• Title/Summary/Keyword: Phase Inversion

Search Result 398, Processing Time 0.027 seconds

The Observation of Nucleation & Growth during Water Vapor Induced Phase Inversion of Chlorinated Poly(vinyl chloride) Solution using SALS

  • Jang, Jae Young;Lee, Young Moo;Kang, Jong Seok
    • Korean Membrane Journal
    • /
    • v.6 no.1
    • /
    • pp.61-69
    • /
    • 2004
  • Small angle light scattering (SALS) and field emission scanning electron microscope (FE-SEM) have been used to investigate the effects of alcohol on phase separation of chlorinated poly(vinyl chloride) (CPVC)/tetrahydrofuran (THF)/alcohol (9/61/30 wt%) solution during water vapor induced phase separation. A typical scattering pattern of nucleation & growth (NG) was observed for all casting solutions of CPVC/THF/alcohol. In the case of the phase separation of CPVC dope solution containing 30 wt% ethanol or n-propanol, the demixing with NG was observed to be heterogeneous. Meanwhile, the phase separation of CPVC dope solution with 30 wt% n-butanol was found to be predominantly homogeneous NG. Although the different phase separation behavior of NG was observed with types of alcohol additives, the resultant surface morphology had no remarkable differences. That is, even though the NG process by water vapor is either homogeneous or heterogeneous, this difference does not play a main role on the final surface morphology. However, it was estimated from the result of hydraulic flux that the phase separation by homogeneous NG provided the membrane geometry with lower resistance in comparison with that by heterogeneous one.

Seismic AVO Analysis, AVO Modeling, AVO Inversion for understanding the gas-hydrate structure (가스 하이드레이트 부존층의 구조파악을 위한 탄성파 AVO 분석 AVO모델링, AVO역산)

  • Kim Gun-Duk;Chung Bu-Heung
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2005.06a
    • /
    • pp.643-646
    • /
    • 2005
  • The gas hydrate exploration using seismic reflection data, the detection of BSR(Bottom Simulating Reflector) on the seismic section is the most important work flow because the BSR have been interpreted as being formed at the base of a gas hydrate zone. Usually, BSR has some dominant qualitative characteristics on seismic section i.e. Wavelet phase reversal compare to sea bottom signal, Parallel layer with sea bottom, Strong amplitude, Masking phenomenon above the BSR, Cross bedding with other geological layer. Even though a BSR can be selected on seismic section with these guidance, it is not enough to conform as being true BSR. Some other available methods for verifying the BSR with reliable analysis quantitatively i.e. Interval velocity analysis, AVO(Amplitude Variation with Offset)analysis etc. Usually, AVO analysis can be divided by three main parts. The first part is AVO analysis, the second is AVO modeling and the last is AVO inversion. AVO analysis is unique method for detecting the free gas zone on seismic section directly. Therefore it can be a kind of useful analysis method for discriminating true BSR, which might arise from an Possion ratio contrast between high velocity layer, partially hydrated sediment and low velocity layer, water saturated gas sediment. During the AVO interpretation, as the AVO response can be changed depend upon the water saturation ratio, it is confused to discriminate the AVO response of gas layer from dry layer. In that case, the AVO modeling is necessary to generate synthetic seismogram comparing with real data. It can be available to make conclusions from correspondence or lack of correspondence between the two seismograms. AVO inversion process is the method for driving a geological model by iterative operation that the result ing synthetic seismogram matches to real data seismogram wi thin some tolerance level. AVO inversion is a topic of current research and for now there is no general consensus on how the process should be done or even whether is valid for standard seismic data. Unfortunately, there are no well log data acquired from gas hydrate exploration area in Korea. Instead of that data, well log data and seismic data acquired from gas sand area located nearby the gas hydrate exploration area is used to AVO analysis, As the results of AVO modeling, type III AVO anomaly confirmed on the gas sand layer. The Castagna's equation constant value for estimating the S-wave velocity are evaluated as A=0.86190, B=-3845.14431 respectively and water saturation ratio is $50\%$. To calculate the reflection coefficient of synthetic seismogram, the Zoeppritz equation is used. For AVO inversion process, the dataset provided by Hampson-Rushell CO. is used.

