• Journal of Adhesion and Interface
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• v.2 no.2
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• pp.11-19
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• 2001

The phase-transfer catalyzed radical polymerization of styrene was carried out using tricaprylylmethylammonium chloride as a phase-transfer catalyst in a two-phase system of an aqueous $Na_2S_2O_8$ solution and toluene at $60^{\circ}C$ under nitrogen atmosphere. The initial rate of radical polymerization was expressed as the combined terms of concentrations of quaternary onium cation and peroxydisulfate anion in the aqueous phase rather than the fed concentrations of catalyst and $Na_2S_2O_8$. The observed initial rate of radical polymerization was used to analyze the radical polymerization mechanism with a cycle phase-transfer initiation step in the heterogeneous liquid-liquid system. The viscosity average molecular weight of polystyrene was inversely proportional to concentration of $Na_2S_2O_8$ expressed as $[Q^+]([S_2O{_8}^{2-}]{\alpha}_2)^{1/2}$ derived by the radical polymerization mechanism.

• Journal of Advanced Marine Engineering and Technology
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• v.24 no.2
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• pp.31-37
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• 2000

This study investigated heat transfer characteristics of refrigeration system using new type aluminium heat transfer tube for evaporator of refrigeration and air-conditioning comparing with bare tube. From the result of heat transfer experiment form one phase flow using cooled and hot water, about 20% heat transfer performance is superior in case of same quantity of flow and about 4% heat transfer performance if superior in case of same velocity comparing with bare tube. Casing of two phase flow, heat transfer performance of new type aluminum heat transfer tube shows about 50% superior heat transfer performance comparing with bare tube in the same evaporating pressure when using heat transfer tube as evaporator and shows about 47% increase when expressing performance coefficient as the rate of refrigerating capacity and compressing work. However, it can be known that pressure drop in the heat transfer tube is taken higher value of about 18% in case of new type aluminum heat transfer tube. From the above result, new type aluminum heat transfer tube is excellent comparing with bare heat transfer tube using the existing heat exchanger for refrigerator.

• 대한공업교육학회지
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• v.33 no.2
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• pp.248-258
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• 2008

Current Internet uses HTTP (Hyper Text Transfer Protocol) as an application layer protocol and TCP (Transmission Control Protocol) as a transport layer protocol to provide web service. SCTP (Stream Control Transmission Protocol) is a recently proposed transport protocol with very similar congestion control mechanisms as TCP, except the initial congestion window during the slow start phase. In this paper, we present a mathematical model of object transfer latency during the slow start phase for HTTP over SCTP and compare with the latency of HTTP over TCP. Validation of the model using experimental result shows that the mean object transfer latency for HTTP over SCTP during the slow start phase is less than that for HTTP over TCP by 11%.

• Journal of Advanced Marine Engineering and Technology
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• v.28 no.6
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• pp.1026-1036
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• 2004

In this study, single-phase heat transfer experiments were conducted with Oblong Shell and Plate heat exchanger using water. An experimental water loop has been developed to measure the single-phase heat transfer coefficient and pressure drop in a vertical Oblong Shell and Plate heat exchanger. Downflow of hot water in one channel receives heat from the cold water upflow of water in the other channel. Similar to the case of a plate heat exchanger, even at a very low Reynolds number, the flow in the Oblong Shell and Plate heat exchanger remains turbulent. The present data show that the heat transfer coefficient and pressure drop increase with the Reynolds number. Based on the present data, empirical correlations of the heat transfer coefficient and pressure drop in terms of Nusselt number and friction factor were proposed. Also, performance prediction analyses for Oblong Shell and Plate heat exchanger were executed and compared with experiments. $\varepsilon$-NTU method was used in this prediction program. Independent variables are flow rates and inlet temperatures. Compared with experimental data, the accuracy of the program is within the error bounds of $\pm$5% in the heat transfer rate.

• Bulletin of the Korean Chemical Society
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• v.16 no.5
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• pp.410-416
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• 1995

The proton transfer energies of gas phase glycine and alanine and those of hydrated glycine and alanine were calculated both with Hartree-Fock and $M{\Phi}ller-Plesset$ ab initio molecular orbital (MO) calculations with 6-31G** basis set. The transition states of the proton transfer of gas phase glycine was also investigated. For zwitterions, both for glycine and alanine, the water bound to -NH3+ site stabilize the complex more compared with the water bound to -CO2-. The proton transfer energy, ΔEpt, of glycine, alanine, mono-hydrated glycine, mono-hydrated alanine, di-hydrated glycine and di-hydrated alanine were obtained as 30.78 (MP2: 22.57), 31.43, 23.99 (MP2: 17.00), 24.98, 22.87, and 25.63 kcal/mol, respectively. The activation energy for proton transfer from neutral (Nt) glycine to zwitterion (Zw) glycine, Ea, was obtained as 16.13 kcal/mol and that for reverse process, Ear, was obtained as 0.85 kcal/mol. Since the transition state of the proton transfer of gas phase glycine locate near the glycine zwitterion on the potential energy surface and the shape of the potential well of the zwitterion is shallow, the zwitterion easily changed to neutral glycine through the proton transfer.

