• Title/Summary/Keyword: Phase Inversion

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A Study on the Preparation and Characterization of Sulfonated PS/PVdF Composite Membranes (술폰화 폴리스틸렌/폴리비닐리덴플로라이드 복합막의 제조 및 특성에 관한 연구)

  • Hong, Young-Taik;Jung, Yeon-Gu;Park, Hyung-Su;Byun, Hong-Sik
    • Membrane Journal
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    • v.16 no.4
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    • pp.286-293
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    • 2006
  • Porous asymmetric membranes based on PVdF as a nascent membrane were prepared by using a phase inversion method. PVdF ion conductive composite membranes were finally made by introducing $SO_3{^-}$ from sulfuric acid after cross-linked PS with various DVB contents in the pores of PVdF. Final PVdF composite membranes were characterized by FTIR, SEM, EDS to verify $SO_3{^-}$. It was revealed that the solvent contents and ion exchange capacity (IEC) decreased with increase of the degree of cross-linking. As the degree of crosslink increases both the electric conductivity and methanol permeability decreased, which was showing the better values than Nafion 117. When DVB content was 8%, its electric conductivity ($5.58{\times}10^{-5}S/cm$) was similar to Nafion 117 ($6.03{\times}10^{-5}S/cm$). But the lower methanol permeability ($1.0{\times}10^{-6}cm^2/sec$) than that of Nafion 117 was obtained.

The measurement of the half period modulated pulse on earth for detection of a underground electric leakage point (지중선로 누전점 탐지를 위한 반주기 변조된 대지 펄스 측정)

  • Kim, Jae-Hyun;Jeon, Jeong-Chay;Yoo, Jae-Geun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.11
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    • pp.5123-5127
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    • 2011
  • Research and development for the technology, that is about maintenance and accidents prevention of underground power distribution line, are demanding. The precise detection of leakage point of underground power line is very important, because it is difficult to detect the exact location of a fault in underground power line and to repair faults. When earth electric potential is measured to detect underground electric leakage point after transmitting AC electric pulse wave to underground power line, it must be measured in a specific half period of AC pulse wave because the distribution of the electric earth potential varies with the polarity of the transmitted wave. In this paper we proposed the measurement of half period modulated earth potential as a method to detect a underground leakage point. And We compared the proposed method with other methods. Through experiments we verified that the proposed method can be implemented and operated properly.

PPTA/PVDF blend membrane integrated process for treatment of spunlace nonwoven wastewater

  • Li, Hongbin;Shi, Wenying;Qin, Longwei;Zhu, Hongying;Du, Qiyun;Su, Yuheng;Zhang, Haixia;Qin, Xiaohong
    • Membrane and Water Treatment
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    • v.8 no.4
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    • pp.311-321
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    • 2017
  • Hydrophilic and high modulus PPTA molecules were incorporated into PVDF matrix via the in situ polymerization of PPD and TPC in PVDF solution. PPTA/PVDF/NWF blend membrane was prepared through the immersion precipitation phase inversion method and nonwoven coating technique. The membrane integrated technology including PPTA/PVDF/NWF blend membrane and reverse osmosis (RO) membrane was employed to treat the polyester/viscose spunlace nonwoven process wastewater. During the consecutive running of six months, the effects of membrane integrated technology on the COD, ammonia nitrogen, suspended substance and pH value of water were studied. The results showed that the removal rate of COD, ammonia nitrogen and suspended substance filtered by PPTA/PVDF blend membrane was kept above 90%. The pH value of the permeate water was about 7.1 and the relative water flux of blend membrane remained above 90%. After the deep treatment of RO membrane, the permeate water quality can meet the water circulation requirement of spunlace process.