  • PDF

Surfactant Washing of Organics from a Contaminated Site I. Clean Up of Hydrocarbon Contaminated Soils (Surfactant washing에 의한 토양 내의 유기물 제거에 관한 연구 I. 탄화수소로 오염된 토양의 정화)

  • Lim, Jong-Choo
    • Applied Chemistry for Engineering
    • /
    • v.8 no.3
    • /
    • pp.357-364
    • /
    • 1997
  • The objective of this study was to find optimum nonionic surfactants for clean up of soils contaminated by hydrocarbon oils. PIT(phase inversion temperature) measurements in ternary systems containing pure hydrocarbons, pure nonionic surfactants, and water were carried out and interfacial tensions were measured as a function of time for n-hexadecane oil drops brought into contact with various mixtures of nonionic surfactant and water. Batch surfactant washing experiments were performed based on the measurement, results of PIT and interfacial tension and the results showed that maximum removal of n-hexadecane occurred at the PIT of the system. For the $C_{12}E_5(C_{12}H_{25}O(CH_2CH_2O)_5H)$ system, maximum n-hexadecane removal of 73.4% occurred at the PIT of $52^{\circ}C$. In contrast, n-hexadecane removal at $25^{\circ}C$ and at $60^{\circ}C$, each corresponding to the conditions of below PIT and above PIT of the system, was found to be 57.1% and 57.0% respectively. The maximum removal of a hydrocarbon at the PIT of a system, where the hydrophilic and hydrophobic properties are balanced, was found to be due to the existence of high oil solubilization into a middle-phase microemulsion and ultralow interfacial of the order of $10^{-2}$ to $10^{-3}$ dyne/cm between middle-phase microemulsion and excess oil phase.

  • PDF

Average Particle Size Prediction of Rubber Dispersed Phase in High Impact Polystyrene (내충격성 폴리스티렌의 고무상 입자경 예측)

  • Lee, Seong-Jae;Chung, Kyung-Ho
    • Elastomers and Composites
    • /
    • v.31 no.5
    • /
    • pp.327-334
    • /
    • 1996
  • A correlative analysis has been carried out to predict the average particle size of rubber dispersed phase In high impact polystyrene manufactured by bulk polymerization. To do the correlation, a mechanistic model suggested previously by the author was used for describing the size of stabilizing particles agitated under the turbulent viscous shear subranges in a prepolymerization reactor, where the rubber particles were assumed to be formed at the time of phase inversion in the reactor. Viscosities required for the model were postulated to describe the overall behavior of butadiene rubber and polystyrene mixture along the wide range of conversion. The good agreement between the model and the experimental data from a plant was quite satisfactory for the prediction of the average rubber particle size of high impact polystyrene.

  • PDF

Pump Light Porer of Wideband Optical Phase Conjugator Dependence on Amplifier Spacing in 320 Gbps WDM Systems with MSSI

  • Lee Seong-Real
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • v.31 no.8A
    • /
    • pp.735-744
    • /
    • 2006
  • In this paper, the optimum pump light powers of optical phase conjugator(OPC) are numerically investigated as a function of amplifier spacing in 1,200 km $8{\times}40$ Gbps WDM systems with 0.1, 0.4, 0.8, or 1.6 ps/nm/km dispersion coefficient. It is confirmed that the variation of optimal pump light power dependence on amplifier spacing for NRZ transmission system is smaller than that for RZ transmission system through the evaluations and analysis of eye opening penalty(EOP) characteristics. And, in both cases of NRZ and RZ transmission, the variation of optimal pump light power is more increased as amplifier spacing becomes longer. Additionally, it is confirmed that the best amplifier spacing in NRZ and RZ transmission system is 50 km.

Compensation for Distorted Signals by using Optimal Pump Light Power in WDM Systems with Non-midway Optical Phase Conjugator

  • Lee Seong-Real
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • v.30 no.7A
    • /
    • pp.542-549
    • /
    • 2005
  • In this paper, the optimal pump light power of optical phase conjugator (OPC) and the compensation characteristics of distorted WDM channel signals are numerically investigated, when the OPC with highly-nonlinear dispersion shifted fiber (HNL-DSF) not be placed at the mid-way of total transmission length. The total dispersion of former half section and latter half section is assumed to be same each other in this approach. It is confirmed that, in WDM transmission systems with OPC deviated from the mid-way, the pump light power for best compensation must be flexible selected depending on the OPC position. This optimal pump light power is gradually increased as the OPC is gradually closer to the receiver. Consequently, it is possible to establish the compensation system independent on the OPC position by setting optimal pump light power connected with the OPC position.

