• Title/Summary/Keyword: Phase diagram

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Recent Development in Computational Welding Mechanics (전산용접역학의 최근 동향)

  • Im, Se-Young;Han, You-Sung;Lee, Kye-Hyoung;Han, Myoung-Soo;Choi, Kang-Hyouk
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.87-91
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    • 2009
  • Welding is one of the most important joining processes and the effect of welding residual stresses in the structure has a great deal of influence on its quality. In this paper, recent development in computational welding mechanics, particularly calculation of welding residual stresses, is introduced. The hypoelastic formulation of finite element analysis for thermoelastic-plastic deformation is applied to welding processes to find residual deformations and stresses. Leblond's phase evolution equation coupled with the energy equation is employed to calculate the phase volume fraction; this plays an important role as a kinetics parameter affecting phase fraction effects in the mechanical constitutive equation of welded materials. Furthermore, transformation plasticity is taken into account for an accurate evaluation of stress. The influence of the phase transformation and the transformation plasticity on residual stress is investigated by means of numerical analyses using metallurgical parameters in Leblond's phase evolution equation that are adjusted with respect to various cooling rates in a CCT-diagram. Coding implementation is conducted by way of the ABAQUS user subroutines, UMAT.

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Fabrication and Crystallization Behavior of BNN Thin Films by H-MOD Process

  • Lou, Junhui;Lee, Dong-Gun;Lee, Hee-Young;Lee, Joon-Hyung;Cho, Sang-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.08a
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    • pp.98-102
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    • 2003
  • $Ba_2NaNb_5O_{15}$, hereafter BNN, thin films are attractive candidates for nonvolatile memory and electro-optic devices. In the present work, thin films that have different contents of Ba, Na and Nb have been prepared by H-MOD technique on silicon and Pt substrates. XRD and SEM were used to investigate the phase evolution behavior and the microstructure of the films. It was found that the films of about 450nm thick were crack-free and uniform in microstructure. Nb content strongly influenced the phase formation of the films, where low temperature phase was always formed at the stoichiometric BNN composition. However, the amount of low temperature phase decreased with the increase of excess Nb content, and the single phase (orthorhombic tungsten bronze structure) BNN thin film was obtained at the temperature as low as $750^{\circ}C$ for samples with excess niobium. From this study, the sub-solidus phase diagram below $850^{\circ}C$ for $BaO-Na_2O-Nb_2O_5$ ternary system is proposed.

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Effect of Double Aging on Microstructure and Mechanical Properties of Ag Added magnesium Alloys (Ag첨가 마그네슘 합금의 이중열처리에 따른 미세조직 및 기계적 특성변화)

  • Lee, Byeong-Deok;Baek, Ui-Hyun;Jang, Kyoung-soo;Han, Jeong-Whan;Son, Hyeon-taek
    • Korean Journal of Metals and Materials
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    • v.49 no.6
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    • pp.440-447
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    • 2011
  • To improving the mechanical properties of Mg alloys at high temperature, we investigated the mechanical properties at high temperature and the change of microstructure of Mg-6 wt%Zn-0.4 wt%Mn and Mg-6 wt%Zn-0.4 wt%Mn-1 wt%Ag alloys on age treatment that have a stable MgZn phase at high temperature and $AgMg_4$ improving yield stress. In order to predict thermodynamic data of Mg alloys, a phase diagram and precipitation phase were calculated using a thermodynamic program, and it was confirmed that the MgZn and $AgMg_4$ phase existed as main precipitation in this alloys. The experimental data examined using DSC and XRD were comparable with the calculated data for reliability. In order to analysis the microstructure and precipitate phase during aging treatment, it was measured by SEM/EDS and TEM. Lastly, mechanical properties of the MgZn and $AgMg_4$ phase were measured by a tensile test at high temperature.

Fully Printed Dual-Band Power Divider Miniaturized by CRLH Phase-Shift Lines

  • Eom, Da-Jeong;Kahng, Sungtek
    • ETRI Journal
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    • v.35 no.1
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    • pp.150-153
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    • 2013
  • In this letter, a compact and fully printed composite right- and left-handed (CRLH) dual-band power divider is proposed. The branches of the conventional Wilkinson power divider are replaced by subwavelength CRLH phase-shift lines having $+90^{\circ}$ for one frequency and $-90^{\circ}$ for another frequency for dual-band and miniaturization performance. Equations are derived for the even- and odd-mode analysis combined with the dual-band CRLH circuit. A PCS and a WLAN band are chosen as the test case and the circuit approach agrees with the CAD simulation and the measurement. Additionally, the CRLH property is shown with the dispersion diagram and the eightfold size reduction is noted.

Analysis of Proportional Control for Grid Connected Inverter With LCL Filter

  • Windarko, Novie Ayub;Lee, Jin-Mok;Choi, Jae-Ho
    • Proceedings of the KIPE Conference
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    • 2008.06a
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    • pp.247-249
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    • 2008
  • There are many types of grid-connected inverter controllers; Synchronous Reference Frame (SRF)-based controller is the most popular methods. SRF-based controller is capable for reducing both of zero-steady state error and phase delay. However, SRF-based controller has a complex algorithm to apply in real application such as digital processor. Resonant controller is also reduced zero-steady state error, but its transfer function has a high order. In this paper, a simple proportional control is applied for grid connected inverter with LCL filter. LCL filter is a third order system. Applying a simple proportional controller is not increased the order of closed loop transfer function. By this technique, the single phase model is easily obtained. To reduce steady state error, proportional gain is set as high as possible, but it may produce instability. To compromise between a minimum steady state error and stability, the single phase model is evaluate through Root Locus and Bode diagram. PSIM simulation is used to verify the analysis.

