• Title/Summary/Keyword: Phase Diagram

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Incompatibility of Casein-Alginate Mixtures (카제인-알긴산 혼합물의 비혼합성)

  • Choi, Moon-Jung;Hwang, Jae-Kwan
    • Korean Journal of Food Science and Technology
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    • v.30 no.5
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    • pp.1035-1039
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    • 1998
  • Phase separation is the typical phenomenon in protein-polysaccharide mixtures because of thermodynamic incompatibility between two macromolecules. Phase separations of casein-alginate-water systems were investigated by using phase diagram under varying pH (6, 8 and 10) and NaCl concentrations (0, 0.25 and 0.5 M). Incompatibility decreased with increasing pH and decreasing NaCl concentration. Molecular weight of alginates did not significantly affect the phase diagram of casein-alginate-water systems. The results strongly suggested that compatibility of casein and alginate involved electrostatic interactions.

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Synthesis of Iron Oxide Using Ferrous Sulfate and Ammonia Water (황산제일철과 암모니아수를 이용한 산화철 합성)

  • Kim, Sam-Joong;Eom, Tae-Hyoung;Wang, Wei;Suhr, Dong-Soo
    • Korean Journal of Materials Research
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    • v.18 no.4
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    • pp.218-221
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    • 2008
  • A $Fe(OH)_2$ suspension was prepared by mixing iron sulfate and a weak alkali ammonia solution. Following this, iron oxides were synthesized by passing pure oxygen through the suspension (oxidation). The effects of different reaction temperatures ($30^{\circ}C$, $50^{\circ}C$, $70^{\circ}C$) and equivalent ratios ($0.1{\sim}10.0$) on the formation of iron oxides were investigated. An equilibrium phase diagram was established by quantitative phase analysis of the iron oxides using the Rietveld method. The equilibrium phase diagram showed a large difference from the equilibrium phase diagram of Kiyama when the equivalent ratio was above 1, and single $Fe_3O_4$ phase only formed above an equivalent ratio 2 at all reaction temperatures. Kiyama synthesized iron oxide using iron sulfate and a strong alkali NaOH solution.

Design and Implementation of a Messenger Program for PDA Using UML (UML을 이용한 PDA용 메신저 프로그램 설계 및 구현)

  • Kwon, Young-Jik;Cui, Jun;Kwon, Dong-Hwoon
    • Journal of Korea Society of Industrial Information Systems
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    • v.15 no.5
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    • pp.149-158
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    • 2010
  • A messenger program in this paper was designed and implemented using Use Case Diagram, Class Diagram, Activity Diagram, and Sequence Diagram. We selected total 7 major functionalities such as PC server, login, friends management, chatting, file transfer, account management, etc. The followings are various implementation results from this paper. First, developers could easily understand the desired product and programming flow from using UML Diagrams. Second, PDA users could communicate with developers for a long time without time constraints. Third, there was high usability of UML Diagram in the phase of objected-oriented analysis. Forth, it was easy to update and maintain a program.

Phase Transitions and Phase Diagram of the Island Model with Migration

  • Park, Jeong-Man
    • Journal of the Korean Physical Society
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    • v.73 no.9
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    • pp.1219-1224
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    • 2018
  • We investigate the evolutionary dynamics and the phase transitions of the island model which consists of subdivided populations of individuals confined to two islands. In the island model, the population is subdivided so that migration acts to determine the evolutionary dynamics along with selection and genetic drift. The individuals are assumed to be haploid and to be one of two species, X or Y. They reproduce according to their fitness values, die at random, and migrate between the islands. The evolutionary dynamics of an individual based model is formulated in terms of a master equation and is approximated by using the diffusion method as the multidimensional Fokker-Planck equation (FPE) and the coupled non-linear stochastic differential equations (SDEs) with multiplicative noise. We analyze the infinite population limit to find the phase transitions from the monomorphic state of one type to the polymorphic state to the monomorphic state of the other type as we vary the ratio of the fitness values in two islands and complete the phase diagram of our island model.

A Study on Client's Decision-Making in Construction Phase of Building Projects in Japan

  • Tamura, Atsushi;Kaneta, Takashi;Furusaka, Shuzo
    • International conference on construction engineering and project management
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    • 2017.10a
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    • pp.183-191
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    • 2017
  • In building project, client needs to decide many things, and clients cooperate with architects, supervisors, general contractors and other consultants. Especially in construction phase, clients often make a decision. However, client's decision-making in construction phase often makes some kinds of risk. This paper aims to clarify the reality of client's decision-making in construction phase. First, client's decision-making is defined by laws and standards. Second, the questionnaire revealed the current status of client's decision-making in 4 works. Third, Fishbone diagram shows the factors of client's decision-making in four works. Finally, it was modeled how client's decision-making in construction phase affects the post-process of 4 works.

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Partial Miscibility of Binary Solution with Specific Interaction of Binomial Distribution (이항분포의 특정 상호작용을 갖는 이성분 용액에서의 부분혼합도)

  • Jung, Hae-Young
    • Journal of the Korean Chemical Society
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    • v.58 no.6
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    • pp.528-534
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    • 2014
  • In some binary solution, closed miscibility loop of temperature-composition phase diagram occurs where both an upper critical solution temperature and a lower critical solution temperature exist. It is known that this phenomena occurs if specific interaction between molecules exists. There are several ways describing the specific interaction. In this work it is assumed that the total number of specific interactions is distributed according to binomial distribution. In this case, exact mathematical conditions for closed miscibility loop phase behavior are derived when the specific interaction is applied to regular solution theory, quasichemical theory and Flory-Huggins lattice theory. And we investigated the effect of parameters on the phase diagram. The phase diagram of water-nicotine is calculated and compared with experimental data.