• 한국생물공학회:학술대회논문집
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• 2000.11a
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• pp.73-76
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• 2000

A novel, continuous bioreactor system combining a bubble column (absorption section) and a two-phase bioreactor (degradation section) has been designed to treat a gas stream containing benzene. The bubble column contained hexadecane as an absorbent for benzene, and was systemically chosen considering physical, biological, environmental, operational and economic factors. This solvent has infinite solubility for benzene and very low volatility. After absorbing benzene in the bubble column, the hexadecane served as the organic phase of the two-phase partitioning bioreactor, transferring benzene into the aqueous phase where it was degraded by Alcaligenes xylosoxidans Y234. The hexadecane was then continuously recirculated back to the absorber section for the removal of additional benzene. All mass transfer and biodegradation characteristics in this system were investigated prior to operation of the integrated unit, and these included: the mass transfer rate of benzene in the absorption column, the mass transfer rate of benzene from the organic phase into the aqueous phase in the two-phase bioreactor, the stripping rate of benzene out of the two-phase bioreactor, etc. All of these parameters were incorporated into model equations, which were used to investigate the effects of operating conditions on the performance of the system. Several experiments were conducted to show the feasibility of this system. This process is believed to be very practical for the treatment of high concentrations of gaseous pollutants.

• Korean Chemical Engineering Research
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• v.46 no.3
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• pp.451-464
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• 2008

Three-phase inverse fluidized bed has been widely adopted with its increasing demand in the fields of bioreactor, fermentation process, wastewater treatment process, absorption and adsorption processes, where the fluidized or suspended particles are small or lower density comparing with that of continuous liquid phase, since the particles are frequently substrate, contacting medium or catalyst carrier. However, there has been little attention on the three-phase inverse fluidized beds even on the hydrodynamics. Needless to say, the information on the hydrodynamics and transport phenomena such as heat and mass transfer in the inverse fluidized beds has been essential for the operation, design and scale-up of various reactors and processes which are employing the three-phase inverse beds. In the present article, thus, the information on the three-phase inverse fluidized beds has been summarized and reorganized to suggest a pre-requisite knowledge for the field work in a sense of engineering point of view. The article is composed of three parts; hydrodynamics, heat and mass transfer characteristics of three-phase inverse fluidized beds. Effects of operating variables on the phase holdup, bubble properties and particle fluctuating frequency and dispersion were discussed in the section of hydrodynamics; effects of operating variables on the heat transfer coefficient and on the heat transfer model were discussed in the section of heat transfer characteristics ; and in the section of mass transfer characteristics, effects of operating variables on the liquid axial dispersion and volumetric liquid phase mass transfer coefficient were examined. In each section, correlations to predict the hydrodynamic characteristics such as minimum fluidization velocity, phase holdup, bubble properties and particle fluctuating frequency and dispersion and heat and mass transfer coefficients were suggested. And finally suggestions have been made for the future study for the application of three-phase inverse fluidized bed in several available fields to meet the increasing demands of this system.

• Journal of Fisheries and Marine Sciences Education
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• v.27 no.5
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• pp.1310-1317
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• 2015

Two-phase flow boiling heat transfer in micro-channels was experimently investigated. The test section consisted of 15 rectangular micro-channels with a depth of 0.45mm, width of 0.20mm. The experiments were performed for heat fluxes ranging from 5.6 to 46.1kW/m2 and mass fluxes from 150 to 450kg/m2s using FC-72 as the working fluid. According to the results, at the low heat flux region, heat transfer coefficient strongly depends on the heat flux, while heat transfer coefficient at the high heat flux region was independent on the heat flux. Four correlations were used to predict the heat transfer coefficient. The measured heat transfer coefficient was compared with four correlations. It was found that Kaew-On and Wongwises's correlation well predicted the measured data, within the MAE of 40.3%.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.7 s.238
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• pp.814-819
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• 2005

The phase change heat transfer has been applied to the processes of machines as well as of manufacturing. The cycle in a heat exchanger includes the phase change phenomena of coolant for air conditioning, the solidification in casting process makes use of the characteristics of phase change of metal, and the welding also proceeds with melting and solidification. To predict the phase change processes, the experimental and numerical approaches are available. In the case of numerical analysis, the Enthalpy method is most widely applied to the phase change problem, comparing to the other numerical methods, i.e. the Equivalent Specific Heat method and the Temperature Recovery method. It's because that the Enthalpy method is accurate and straightforward. The Enthalpy method does not include any correction step while the correction of final temperature field is inevitable in the Equivalent Specific Heat method and the Temperature Recovery method. When the temperature field is to be used in the calculation, however, there must be converting process from enthalpy to temperature in the calculation scheme of Enthalpy method. In this study, an improved method for the Equivalent Specific Heat method is introduced whose method dose not include the correction steps and takes temperature as an independent variable so that the converting between enthalpy and temperature does not need any more. The improved method is applied to the solidification process of pure metal to see the differences of conventional and improved methods.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.9 no.5
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• pp.96-104
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• 2000

This paper represents to develop a computer software system which is capable to analyze the phase transformation of high strength steel(BV-AH32) and to predict heat transfer and welding residual stress due to phase transformation during Gas Metal Arc(GMA) welding. The developed model was considered temperature dependent properties such as young's modules, coefficient of thermal expansion and yield stress as well as the double ellipsoidal heat distribution by the moving arc. From the results, it was found that the longitudinal and transverse residual stresses calculated by the coupled analysis of heat transfer, residual stress and phase transformation showed good agreement with the experimental data. In addition, the temperature distribution as well as longitudinal and transverse residual stresses of weldment by the 1-pass and 2-pass of welding were also determined.