A study on membrane technology for surface water treatment: Synthesis, characterization and performance test

  • Haan, Teow Yeit;Shah, Mubassir;Chun, Ho Kah;Mohammad, Abdul Wahab
    • Membrane and Water Treatment
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    • v.9 no.2
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    • pp.69-77
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    • 2018
  • The use of membrane as an innovative technology for water treatment process has now widely been accepted and adopted to replace the conventional water treatment process in increasing fresh water production for various domestic and industrial purposes. In this study, ultrafiltration (UF) membranes with different formulation were fabricated via phase inversion method. The membranes were fabricated by varying the polymer concentration (16 wt%, 18 wt%, 20 wt%, and 21 wt%). A series of tests, such as field emission scanning electron microscope (FESEM), pore size and porosity, contact angle, and zeta potential were performed to characterize the membranes. The membrane performance in terms of permeation flux and rejection were evaluated using a laboratory bench-scale test unit with mine water, lake water and tube well as model feed solution. Long hour filtration study of the membranes provides the information on its fouling property. Few pore blocking mechanism models were proposed to examine the behaviour of flux reduction and to estimate the fouling parameters based on different degree of fouling. 21 wt% PVDF membrane with smaller membrane pore size showed an excellent performance for surface water treatment in which the treated water complied with NWQS class II standard.

Exploration of shockwaves on polymeric membrane physical properties and performance

  • Lakshmi, D. Shanthana;Saxena, Mayank;Ekambaram, Shivakarthik;Sivaraman, Bhalamurugan
    • Membrane and Water Treatment
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    • v.12 no.1
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    • pp.43-49
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    • 2021
  • The Commercial polymeric membranes like Polysulfone (PSF), Polyvinylidene difluoride (PVDF) and Polyacrylonitrile (PAN) which are an integral part of water purification investigation were chosen for the shockwave (SW) exposure experiment. These membranes were prepared by blending polymer (wt. %) / DMF (solvent) followed by phase-inversion casting technique. Shockwaves are generated by using Reddy Tube lab module (Table-top Shocktube) with range of pressure (1.5, 2.5 and 5 bar). Understanding the changes in membrane before and after shock wave treatment by parameters, i.e., pure water flux (PWF), rejection (%), porosity, surface roughness (AFM), morphology (SEM) and contact angle which can significantly affect the membrane's performance. Flux values PSf membranes shows increase, 465 (pristine) to 524 (1.5wt%) LMH at 50 Psi pressure and similar enhancement was observed at 100Psi (625 to 696 LMH). Porosity also shows improvement from 73.6% to 76.84% for 15wt% PSf membranes. It was observed that membranes made of polymers such as PAN and PSF (of high w/w %) exhibits some resistance against shockwaves impact and are stable compared to other membranes. Shockwave pressure of up to 1.5 bar was sufficient enough to change properties which are crucial for performance. Membranes exposed to a maximum pressure of 5 bar completely scratched the surface and with minimum pressure of 1.5bar is optimum enough to improve the water flux and other parameters. Initial results proved that SW may be suitable alternative route to minimize/control membrane fouling and improve efficiency.

Comparison of Ankle Angle and Lower extremity Muscle Activities Between Forefoot Strike, Heelfoot strike During the Stair Ascent Walking (계단 오름 보행 시 전족, 후족 착지 방법에 따른 하지의 근활성도와 발목 각도 비교)

  • Jun-Su Kim;Hyun-Jun Kim;Sang-Yeol Lee
    • PNF and Movement
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    • v.22 no.1
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    • pp.31-41
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    • 2024
  • Purpose: The purpose of this study is to compare lower extremity muscle activities and ankle joint angles between different foot strike patterns (forefoot strike, heelfoot strike) during stair ascent walking. Methods: The subjects of this study were 22 males who walked in each foot strike pattern on ascent stairs at a speed of 85 beats/min. During stair walking with the two types of foot strike patterns, the muscle activities of the rectus femoris, tibialis anterior, medial gastrocnemius, hamstring, and gluteus medius were measured. Additionally, ankle joint angles for inversion, eversion, dorsi flexion, and plantar flexion were recorded. Each participant underwent the experiment three times, with the foot strike pattern randomized. Results were averaged according to the foot strike pattern. Results: Significant differences in ankle angles were observed across all phases according to foot strike pattern. Muscle activities in the lower extremities showed significant differences in all phases except the swing 1 phase. Moreover, differences in foot movement trajectory were noted depending on the foot strike pattern. Conclusion: Walking on ascent stairs elicited differences in lower extremity muscle activities and ankle joint angles based on foot strike pattern. These findings can serve as foundational data for selecting a suitable foot strike pattern tailored to individual patient conditions when training patients in walking on ascent stairs.