Adaptive Control Design for Missile using Neural Networks Augmentation of Existing Controller (기존제어기와 신경회로망의 혼합제어기법을 이용한 미사일 적응 제어기 설계)

  • Choi, Kwang-Chan;Sung, Jae-Min;Kim, Byoung-Soo
    • Journal of Institute of Control, Robotics and Systems
    • /
    • v.14 no.12
    • /
    • pp.1218-1225
    • /
    • 2008
  • This paper presents the design of a neural network based adaptive control for missile is presented. The application model is Exocet MM40, which is derived from missile DATCOM database. Acceleration of missile by tail Fin control cannot be controllable by DMI (Dynamic Model Inversion) directly because it is non-minimum phase system. So, the inner loop consists of DMI and NN (Neural Network) and the outer loop consists of PI controller. In order to satisfy the performances only with PI controller, it is necessary to do some additional process such as gain tuning and scheduling. In this paper, all flight area would be covered by just one PI gains without tuning and scheduling by applying mixture control technique of conventional controller and NN to the outer loop. Also, the simulation model is designed by considering non-minimum phase system and compared the performances to distinguish the validity of control law with conventional PI controller.

Transversely isotropic thin circular plate with multi-dual-phase lag heat transfer

  • Lata, Parveen;Kaur, Iqbal;Singh, Kulvinder
    • Steel and Composite Structures
    • /
    • v.35 no.3
    • /
    • pp.343-351
    • /
    • 2020
  • The present research deals with the multi-dual-phase-lags thermoelasticity theory for thermoelastic behavior of transversely isotropic thermoelastic thin circular plate The Laplace and Hankel transform techniques have been used to find the solution of the problem. The displacement components, stress components, and conductive temperature distribution are computed in the transformed domain with the radial distance and further determined in the physical domain using numerical inversion techniques. The effect of rotation and two temperature are depicted graphically on the resulting quantities.

Liquid-Liquid Phase Separation in a Quaternary System of PolysuIfone/Polyethersulfone/N-Methyl-2-pyrrolidone/water (사성분계 시스템의 액액상분리에 관한 연구 (폴리술폰/폴리에테르술폰/NMP/물))

  • 백기전;김제영;이환광;김성철
    • Proceedings of the Membrane Society of Korea Conference
    • /
    • 1998.04a
    • /
    • pp.22-24
    • /
    • 1998
  • 1. INTRODUCTION : The phase inversion method is widely used to prepare a variety of polymeric membranes ranging from micro-filtration to gas separation. The final morphology obtained by immersion precipitation strongly reflects the thermodynamics and kinetics of the system involved. The equilibrium thermodynamics of the ternary system of polymer/solvent/ nonsolvent is still very important to understand and predict membrane structure. Polysulfone (PSf) and polyethersulfone (PES) are important polymers as membrane materials due to the chemical resistance, mechanical strength, thermal stability and transport properies. There are several reports on the experimental phase diagrams in ternary mixtures of PSf/solvent/nonsolvent, and PES/solvent/nonsolvent. It would be interesting to investigate the solution thermodynamics containing these two polymers since PES is slightly less hyclrophobic than PSf.

  • PDF

Reaction of Gae-Phase Atomic Hydrogen with Chemisorbed Hydrogen Atoms on an Iron Surface

  • Kim, M. S.;Ree, J.
    • Bulletin of the Korean Chemical Society
    • /
    • v.18 no.9
    • /
    • pp.985-994
    • /
    • 1997
  • The reaction of gas-phase atomic hydrogen with hydrogen atoms chemisorbed on Fe(110) surface is studied by use of classical trajectory procedures. Flow of energy between the reaction zone and bulk solid phase has been treated in the generalized Langevin equation approach. A London-Eyring-Polanyi-Sato energy surface is used for the reaction zone interaction. Most reactive events are found to occur in strong single-impact collisions on a subpicosecond scale via the Eley-Rideal mechanism. The extent of reaction is large and a major fraction of the available energy goes into the vibrational excitation of H2, exhibiting a vibrational population inversion. Dissipation of reaction energy to the heat bath can be adequately described using a seven-atom chain with the chain end bound to the rest of solid. The extent of reaction is not sensitive to the variation of surface temperature in the range of Ts=0-300 K in the fixed gas temperature, but it shows a minimum near 1000 K over the Tg=300-2500 K.