• Title/Summary/Keyword: Phase boundary

Search Result 1,095, Processing Time 0.025 seconds

Effects of α2/β Volume Fraction on the Superplastic Deformation (2 상 Ti3Al-xNb 계 금속간 화합물들의 초소성 특성에 미치는 상분율의 영향)

  • 김지식
    • Transactions of Materials Processing
    • /
    • v.11 no.5
    • /
    • pp.447-456
    • /
    • 2002
  • A study has been made to investigate the boundary sliding and its accommodation mode with respect to the variation of $\alpha$$_2$/$eta$ volume fraction during superplastic deformation of two-phase Ti$_3$Al-xNb intermetallics. Step strain rate and load relaxation tests have been performed at 950, 970 and 99$0^{\circ}C$ to obtain the flow stress curves and to analyze the deformation characteristics by the theory of inelastic deformation. The results show that the grain matrix deformation and boundary sliding of the three intermetallics containing 21, 50 and 77% in $eta$ volume fractions are well described by the plastic deformation and viscous flow equations. Due to the equal accommodation of both $a^2$ and $\beta$ phases, the accommodation modes for fine-grained materials are in good agreement with the iso-strain rate models. The sliding resistance analyzed for the different boundaries is the lowest in the $\alpha$$_2$/$\alpha$$_2$ boundary, and increases in the order of $\alpha$$_2$/$\alpha$$_2$<< $\alpha$$_2$/$\beta$ = $\beta$/$\beta$, which plays an important role in controlling the superplasticity of the alloys with the various $\alpha$$_2$/$\beta$ phase ratio.

Precipitation Behavior of Laves Phase in 10%Cr Ferrite System Alloy (10%Cr 페라이트계 합금에서 라베스상의 석출거동에 관한 연구)

  • Kim, I.S.;Kang, C.Y.;Bae, D.S.
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.12 no.1
    • /
    • pp.21-30
    • /
    • 1999
  • The present study were investigated changes of precipitation behaviour of laves phase in ferrite single phase and ferrite-martensite dual phase and precipitation of laves phase under stress. Hardness changes in ferrite phase appeared two hardness peaks by precipitation of initial fine precipitator and laves phase in 3Mo-0.3Si and 3Mo-0.3Si-C specimens, respectively. Hardness changes in martensite phase of 3Mo-0.3Si-C specimen was lower in the initial stage of aging by carbide precipitation and after this, increased by re-hardening due to precipitation of laves phase. In the ferrite phase, laves phase was mainly precipitated, whereas in the martensite phase, carbide was preferentially formed during the initial stage of aging and with increasing aging time, laves phase and carbide were simultaneously precipitated by precipitation of laves phase at around carbide. In the ferrite-martensite interface, laves phase was mainly precipitated and carbide was mainly formed at boundary of lath martensite than grain boundary. Adding the stress in aging, fine precipitator of inital precipitation of laves phase precipitated in (100) of perpendicular to tensile direction and has grown to only followed<010>direction and also, volume fraction of laves phase increased. Consequently, the stress added was accelerated initial precipitation of laves phase.

  • PDF

The Effect of Mechanical Stress and Electric Field on the Morphotropic Tetragonal and Rhombohedr Phase Boundary in PZT System : Thermodynamic Consideration (PZT계의 정방정상과 능면체정상의 경계조성에 대한 기계적 응력과 전기장의 영향 : 열역학적 고찰)

  • 천채일;김호기
    • Journal of the Korean Ceramic Society
    • /
    • v.30 no.10
    • /
    • pp.859-865
    • /
    • 1993
  • Morphotropic tetragonal and rhombohederal phase boundary(MPB) in PZT system was calculated and the effect of mechanical stress and electric field on the MPB was examined using phenomenological thermodynamic theory proposed by Devonshire. Mechanical stress and electric field was calculated to change free energies of phases and shift MPB. The stable composition range of the phase, of which spontaneous strain and spontaneous polarization aligned to the direction of tensile stress or electirc field, was expanded.

