• Title/Summary/Keyword: Phase Behavior

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The Effect of an External Electric Field on Phase Separation, Phase Dissolution, and Isothermal Crystallization Behavior of Poly(vinylidene fluoride)/Poly(1,4-butylene adipate) Blends

  • Kim, Kap-Jin;Lee, Jong-Soon
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.7-8
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    • 2003
  • Since PVDF/poly(1,4-butylene adipate) blend shows much lower LCST curve compared with PVDF/PMMA blend, the PVDF/PBA blend can be a good candidate for investigating the effect of the electric field on the phase separation and dissolution behavior of an electro-active polymer and electro-inactive polymer blend. (omitted)

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Pull-in Behavior Analysis in Optical Disk Drive Using Phase Plane and Evaluations for Effecting Parameters of it (위상 평면을 이용한 광 디스크 트랙 끌어들임의 동적 해석 및 영향 인자의 평가)

  • Choi, Jin-Young;Park, Tae-Wook;Yang, Hyunseok;Park, No-Cheol;Park, Young-Pil
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.15 no.1 s.94
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    • pp.29-38
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    • 2005
  • The track pull-in behavior analysis in an optical disk drive (ODD) using plane phase and the evaluations for effecting parameters of it are discussed. Track pull-in, track capture procedure to do track following control, is a key factor to increase data transfer rate. First, the relative velocity between the beam spot of an optical pick-up and the target track of an optical disk is analyzed during the track pull-in procedure. In this process, it is showed that the track error signal has nonlinear characteristics which are depending on the time. Second, Runge-Kutta method to solve the nonlinear equation is applied to find the track pull-in behavior, and some optimal parameters to get stable and fast pull-in condition are obtained. Then, the phase plane analysis for track pull-in procedure is presented. Finally, some comments for the simulated results are discussed briefly.

Phase Behavior of Poly(ethylene-co-norbornene) in $C_6$ Hydrocarbon Solvents: Effect of Polymer Concentration and Solvent Structure

  • Kwon, Hyuk-Sung;Lee, Sang-Ho
    • Macromolecular Research
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    • v.11 no.4
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    • pp.231-235
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    • 2003
  • Phase behavior information is necessary for accomplishing homogeneous copolymerization to obtain high yield of copolymers and prevent a fouling problem. Cloud-point data to $160^{\circ}C$ and 1,450 bar are presented for five $C_6$ hydrocarbon solvents, normal hexane, 2,2-dimethyl butane, 2,3-dimethyl butane, 2-methyl pentane, and 3-methyl pentane, with poly(ethylene-co-53 mol% norbornene) ($PEN_{53}$). The pressure-concentration isotherms measured for $PEN_{53}$/n-hexane have maximums that range between 5 and 12 wt% $PEN_{53}$. The cloud-point curves for $PEN_{53}$ all have negative slopes that decrease in pressure with temperatures. The single-phase region of $PEN_{53}$ in n-hexane is larger than the regions in 2,2-dimethyl butane, 2,3-dimethyl butane, 2-methyl pentane, and 3-methyl pentane. The cloud-point curve of $PEN_{53}$ in 2,2-dimethyl butane is located at higher temperatures and pressures than the curve in 2,3-dimethyl butane due to the reduced dispersion interactions with and limited access of 2,2-dimethyl butane to the copolymer. Similar cloud-point behavior is observed for $PEN_{53}$ in 2-methyl pentane and 3-methyl pentane.

Acute Systemic Infusion of Bupropion Decrease Formalin Induced Pain Behavior in Rat

  • Naderi, Somayyeh;Pakdel, Firouz Ghaderi;Osalou, Mostafa Ashrafi;Cankurt, Ulker
    • The Korean Journal of Pain
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    • v.27 no.2
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    • pp.118-124
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    • 2014
  • Background: The chronic pain can disturb physical, psychological, and social performances. Analgesic agents are widely used but some antidepressants (ADs) showed analgesia also. Bupropion is using for smoke cessation but it can change morphine withdrawal signs such as pain. This study tested the acute systemic effect of bupropion on formalin induced pain behavior in rats. Methods: Wistar male healthy rats were divided into 7 groups (control, sham, and 5 treated groups with 10, 30, 90, 120, and 200 mg/kg of bupropion, i.p.). The bupropion injected 3 hours prior to formalin induced pain behavior. Formalin (50 ${\mu}l$, 2.5%) was injected subcutaneously in dorsal region of right hindpaw in all animals. Nociceptive signs were observed continuously on-line and off-line each minute. Common pain scoring was used for pain assessment. Results: The analysis of data by one-way ANOVA showed that bupropion can reduce pain scores in the second phase but not in first phase. Bupropion decreased the licking/biting duration significantly in first and second phase of formalin test. Conclusions: The results showed that bupropion has analgesic effects at systemic application. The change of second phase of the pain behavior was significant and it revealed that central mechanisms involve in bupropion analgesia.