Effectiveness and Preparation of Nano-emulsion of a Rapeseed Oil Extract Originated from Jeju with PIT Emulsifying System (PIT유화시스템을 이용한 제주산 유채씨앗 오일추출물의 나노에멀젼의 제조 및 효과)

  • Joo, Se-Jin;Kim, Hack-Soo;Lee, Jeong-Koo;Lee, Min-Hee;Kim, In-Young
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.3
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    • pp.486-494
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    • 2012
  • Nano-emulsion with phase inversion temperature (PIT) emulsifying system was prepared to use rapeseed oil from originating Jeju in order to apply various cosmetic applications. Natural rape seed oil (NRSO) extraction was extracted using n-hexane as a solvent. NRSO extract showed a light yellowish color of viscous liquid as well as yield was $43{\pm}2.5%$. Acid value was $2.76{\pm}0.5$ and gravity was $0.89{\pm}0.05$. Droplet size of PIT-Yuche-NE with 20wt% of rapeseed oil was 50-120nm (average: $82{\pm}5.8nm$) and zeta potential was -29.5mV. It was thermodynamically good stable emulsion due to $(PEG)_{5-30}$fattyacidether. Some conclusions from the result of characteristic experiment were obtained as follows. First, the anti-oxidative activity was measured by free radical scavenging activity using DPPH (1,1-diphenyl-2-picrylhydrazyl radical). Anti-oxidative activity of PIT-Yuche-NE was $37.2{\pm}6.7%$ on 10mg/mL compared with PIT-Toco-NE (Natural tocopherol nano-emulsion, $28.8{\pm}6.5%$ on 10 mg/mL) and PIT-Nokcha-NE (Green tea extract nano-emulsion, $29.6{\pm}7.2%$ on 10mg/mL). Second, the collagen synthesis activity of PIT-Yuche-NE was $148{\pm}15.2%$ compared with PIT-Toco-NE (Natural tocopherol nano-emulsion, $121{\pm}13.5%$ on 10mg/mL) and PIT-Nokcha-NE (Green tea extract nano-emulsion, $95{\pm}12.7%$ on 10mg/mL). Third, the effectiveness of moisturizing activity of Yuche-CRM with Aramo-TS after 6 hours increase $47{\pm}3.9%$ (*p-value£0.05, n=7) whereas Both Toco-CRM was $30{\pm}5.2%$ (*p-value£0.05, n=7) and Nokcha-CRM was $35{\pm}4.5%$. Therefore, Yuche-CRM has higher moisturizing effect than other two creams. Finally, Nano-emulsion stabilizing rapeseed oil using PIT emulsifying system of this study can be used to apply cosmetics industry and pharmaceutical industry.

Effect of Nonsolvent Additive in Casting Solutions on Polysulfone Membrane Preparation (Polysilfone 막의 제조에 있어 제막용액에 첨가된 비용매의 영향)

