change, it was found that up to 100 cycles Ms and Af points increased by $3-7^{\circ}C$ and Mf decreased a little bit and after that all of them were remain constant, and As point was not affected. All of the phase transformation temperatures were decreased $5-7^{\circ}C$ by aging heat treatment, at $140^{\circ}C$ for 24h however the effects of thermal cycle on aged alloys were same as on unaged alloys. As the thermal cycle increased the shape memory ability decreased a little up to 20 cycles, but above that it kept almost same ability. By Boron addition, grain size was refined from $1500{\mu}m$ to about $330{\mu}m$ and the hardness, fatigue property were improved but shape memory ability was lowered.

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Real-Time CoM/ZMP Trajectory Transformation Method for Humanoid Robots Considering Structure Characteristics (구조 특성을 반영한 인간형 로봇을 위한 실시간 CoM/ZMP 궤적 변환 방법)

  • Hong, Seok-Min
    • Journal of Advanced Navigation Technology
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    • v.21 no.1
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    • pp.132-137
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    • 2017
  • This paper proposes a transformation method of the zero moment point (ZMP) and the center of mass (CoM) from one walking pattern to other patterns by considering the structure of a robot or walking situations in real time. In general, a humanoid robot has own structure characteristics like height and mass. The structure characteristics make the given CoM/ZMP walking pattern of one human or one humanoid robot to be difficult to apply to other robot directly. For this purpose, we analyze the characteristics of walking patterns according to the step length, duration of walking support phase and the CoM height by using the cart-table model as the simple humanoid robot model. A transformation equation is derived from the analyzation and it is verified with simulation.

Circuit Topology and Characteristics of Three Phase PWM Noninverting Buck-Boost AC-AC Converter (3상 PWM 비반번 Buck-Boost AC-AC 컨버터의 회로구성과 특성)

  • Choi, Nam-Sup
    • Proceedings of the KIPE Conference
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    • 2005.07a
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    • pp.116-118
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    • 2005
  • In this paper, a three phase PWM noninverting Buck-Boost AC-AC converter for WCF applications is presented. The PWM noninverting Buck-Boost AC-AC converter is modelled by using vector DQ transformation whereby the basic DC characteristics equation is analytically obtained. Finally, the PSIM simulation shows the validity of the modelling and analysis.

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