Effects of Nitrogen on Deformation Behavior of Duplex Stainless Steel (이상 스테인레스강의 변형거동에 미치는 질소의 영향)

  • 이형직;장영원
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.05a
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    • pp.49-52
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    • 2003
  • The effects of nitrogen on the deformation behavior of duplex stainless steel have been studied The variation of strength was correlated with the characteristic microstructures. Analysis based on Hall-Petch relation confirmed that nitrogen enhances phase-boundary strengthening effect. The evolution of dislocation structure, slip traces, and misorientation distribution during deformation were also characterized to elucidate the effect of nitrogen on inelastic deformation mechanism.

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Ferroelectric Phase Transition Behavior in $(Na_{1/2}Bi_{1/2})TiO_3-PbTiO_3$ System ($(Na_{1/2}Bi_{1/2})TiO_3-PbTiO_3$ 고용체의 강유전 상전이 거동)

  • 홍국선;조서용;박승익
    • Journal of the Korean Ceramic Society
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    • v.32 no.8
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    • pp.915-921
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    • 1995
  • The morphotropic phase boundary and phase transitions of the solid solutiion system, (1-x)(Na1/2Bi1/2)TiO3-PbTiO3+xPbTiO3 were studied by investigating changes in crystal structure, variations in permittivity with temperature, and calorimetric behavior. It was observed that the morphotropic phase boundary (MPB) of this solid solutiion system was at near 14 mol% of PbTiO3. Compositions containing less than 10mol% PbTiO3 (x<0.1) exhibited a phase transition, i.e. ferroelectric rhombohedrallongrightarrowparaelectric paraelectric cubic, with increasing temperature. Composition containing more than 14 mol% PbTiO3 (x 0.14) showed a phase transition from ferroelectric tetragonal to paraelectric cubic. In the composition range of 0.1$\varepsilon$ (T) curve, which coincided with a phase transition from ferroelectric rhombohedral to an intermediate phase, was also found.

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Prediction of Retention Behavior of Alkyl Benzenes by Hydrophobicity Parameters in Reversed-Phase Column (소수성 파라메터를 적용한 알킬벤젠류의 역상컬럼내의 용출거동 예측)

  • Lee, Chang-Young;Park, Myung-Yong;Lee, Yong-Moon
    • YAKHAK HOEJI
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    • v.53 no.5
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    • pp.281-285
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    • 2009
  • The retention of solutes in reversed-phase high-performance liquid chromatography depends on their hydrophobicity. Although the retention behaviors of alkyl benzenes have been reported so far, quite a few authors have mentioned the retention behavior of alkyl benzenes with plural hydrophobicity parameters. In this sense, we were interested in the retention behaviors of alkyl benzenes having benzene moiety and increasing alkyl chain. In this study, we therefore investigated the retention behavior of alkyl benzenes in reversed-phase high-performance liquid chromatography in order to obtain information concerning the effects of the aromatic moiety and the carbon chain on the retention mechanism by comparing their capacity factor (k') in relation to the carbon chain length. The eluent acetonitrile ($CH_3CN$) showed high selectivity on alkyl benzenes, showing the high difference of capacity factor (${\Delta}log\;k'$) between toluene and octyl benzene. Indeed, the ${\Delta}log\;k'$ of 80% $CH_3CN$ represented 1.42- and 4.25-times longer than 90% MeOH and 60% THF, respectively. The hydrophobicity parameters, van der Waals volume, bond constant, partition constant, $\pi$-energy effect and enthalpy were evaluated with the capacity factor (k') of alkyl benzenes eluted on 80% CH3CN, 90% MeOH and 60% THF, respectively. The best eluent for predicting retention behavior of alkyl benzenes was 90% MeOH ($R^2$ 0.999). The three parameters, van der Waals volume, bond constant and partition constant were well coincident to log k' by increasing alkyl benzenes. However, $\pi$-energy effect and enthalpy were severely disagreeable. Taken together, van der Waals volume, bond constant and partition constant were a reliable parameters to predict the retention behaviors of alkyl benzenes on reversed-phase column.