  • 한명진
    • Membrane Journal
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    • v.6 no.3
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    • pp.157-165
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    • 1996
  • Polysulfone(PS) membranes were prepared from homogeneous PS solutions by the phase inversion technique. When propionic acid(PA) was added into a casting solution of n-methylpyrrolidone(NMP) and PS, precipitation rate of the solution film was accelerated. This kind of acceleration was consistent, even though a precipitating nonsolvent was changed from water to isopropanol. These phenomena were caused by decrease of nonsolvent tolerance in the casting solution due to addition of PA. PS powder was prepared by precipitation of a 3wt% solution in dimethylformamide(DMF) using ethanol as nonsolvent. Gas adsorption analysis of the powder showed that the capillary condensation sites were found in the powder structure. Membranes prepared from PS solution(15wt%) in NMP had the following characteristics of gas adsorption and water permeation. In gas adsorption analysis, the membrane precipitated using isopropanol showed low uptake of nitrogen gas and the capillary condensation sites were not found. On the contrary, a significant amount of the capillary condensation sites was found in the membrane coagulated by water, which was related to increase of nitrogen uptake. tn the membrane prepared froin the solution including PA, an increase of the Henry's law sites and the Langmuir sites was not found clearly. However, the capillary condensation sites were significantly increased, and the water transport also increased.

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Evaluation of 2D Shear Wave Velocity Imaging of Subground Using HWAW Method (HWAW 기법을 이용한 지반의 2차원 전단파 속도 평가)

  • Kim, Jong-Tae;Park, Hyung-Choon;Bang, Eun-Seok;Park, Heon-Joon;Kim, Dong-Soo
    • Journal of the Korean Society for Nondestructive Testing
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    • v.27 no.2
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    • pp.105-114
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    • 2007
  • Two-dimensional imaging of $V_s$ profile becomes more important in Korea because of the large horizontal variation of soil stiffness. To obtain a shear-wave velocity profile in geotechnical practice, various seismic nondestructive investigation methods are being frequently used. In this study, harmonic wavelet analysis of wave (HWAW) method is applied to the determination of $V_s$ profile to overcome some of weaknesses in the existing surface wave methods. HWAW method which is based on time-frequency analysis using harmonic wavelet transform has been developed to determine phase and group velocities of waves. Field testing of this method is relatively simple and fast because one experimental setup which consists of one pair of receivers is needed to determine $V_s$ profile of site. The proposed method uses the signal portion of the maximum local signal/noise ratio to evaluate the phase velocity to minimize the effects of noise, and uses single array inversion which considers receiver locations. Field tests were performed in 2 sites in order to evaluate accuracy of test method and estimate the applicability of 2-D imaging by HWAW method. Through field applications and comparison with other test results, the good accuracy and applicability of the proposed method were verified.

Preparation of the Hollow Fiber Type Perovskite Catalyst for Methane Complete Oxidation (메탄의 완전산화 반응을 위한 중공사형 페롭스카이트 촉매 제조)

  • Lee, Seong Woon;Kim, Eun Ju;Lee, Hong Joo;Park, Jung Hoon
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.297-302
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    • 2018
  • Bead type and hollow fiber type catalyst (HFC, Hollow Fiber type Catalyst) was prepared by $La_{0.1}Sr_{0.9}Co_{0.2}Fe_{0.8}O_{3-{\delta}}$ (LSCF1928) perovskite powder catalyst which showed excellent methane complete oxidation characteristics through previous studies. The HFC have a cylindrical shape with an empty interior, and pores can be formed through Phase inversion method so the specific surface area can be remarkably improved. In the case of the bead type catalyst prepared by adding Methyl Cellulose (MC), $SrCO_3$ was produced in addition to the original catalyst composition of LSCF1928 due to the reaction of $CO_2$ emitted from MC and Sr of the catalyst. In the case of the HFC, a single phase perovskite structure was obtained without impurities. The HFC calcined at $700{\sim}900^{\circ}C$ showed pore structure of finger-sponge-finger structure, and 99.9% oxygen conversion rate was achieved through complete oxidation of methane at $475^{\circ}C$. Air gap and spinning pressure condition were changed to control the HFC pore. 2 cm air gap and 7 bar spinning pressure showed the best catalytic performance and achieved oxygen conversion rates of more than 70.65%, 93.01%, and 99.99% at $425^{\circ}C$, $450^{\circ}C$ and $475^{\circ}C$, respectively.