Structural Study of Thermally-Induced Phase Separation Membranes (열유도 상분리막의 구조 연구)

  • ;;Lloyd, Douglas R.
    • Proceedings of the Membrane Society of Korea Conference
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    • 1991.04a
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    • pp.1-4
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    • 1991
  • 고분자와 희석제 간의 interaction은 phase diagram의 형태로 결정하고 상분리 mechanism은 phase diagram에 의해 설명된다. Thermodynamic interaction이 TIPS 분리막의 구조에 미치는 영향을 조사하기 위하여 PP/C20alkane, PP/C20acid, PP/TA 3가지 system을 선택하였다. 200$^{\circ}$C에서 25 $^{\circ}$C로의 급냉과 분당 10 $^{\circ}$C의 냉각조건을 적용하였다. 각 phase diagram의 형태와 냉각조건에 따라 상분리 mechanism이 달라져서 서론에서 언급한 바와 같이 각기 특유의 구조를 갖게됨을 확인하였다. 같은 종류의 희석제의 chain length가 분리막의 구조에 미치는 영향을 조사하였다. 희석제의 chain length에 따라 결정화 온도가 달라지며 PP와의 결정화 속도 차이에 의하여 구조가 다양하게 변화되었다. 또한 가 희석제의 확산계수의 차이에 의하여 PP 결정화 시 희석제의 외부 방출 정도가 달라 이에 의한 구조의 차이도 관찰되었다. TIPS 공정에서 용액의 조성이 분리막의 구조에 미치는 영향을 조사하였는데, 조성에 의한 nucleation density의 차이에 따라 PP spherulite의 충돌 (impingment)등이 구조에 영향을 미쳤으며 porosity도 변화하였다. 또한 PP/TA system에서는 조성에 따라 상분리 mechanism이 달라져 현격한 구조의 차이를 보였다. 또한 냉각 속도에 따라 PP spherulitic structure가 변화함을 확인하였고, PP 결정화에 따른 희석제의 방출에 의하여 interspherulitic과 intraspherulitic pore를 갖는 2중 구조를 갖게 됨을 알 수 있다.

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Quantitative Analysis and Comparisons between In-Phase Control and Energy-Optimized Control for Series Power Quality Controllers

  • Xinming, Hunag;Jinjun, Liu;Hui, Zhang
    • Journal of Power Electronics
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    • v.9 no.4
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    • pp.553-566
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    • 2009
  • In-phase control and energy-optimized control are the two major control strategies proposed for series power quality controllers (SPQC). However quantitative analysis and comparison between these two control strategies is quite limited in previous publications. In this paper, an extensive quantitative analysis is carried out on these two control strategies through phasor diagram approach, and a detailed quantitative comparison is conducted accordingly. The load current is used as the reference phasor, and this leads to a simpler and clearer phasor diagram for the quantitative relationship. Subsequently detailed analysis of SPQC using in-phase control and energy-optimized control are provided respectively, under different modes both for under voltage/voltage sag and for over voltage/voltage swell. The closed form analytic expressions and the curves describing SPQC compensation characteristics are obtained. The detailed system power flow is figured out for each mode, and the detailed quantitative comparison between the two control strategies is then carried out. The comparison covers several aspects of SPQC, such as required compensating voltage magnitude, required capacity of energy storage component, and maximal ride-through time. In the end, computer simulation and prototype experimental results are shown to verify the validity of all the analysis and the result of the comparison.

Characterization of Ca Precipitation in Al-Mg Alloys Containing a Trace of Ca During Homogenization

  • Seong-Ho Ha;Young-Chul Shin;Bong-Hwan Kim;Young-Ok Yoon;Hyun-Kyu Lim;Sung-Hwan Lim;Shae K. Kim
    • Archives of Metallurgy and Materials
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    • v.66 no.4
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    • pp.959-962
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    • 2021
  • In this study, precipitation of Ca in Al-Mg alloys containing a trace of Ca during homogenization was investigated using a transmission electron microscope (TEM) and calculated phase diagrams. TEM result indicated that the Ca-based particles found in the examined sample are Ca7Mg7.5Si14. From the calculation of Scheil-Gulliver cooling, it was found that the Ca was formed as Al4Ca and C36 laves phases with Mg2Si and Al13Fe4 from other impurities phase during solidification. No Ca-Mg-Si ternary phase existed at the homogenization temperature in the calculated phase diagram. From the phase diagram of Al-Al4Ca-Mg2Si three-phase isothermal at 490℃, it was shown that Ca7Mg6Si14 phase co-exists with Al, Mg2Si and Al4Ca in the largest region and with only Al and Mg2Si in Al4Ca-poor regions. It was thought that the Ca7Mg6Si14 ternary phase was formed by the interaction between Mg2Si and Al4Ca considering that the segregation can occur throughout the entire microstructures.

An Automatic Construction for Class Diagram from Problem Statement using Natural Language Processing

  • Utama, Ahmad Zulfiana;Jang, Duk-Sung
    • Journal of Korea Multimedia Society
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    • v.22 no.3
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    • pp.386-394
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    • 2019
  • This research will describe algorithm for class diagram extraction from problem statements. Class diagram notation consist of class name, attributes, and operations. Class diagram can be extracted from the problem statement automatically by using Natural Language Processing (NLP). The extraction results heavily depends on the algorithm and preprocessing stage. The algorithm obtained from various sources with additional rules that are obtained in the implementation phase. The evaluation features using five problem statement with different domains. The application will capture the problem statement and draw the class diagram automatically by using Windows Presentation Foundation(WPF). The classification accuracy of 100% was achieved. The final algorithm achieved 92 % of average precision score.