  • PDF

Morphology and Segregation of Sulfide Inclusions in Cast Steels (II) (Influence of [Mn/S] Ratios on the Morphology of Sulfide Inclusions in Fe-Mn-S Alloys) (주강의 유화물 형태와 편석에 대한 연구 (II) (Fe-Mn-S 합금의 유화물 형태에 미치는 Mn/S비의 영향))

  • Park, Heung-Il;Kim, Ji-Tae;Kim, Woo-Yeol
    • Journal of Korea Foundry Society
    • /
    • v.29 no.6
    • /
    • pp.270-276
    • /
    • 2009
  • After casting button-type small ingots of ternary Fe-Mn-S alloys which had three different Mn/S ratios (1, 5 and 70) in a vacuum arc furnace, the effect of the ratio on the sulfide formation was investigated. In case of the Mn/S ratio of 1, if alloy composition was located in an iron-rich corner on a Fe-Mn-S ternary phase diagram, only duplex MnS-FeS sulfide films were observed in the grain boundary. If the alloy composition was located in the miscibility gap area of the phase diagram, primary globular dendritic sulfides and dendritic sulfide slags were generated within the grain and tubular monotectic sulfides were also detected in the grain boundary. When the Mn/S ratio was 5, if the alloy composition was in the iron-rich corner, only bead-like sulfides were generated. On the other hand, if the composition was in the miscibility gap area, globular dendritic sulfides and dendritic sulfide slags were generated in the form of primary sulfide inclusions and rod-like eutectic sulfides were observed in the grain boundary. Especially, if the contents of Mn and S increased more in the miscibility gap area of the phase diagram, primary globular sulfides containing iron intrusions were observed. In case of Mn/S ratio of 70, if the contents of Mn and S was decreased in the Fe corner of the phase diagram, only bead-like sulfides were observed in the grain boundary. Despite the composition was outside the miscibility gap area of the phase diagram, if the contents of Mn and S increased, clusters of fine sulfide particles as well as fine spherical primary monophase sulfides were observed in the grain boundary.

Effect of Change of Grain-Boundary Phases on the Fracture Toughness of Silicon Nitride Ceramics (입계상 변화가 질화규소의 요업체의 파괴인성에 미치는 영향)

  • Lee, Sang-Hun;Park, Hui-Dong;Lee, Jae-Do;Kim, Do-Yeon
    • Korean Journal of Materials Research
    • /
    • v.5 no.6
    • /
    • pp.699-705
    • /
    • 1995
  • Effect of the grain boundary phases in Si$_3$N$_4$ ceramics on the fracture tonghness has been investigated. The Si$_3$N$_4$-Y$_2$O$_3$-SiO$_2$, (YS) and Si$_3$N$_4$-Y$_2$O$_3$-Al$_2$O$_3$(YA) systems were Can/HIP treated at 1750$^{\circ}C$ and then heat-treated at 1800∼2000$^{\circ}C$. The fracture toughness of the YA system, the grain boundary phase was only glass phase after heat-treatement, was increased. That of the YS system, however, the grain boundary phase was changed from crystalline and glass to glass phase after the heat -treatement above 1900$^{\circ}C$, was abruptly decreased. The reason of the sudden drop of the fracture toughness of the YS system was believed that the change of the grain boundary phases from crystalline and glass to glass phase effected un the fracture behavior.

  • PDF

HRTEM Study of Phase Transformation from Anatase to Rutile in Nanocrystalline $TiO_2$ Particles

  • Kim, Kyou-Hyun;Park, Hoon;Ahn, Jae-Pyoung;Lee, Jae-Chul;Park, Jong-Ku
    • Proceedings of the Korean Powder Metallurgy Institute Conference
    • /
    • 2006.09a
    • /
    • pp.466-467
    • /
    • 2006
  • The anatase particle was facetted at the free surface and a neck formation between the anatase particles prior to the phase transformation occured. This resulted in the severe lattice distortion at the region of the interface near the neck and this can act as the nucleation sites for the phase transformation. The grain growth of rutile particles after the phase transformation grew very fast by the sweeping phenomena of grain boundary. Therfore, It leaded to the microstructure without the rutile phase located in anatase particle.