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Correction of lmpurity Effects on the Characterization of YBCO (YBCO의 특성분석에 있어서 불순물효과의 보정)

  • Ha, Dong-Han;Byon, Sun-Ye;Kim, Yong-Il;Han, Gi-Yeol;Lee, Kyu-Won
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.171-174
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    • 1999
  • We have characterized solid solution Y$_{l-x}Ca_xBa_2Cu_3O_y$ (0${\le}$x${\le}$0.3) materials by measuring the XRD pattern, resistivity and hole concentrations, etc. As Ca concentration increases, T$_c$, is decreased monotonically because the hole concentration on the superconducting plane increases beyond the optimum region in the electronic phase diagram due to the hole transfer from the Cu-O chain to the CuO$_2$ plane. A very small amount of secondary phase have large effects on the analysis of oxygen content and hole concentration etc. The results before the correction of impurity phase are compared with those after the correction.

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Diffusion Kinetics of Si in GaAs and Related Defect Chemistry (GaAs에서의 Si의 확산기구와 그에 관련된 격자 결함 화학)

  • Lee, Gyeong-Ho
    • ETRI Journal
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    • v.11 no.4
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    • pp.75-83
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    • 1989
  • The diffusion mechanism of Si in GaAs was investigated using different diffusion sources based on the Si-Ga-As ternary phase equilibria. The Si profiles are measured with secondary ion mass spectrometry and differ significantly for sources taken from the different phase fields in the ternary phase diagram. Neutral As vacancy diffusion is proposed for acceptor Si diffusion anneals using a Ga - Si - GaAs source. Donor Si diffusion using As - rich sources and a Si -GaAs tie line source shows concentration dependent diffusion behavior. Concentration dependent diffusion coefficients of donor Si for As - rich source diffusion were found to be related to net ionized donor concentration and showed three regimes of different behavior: saturation regime, intermediate regime,and intrinsic regime. Ga vacancies are proposed to be responsible for donor Si diffusionin GaAs: $Si_Ga^+V_Ga^-$ (donor Si -acceptor Gavacancy) complex for the extrinsic regime and neutral $V_G$a, for the intrinsic regime.The Si - GaAs tie line source resulted in two branch profiles, intermediate between the As - rich and the Ga - rich source diffusion cases.

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Solvent Extraction of Copper and Nickel from Manganese Nodule Leachate by LIX 84 (망간단괴 침출액으로부터 LIX 84에 의한 구리, 니켈의 용매추출)

  • Lee, Jae-Jang;Roh, Beom-Sik
    • Journal of Industrial Technology
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    • v.19
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    • pp.189-195
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    • 1999
  • A study on the separation Cu, Ni, and Co was carried out using LIX 84 leachate, chelate extractant. For this test, artificial test solution was prepared by varing concentrations of Cu, Ni, Co, $(NH_4)_2CO_3$ and $(NH_4)_2SO_4$. It found that pH of the solution was very important factor for the separation of nickel from copper. The results showed that nickel was effectively extracted from copper by using LIX 84 at pH 1.0 to 1.2. The volume ration or organic to aqueous phases was 1.0. According to the McCabe-Thiele diagram, the extraction rate of copper was 99 percents at the equal ratio of organic to aqueous phase in three stages.

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Temperature and Property Control of High Strength Steel in Hot Strip Mills (열간압연 고강도강의 온도 및 재질제어)

  • Park, Cheol-Jae
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.20 no.6
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    • pp.817-823
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    • 2011
  • This paper proposes a cooling stop temperature control(CST) and a phase transformation control(PTR) which aim at obtaining the uniform temperature and quality along the longitudinal direction of the high strength steel on the run-out table(ROT) process. The problems of the temperature control are analyzed for the conventional steel and the new control concepts are derived from a time-temperature transformation(TTT) diagram. The proposed control technologies are verified from the simulation results under the temperature prediction model by the heat transfer governing equation, and the temperature estimation simulator. It is shown through the field test of the hot strip mills that the phase transformation ratio of the high strength steel is considerably improved by the proposed temperature controls.

Solidification and Phase Equilibria Studies by Directional Solidification Technique in the Ni-Al System (Ni-Al계에서 일방향응고에 의한 응고 및 상평형 연구)

  • Lee, Jae-Hyeon;Jo, Chang-Yong;Lee, Jong-Hun;Choe, Seung-Ju
    • 연구논문집
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    • s.25
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    • pp.163-168
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    • 1995
  • The intermetallic compound $Ni_3Al$ causes a peritectic reaction at the composition and temperature very close to the eutectic reaction in Ni-Al system. Although the phase diagram accepted for this system by ASM Handbook has the eutectic forming between the $\gamma$ and $\gamma$ phases, directional solidification study has shown that the eutectic occurs between $\beta$ and $\gamma$. This work examines the liquidus region using quenched, directional solidification experiments that preserve the microstructrues formed at the solidification front. It is also shown that under certain composition and growth conditions a metastable eutectic between the $\beta$ and $\gamma$ phases forms in this system. Finding of the metastable eutectic provided an important information to understand the phase equilibria near the $Ni_3Al$ composition.

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