CFD Analysis on Two-phase Flow Behavior of Liquid Water in Cathode Channel of PEM Fuel Cell (PEM 연료전지 공기극 유로에서 물의 가동에 대한 CFD 해석)

  • Kim, Hyun-Il;Nam, Jin-Hyun;Shin, Dong-Hoon;Chung, Tae-Yong;Kim, Young-Gyu
    • New & Renewable Energy
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    • v.3 no.4
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    • pp.8-15
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    • 2007
  • Liquid water in flow channel is an important factor that limits the steady and transient performance of PEM fuel cells. A computational fluid dynamics study based on the volume-of-fluid [VOF] multi-phase model was conducted to understand the two-phase flow behavior of liquid water in cathode gas channels. The liquid water transport in $180^{\circ}{\Delta}$ bends was investigated, where the effects of surface characteristics (hydrophilic and hydrophobic surfaces], channel geometries (rectangular and chamfered corners], and air velocity in channel were discussed. The two-phase flow behavior of liquid water with hydrophilic channel surface and that with hydrophobic surface was found very different; liquid water preferentially flows along the corners of flow channel in hydrophilic channels while it flows in rather spherical shape in hydrophobic channels. The results showed that liquid water transport was generally enhanced when hydrophobic channel with rounded corners was used. However, the surface characteristics and channel geometries became less important when air velocity was increased over 10m/s. This study is believed to provide a useful guideline for design optimization of flow patterns or channel configurations of PEM fuel cells.

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Concrete-steel bond-slip behavior of recycled concrete: Experimental investigation

  • Ren, Rui;Qi, Liangjie;Xue, Jianyang;Zhang, Xin;Ma, Hui;Liu, Xiguang;Ozbakkaloglu, Togay
    • Steel and Composite Structures
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    • v.38 no.3
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    • pp.241-255
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    • 2021
  • In order to study the interfacial bond-slip behavior of steel reinforced recycled concrete (SRRC) under cyclic loading, thirteen specimens were designed and tested under cyclic loading and one under monotonic loading. The test results indicated that the average bond strength of SRRC decreased with the increasing replacement ratio of recycled concrete, whereas the bond strength increased with an increase in the concrete cover thickness, the volumetric stirrup ratio, and the strength of recycled concrete. The ultimate bond strength of the cyclically-loaded specimen was significantly (41%) lower than that of the companion monotonically-loaded specimen. The cyclic phenomena also showed that SRRC specimens went through the nonslip phase, initial slip phase, failure phase, bond strength degradation phase and residual phase, with all specimens exhibiting basically the same shape of the bond-slip curve. Additionally, the paper presents the equations that were developed to calculate the characteristic bond strength of SRRC, which were verified based on experimental results.

Effect of the change of second phase hardness on corrosion fatigue behavior of dual phase steel in 3% nacl solution (3% NaCl 수용액중에서 복합조직강의 부식피로거동에 미치는 제2상 속도변화의 영향)

  • 오세욱;김웅집
    • Journal of Ocean Engineering and Technology
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    • v.6 no.2
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    • pp.85-93
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    • 1992
  • The only hardness of 2nd phase of martensite in dual phase steel which was composed of the martensite and ferrite was changed. Fatigue test was conducted by cantilever type of self-made rotated bending fatigue testing machine. The corrosion fatigue fracture behaviors of dual phase steel were investigated in 3% NaCl solution at $N_f$ = $1.5\times$$10^5$ $N_f$=1.0 $\times$ $10^6$ cycles. The fatigue strength was increased with increasing the hardness of 2nd phase. The size and number of corrsion pits were influenced by the 2nd phase hardness and pits remain constant in size just after they were transited into cracks. The life of crack initiation was effected by stress level. The shape of relation of $\Delta$K and da/dn has smaller scattering in it in 3% NaCl solution than that in air. The higher the 2nd phase hardness is, the higher the corrosion fatigue life becomes. Corrosion fatigue fracture behavior was effected by mechanics in case of $N_f$=1.5$\times$10$^5$$N_f$=1.5$\times$10$^6$ cycles.

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