  • PDF

Trajectory Optimization for Autonomous Berthing of a Twin-Propeller Twin-Rudder Ship

  • Changyu Lee;Jinwhan Kim
    • Journal of Ocean Engineering and Technology
    • /
    • v.37 no.3
    • /
    • pp.122-128
    • /
    • 2023
  • Autonomous berthing is a crucial technology for autonomous ships, requiring optimal trajectory planning to prevent collisions and minimize time and control efforts. This paper presents a two-phase, two-point boundary value problem (TPBVP) strategy for creating an optimal berthing trajectory for a twin-propeller, twin-rudder ship with autonomous berthing capabilities. The process is divided into two phases: the approach and the terminal. Tunnel thruster use is limited during the approach but fully employed during the terminal phase. This strategy permits concurrent optimization of the total trajectory duration, individual phase trajectories, and phase transition time. The efficacy of the proposed method is validated through two simulations. The first explores a scenario with phase transition, and the second generates a trajectory relying solely on the approach phase. The results affirm our algorithm's effectiveness in deciding transition necessity, identifying optimal transition timing, and optimizing the trajectory accordingly. The proposed two-phase TPBVP approach holds significant implications for advancements in autonomous ship navigation, enhancing safety and efficiency in berthing operations.

Development of Simplified Immersed Boundary Method for Analysis of Movable Structures (가동물체형 구조물 해석을 위한 Simplified Immersed Boundary법의 개발)

  • Lee, Kwang-Ho;Kim, Do-Sam
    • Journal of Korean Society of Coastal and Ocean Engineers
    • /
    • v.33 no.3
    • /
    • pp.93-100
    • /
    • 2021
  • Since the IB (Immersed Boundary) method, which can perform coupling analysis with objects and fluids having an impermeable boundary of arbitrary shape on a fixed grid system, has been developed, the IB method in various CFD models is increasing. The representative IB methods are the directing-forcing method and the ghost cell method. The directing-forcing type method numerically satisfies the boundary condition from the fluid force calculated at the boundary surface of the structure, and the ghost-cell type method is a computational method that satisfies the boundary condition through interpolation by placing a virtual cell inside the obstacle. These IB methods have a disadvantage in that the computational algorithm is complex. In this study, the simplified immersed boundary (SIB) method enables the analysis of temporary structures on a fixed grid system and is easy to expand to three proposed dimensions. The SIB method proposed in this study is based on a one-field model for immiscible two-phase fluid that assumes that the density function of each phase moves with the center of local mass. In addition, the volume-weighted average method using the density function of the solid was applied to handle moving solid structures, and the CIP method was applied to the advection calculation to prevent numerical diffusion. To examine the analysis performance of the proposed SIB method, a numerical simulation was performed on an object falling to the free water surface. The numerical analysis result reproduced the object falling to the free water surface well.

A decoupling FEM for simulating near-field wave motion in two-phase media

  • Chen, S.L.;Liao, Z.P.;Chen, J.
    • Structural Engineering and Mechanics
    • /
    • v.25 no.2
    • /
    • pp.181-200
    • /
    • 2007
  • A decoupling technique for simulating near-field wave motions in two-phase media is introduced in this paper. First, an equivalent but direct weighted residual method is presented in this paper to solve boundary value problems more explicitly. We applied the Green's theorem for integration by parts on the equivalent integral statement of the field governing equations and then introduced the Neumann conditions directly. Using this method and considering the precision requirement in wave motion simulation, a lumped-mass FEM for two-phase media with clear physical concepts and convenient implementation is derived. Then, considering the innate attenuation character of the wave in two-phase media, an attenuation parameter is introduced into Liao's Multi-Transmitting Formula (MTF) to simulate the attenuating outgoing wave in two-phase media. At last, two numerical experiments are presented and the numerical results are compared with the analytical ones demonstrating that the lumped-mass FEM and the generalized MTF introduced in this paper have good precision.

Low-temperature/high-strain rate superplasticity of two-phase titanium alloys (2상 타이타늄 합금의 저온/고속 초소성)

  • Part, C.H.;Lee, C.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
    • /
    • 2009.10a
    • /
    • pp.76-79
    • /
    • 2009
  • The current understanding for phase/grain boundary sliding and low-temperature/high-strain rate superplasticity of two-phase titanium alloys is summarized. The quantitative analysis on boundary sliding revealed increased sliding resistance on the order of $\alpha/\beta\;\ll\;\alpha/\alpha\;\approx\;\beta/\beta$ boundary, hence, led to the conclusion that approximately 50% alpha(or beta) volume fraction and/or grain refinement is beneficial for obtaining large superplastic elongation at low temperature and/or high strain rate. To predict the temperature for 50% alpha volume in various alpha/beta Ti, artificial neural network was applied. Finally, much enhanced superplasticity was achieved through grain refinement utilizing dynamic globularization.

  • PDF